130 lines
12 KiB
XML
130 lines
12 KiB
XML
<document id="65B1811E0BC107D87E3D91E19DE62ACB" ID-DOI="10.1016/j.phytochem.2018.12.022" ID-ISSN="1873-3700" ID-Zenodo-Dep="10481924" IM.bibliography_approvedBy="karina" IM.illustrations_approvedBy="karina" IM.materialsCitations_approvedBy="felipe" IM.metadata_approvedBy="felipe" IM.tables_requiresApprovalFor="GgImagineBatch" IM.taxonomicNames_approvedBy="karina" IM.treatments_approvedBy="karina" checkinTime="1704928502977" checkinUser="felipe" docAuthor="Nawrot, Joanna, Budzianowski, Jaromir & Nowak, Gerard" docDate="2019" docId="038587F2FFB2FFC22933FB4EFC67F9FB" docLanguage="en" docName="Phytochemistry.159.172-178.pdf" docOrigin="Phytochemistry 159" docSource="http://dx.doi.org/10.1016/j.phytochem.2018.12.022" docStyle="DocumentStyle:9E596C34F4E94307D29315B03ACE1007.6:Phytochemistry.2014-2019.journal_article" docStyleId="9E596C34F4E94307D29315B03ACE1007" docStyleName="Phytochemistry.2014-2019.journal_article" docStyleVersion="6" docTitle="Psephellus sibiricus subsp. leaves Wagenitz" docType="treatment" docVersion="4" lastPageNumber="177" masterDocId="FFBCFF8AFFB7FFC72A01FFD8FFA3FFEF" masterDocTitle="Phytochemical profiles of the leaves of Stizolophus balsamita and Psephellus sibiricus and their chemotaxonomic implications" masterLastPageNumber="178" masterPageNumber="172" pageNumber="177" updateTime="1706407054321" updateUser="karina">
|
||
<mods:mods id="E3B1058CE8BB35DCC7DB7719CDBD63A0" xmlns:mods="http://www.loc.gov/mods/v3">
|
||
<mods:titleInfo id="A80F36D1B61E76A6939B748C014A8D2E">
|
||
<mods:title id="3ED78663D1ACC7A478BA9B03FFBDDF0D">Phytochemical profiles of the leaves of Stizolophus balsamita and Psephellus sibiricus and their chemotaxonomic implications</mods:title>
|
||
</mods:titleInfo>
|
||
<mods:name id="90EF7965224FB687CB95BFFB34146B79" type="personal">
|
||
<mods:role id="20FCDE06F6BD0F3BAA98A0AAECFDB31F">
|
||
<mods:roleTerm id="65BC24E59389B17E7820B6116EF99323">Author</mods:roleTerm>
|
||
</mods:role>
|
||
<mods:namePart id="2CC52022EEA5CD6830F733E4FC641204">Nawrot, Joanna</mods:namePart>
|
||
<mods:affiliation id="A3C33C011B8682A9B61D6249103BD00E">∗ & Department of Medicinal and Cosmetic Natural Products, Poznan University of Medical Sciences, Mazowiecka Str. 33, 60 - 623 Poznan, Poland</mods:affiliation>
|
||
</mods:name>
|
||
<mods:name id="81B61F32586CE2656FFBC0B009B3E88C" type="personal">
|
||
<mods:role id="CCC5833882829FE8A83726426FFEE0FA">
|
||
<mods:roleTerm id="E49FFF76F3D6509E96C662B0C6E1DBD0">Author</mods:roleTerm>
|
||
</mods:role>
|
||
<mods:namePart id="CC8A73DF7357F80265F5B863A5E5A4B4">Budzianowski, Jaromir</mods:namePart>
|
||
</mods:name>
|
||
<mods:name id="2B8BBA53EC66C07E6082E7466549542C" type="personal">
|
||
<mods:role id="1C5F481618A12E59140165B53D0C3912">
|
||
<mods:roleTerm id="B214731023EFCE427122D35523A76E77">Author</mods:roleTerm>
|
||
</mods:role>
|
||
<mods:namePart id="098C209598005D14DAA0A7CD135204A8">Nowak, Gerard</mods:namePart>
|
||
</mods:name>
|
||
<mods:typeOfResource id="DB36BE0189BDAACBA2D79DAA9DEFEC7F">text</mods:typeOfResource>
|
||
<mods:relatedItem id="C3BF8566186606DEAF645FECE0F7E448" type="host">
|
||
<mods:titleInfo id="E5933B0ACB50D873D9388F04FBF77DC9">
|
||
<mods:title id="1867C28040832116270A48382590F548">Phytochemistry</mods:title>
|
||
</mods:titleInfo>
|
||
<mods:part id="97282490EBAE0CEC2F1BF8C35BF2F997">
|
||
<mods:date id="0005E1465A355F92C4976C1B774EB583">2019</mods:date>
|
||
<mods:detail id="8579B3C98E43811D942DB33915C0632E" type="pubDate">
|
||
<mods:number id="62763FE888222AE27A99B8C971987229">2019-03-31</mods:number>
|
||
</mods:detail>
|
||
<mods:detail id="FF317B6F025C38092F2E14A1B416D166" type="volume">
|
||
<mods:number id="B72507AEBA4FEA0F53ADF6E6BFF93E4A">159</mods:number>
|
||
</mods:detail>
|
||
<mods:extent id="DC3719DC5C3305B219EFD1B9C0739279" unit="page">
|
||
<mods:start id="663E03214EDB88EC772FBE560264EA29">172</mods:start>
|
||
<mods:end id="B931E387288C5F074BFC78FFBEF02515">178</mods:end>
|
||
</mods:extent>
|
||
</mods:part>
|
||
</mods:relatedItem>
|
||
<mods:location id="0FCD95188BC963DEFF1E352687CCB454">
|
||
<mods:url id="638166E287EB3BD5C8FB7996F6E0DFBA">http://dx.doi.org/10.1016/j.phytochem.2018.12.022</mods:url>
|
||
</mods:location>
|
||
<mods:classification id="1DD5D1AF5EDD0230543AAAA91C0DAD7E">journal article</mods:classification>
|
||
<mods:identifier id="7AB8EAA4BE5C93B967C4E6C7E5435F50" type="DOI">10.1016/j.phytochem.2018.12.022</mods:identifier>
|
||
<mods:identifier id="4657FA1B108C47EA05505FAA662A081B" type="ISSN">1873-3700</mods:identifier>
|
||
<mods:identifier id="8C73476B84CC3F14C72669317610160F" type="Zenodo-Dep">10481924</mods:identifier>
|
||
</mods:mods>
|
||
<treatment id="038587F2FFB2FFC22933FB4EFC67F9FB" LSID="urn:lsid:plazi:treatment:038587F2FFB2FFC22933FB4EFC67F9FB" httpUri="http://treatment.plazi.org/id/038587F2FFB2FFC22933FB4EFC67F9FB" lastPageNumber="177" pageId="5" pageNumber="177">
|
||
<subSubSection id="C336656FFFB2FFC22933FB4EFA2DFB46" box="[818,1422,1174,1193]" pageId="5" pageNumber="177" type="nomenclature">
|
||
<paragraph id="8B9336E4FFB2FFC22933FB4EFA2DFB46" blockId="5.[818,1422,1174,1193]" box="[818,1422,1174,1193]" pageId="5" pageNumber="177">
|
||
<heading id="D0DB8188FFB2FFC22933FB4EFA2DFB46" bold="true" box="[818,1422,1174,1193]" fontSize="36" level="1" pageId="5" pageNumber="177" reason="1">
|
||
<emphasis id="B958EAF6FFB2FFC22933FB4EFA2DFB46" bold="true" box="[818,1422,1174,1193]" italics="true" pageId="5" pageNumber="177">
|
||
3.4. Extraction and isolation of compounds from
|
||
<taxonomicName id="4C2C4D67FFB2FFC22EF0FB4EFAF1FB46" authority="(L.) Wagenitz" authorityName="Wagenitz" baseAuthorityName="L." box="[1265,1362,1174,1193]" class="Magnoliopsida" family="Asteraceae" genus="Psephellus" kingdom="Plantae" order="Asterales" pageId="5" pageNumber="177" phylum="Tracheophyta" rank="subSpecies" species="sibiricus" subSpecies="leaves">P. sibiricus</taxonomicName>
|
||
leaves
|
||
</emphasis>
|
||
</heading>
|
||
</paragraph>
|
||
</subSubSection>
|
||
<subSubSection id="C336656FFFB2FFC22952FB16FC67F9FB" pageId="5" pageNumber="177" type="description">
|
||
<paragraph id="8B9336E4FFB2FFC22952FB16FC67F9FB" blockId="5.[818,1488,1230,1556]" pageId="5" pageNumber="177">
|
||
The dried leaves of
|
||
<taxonomicName id="4C2C4D67FFB2FFC22E10FB16FBD0FB0E" box="[1041,1139,1230,1249]" class="Magnoliopsida" family="Asteraceae" genus="Psephellus" kingdom="Plantae" order="Asterales" pageId="5" pageNumber="177" phylum="Tracheophyta" rank="species" species="sibiricus">
|
||
<emphasis id="B958EAF6FFB2FFC22E10FB16FBD0FB0E" bold="true" box="[1041,1139,1230,1249]" italics="true" pageId="5" pageNumber="177">P. sibiricus</emphasis>
|
||
</taxonomicName>
|
||
(
|
||
<quantity id="4CD49B01FFB2FFC22E81FB16FB15FB0E" box="[1152,1206,1230,1249]" metricMagnitude="-1" metricUnit="kg" metricValue="4.529999999999999" pageId="5" pageNumber="177" unit="g" value="453.0">453 g</quantity>
|
||
) were crushed and soaked in MeOH. The MeOH extract was evapd, and the residue was dissolved in H
|
||
<subScript id="17A834A1FFB2FFC22940FAD7FCE9FAF4" attach="both" box="[833,842,1295,1307]" fontSize="5" pageId="5" pageNumber="177">2</subScript>
|
||
O. The aq. soln was re-extracted with
|
||
<collectingCountry id="F33B7674FFB2FFC22EA9FADEFB66FAF6" box="[1192,1221,1286,1305]" name="Switzerland" pageId="5" pageNumber="177">CH</collectingCountry>
|
||
<subScript id="17A834A1FFB2FFC22EC4FAD7FB6DFAF4" attach="both" box="[1221,1230,1295,1307]" fontSize="5" pageId="5" pageNumber="177">2</subScript>
|
||
Cl
|
||
<subScript id="17A834A1FFB2FFC22EE3FAD7FB48FAF4" attach="left" box="[1250,1259,1295,1307]" fontSize="5" pageId="5" pageNumber="177">2</subScript>
|
||
. The
|
||
<collectingCountry id="F33B7674FFB2FFC22F1FFADEFA98FAF6" box="[1310,1339,1286,1305]" name="Switzerland" pageId="5" pageNumber="177">CH</collectingCountry>
|
||
<subScript id="17A834A1FFB2FFC22F3AFAD7FAE7FAF4" attach="both" box="[1339,1348,1295,1307]" fontSize="5" pageId="5" pageNumber="177">2</subScript>
|
||
Cl
|
||
<subScript id="17A834A1FFB2FFC22F59FAD7FAC2FAF4" attach="left" box="[1368,1377,1295,1307]" fontSize="5" pageId="5" pageNumber="177">2</subScript>
|
||
extract was dried with Na
|
||
<subScript id="17A834A1FFB2FFC229BDFAF3FC66FAD8" attach="both" box="[956,965,1323,1335]" fontSize="5" pageId="5" pageNumber="177">2</subScript>
|
||
SO
|
||
<subScript id="17A834A1FFB2FFC229E1FAF3FC4AFAD8" attach="left" box="[992,1001,1323,1335]" fontSize="5" pageId="5" pageNumber="177">4</subScript>
|
||
, filtrated and evapd gave a residue (
|
||
<quantity id="4CD49B01FFB2FFC22F61FAFAFA38FADA" box="[1376,1435,1314,1333]" metricMagnitude="-2" metricUnit="kg" metricValue="1.09" pageId="5" pageNumber="177" unit="g" value="10.9">10.9 g</quantity>
|
||
) and chromatographed with CC method on silica gel with a mixtures of
|
||
<collectingCountry id="F33B7674FFB2FFC22933FA81FCECFA83" box="[818,847,1369,1388]" name="Switzerland" pageId="5" pageNumber="177">CH</collectingCountry>
|
||
<subScript id="17A834A1FFB2FFC2294EFABBFCFBFA80" attach="both" box="[847,856,1379,1391]" fontSize="5" pageId="5" pageNumber="177">2</subScript>
|
||
Cl
|
||
<subScript id="17A834A1FFB2FFC2296AFABBFCD7FA80" attach="left" box="[875,884,1379,1391]" fontSize="5" pageId="5" pageNumber="177">2</subScript>
|
||
and (
|
||
<collectingCountry id="F33B7674FFB2FFC229AAFA81FC69FA83" box="[939,970,1369,1388]" name="Switzerland" pageId="5" pageNumber="177">CH</collectingCountry>
|
||
<subScript id="17A834A1FFB2FFC229CBFABBFC70FA80" attach="left" box="[970,979,1379,1391]" fontSize="5" pageId="5" pageNumber="177">3</subScript>
|
||
)
|
||
<subScript id="17A834A1FFB2FFC229DAFABBFC47FA80" attach="right" box="[987,996,1379,1391]" fontSize="5" pageId="5" pageNumber="177">2</subScript>
|
||
CO (ratio 45:1, 35:1 and 10:1) as eluent. The result was the isolation of the following compounds: scoparone (
|
||
<emphasis id="B958EAF6FFB2FFC22F5AFAADFAC4FA67" bold="true" box="[1371,1383,1397,1416]" pageId="5" pageNumber="177">9</emphasis>
|
||
) (
|
||
<quantity id="4CD49B01FFB2FFC22F7CFAADFA6FFA66" box="[1405,1484,1397,1417]" metricMagnitude="-5" metricUnit="kg" metricValue="1.27" pageId="5" pageNumber="177" unit="mg" value="12.7">12.7 mg</quantity>
|
||
, amorphous solid), scopoletin (
|
||
<emphasis id="B958EAF6FFB2FFC22E52FA49FBCFFA4B" bold="true" box="[1107,1132,1425,1444]" pageId="5" pageNumber="177">10</emphasis>
|
||
) (
|
||
<quantity id="4CD49B01FFB2FFC22E83FA49FB71FA4A" box="[1154,1234,1425,1445]" metricMagnitude="-5" metricUnit="kg" metricValue="4.54" pageId="5" pageNumber="177" unit="mg" value="45.4">45.4 mg</quantity>
|
||
, m.p. 192–195 °C), umbelliferone (
|
||
<emphasis id="B958EAF6FFB2FFC22988FA75FC01FA2F" bold="true" box="[905,930,1453,1472]" pageId="5" pageNumber="177">11</emphasis>
|
||
) (
|
||
<quantity id="4CD49B01FFB2FFC229B9FA75FBABFA2E" box="[952,1032,1453,1473]" metricMagnitude="-5" metricUnit="kg" metricValue="6.37" pageId="5" pageNumber="177" unit="mg" value="63.7">63.7 mg</quantity>
|
||
, m.p. 230 °C), cynaropicrin (
|
||
<emphasis id="B958EAF6FFB2FFC22F1AFA75FA97FA2F" bold="true" box="[1307,1332,1453,1472]" pageId="5" pageNumber="177">12</emphasis>
|
||
) (
|
||
<quantity id="4CD49B01FFB2FFC22F4BFA75FA2EFA2E" box="[1354,1421,1453,1473]" metricMagnitude="-6" metricUnit="kg" metricValue="6.7" pageId="5" pageNumber="177" unit="mg" value="6.7">6.7 mg</quantity>
|
||
, amorphous solid) and desacylcynaropicrin 8α-(
|
||
<emphasis id="B958EAF6FFB2FFC22EDEFA11FB48FA33" bold="true" box="[1247,1259,1481,1500]" italics="true" pageId="5" pageNumber="177">Z</emphasis>
|
||
)-(4′-hydroxy-2′-methyl) butenoate (]cebellin F) (
|
||
<emphasis id="B958EAF6FFB2FFC22E26FA3DFBE3FA17" bold="true" box="[1063,1088,1509,1528]" pageId="5" pageNumber="177">13</emphasis>
|
||
) (
|
||
<quantity id="4CD49B01FFB2FFC22E57FA3DFB3AFA17" box="[1110,1177,1509,1528]" metricMagnitude="-6" metricUnit="kg" metricValue="3.9" pageId="5" pageNumber="177" unit="mg" value="3.9">3.9 mg</quantity>
|
||
, amorphous solid). NMR data in
|
||
<tableCitation id="C6AE035FFFB2FFC22933F9D9FC22F9FB" box="[818,897,1537,1556]" captionStart="Table 7" captionStartId="5.[100,150,897,913]" captionTargetPageId="5" captionText="Table 7 1H and13C NMR data of compounds 9-11." pageId="5" pageNumber="177">Tables 7</tableCitation>
|
||
and
|
||
<tableCitation id="C6AE035FFFB2FFC229B3F9D9FC1DF9FB" box="[946,958,1537,1556]" captionStart="Table 8" captionStartId="5.[818,868,161,177]" captionTargetPageId="5" captionText="Table 8 1H and13C NMR data of compounds 12 and 13 in DMSO-d6" pageId="5" pageNumber="177">8</tableCitation>
|
||
.
|
||
</paragraph>
|
||
</subSubSection>
|
||
</treatment>
|
||
</document> |