3004 lines
292 KiB
XML
3004 lines
292 KiB
XML
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<mods:title id="1E318007779A8E6B9E7130438E3695A3">Profiling of secondary metabolites in root exudates of Arabidopsis thaliana</mods:title>
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<mods:namePart id="5E429BBAC21CFA08F8622BF973897A8D">Strehmel, Nadine</mods:namePart>
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<mods:affiliation id="A813FC02201D9556D504C7B891A73C49">, & Leibniz Institute of Plant Biochemistry, Department of Stress and Developmental Biology, Weinberg 3, 06120 Halle (Saale), Germany</mods:affiliation>
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<mods:namePart id="758C097B753F83427386711F8FFA0BEF">Böttcher, Christoph</mods:namePart>
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<mods:namePart id="7AAE52E228FED247274F767127BDAD61">Schmidt, Stephan</mods:namePart>
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<mods:namePart id="64BC72D1526D791203357AB58248C257">Scheel, Dierk</mods:namePart>
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<mods:title id="B6E3081C69C0FFD7D61380B4A62C5106">Phytochemistry</mods:title>
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<mods:date id="E6D6D1AD1AF0DF5F6178C156E9E6B70A">2014</mods:date>
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<mods:number id="BB8C21BE76F6E7479F3DEB85ADF860BD">2014-12-31</mods:number>
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<mods:number id="DE75B78AC569F952CA03230AF1EAE1F7">108</mods:number>
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<treatment id="03C787EACE7F7B6BFFB1FE4AFB43FCDB" LSID="urn:lsid:plazi:treatment:03C787EACE7F7B6BFFB1FE4AFB43FCDB" httpUri="http://treatment.plazi.org/id/03C787EACE7F7B6BFFB1FE4AFB43FCDB" lastPageId="8" lastPageNumber="43" pageId="3" pageNumber="38">
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<subSubSection id="C3746577CE7F7B60FFB1FE4AFDD4FE47" box="[87,638,474,494]" pageId="3" pageNumber="38" type="nomenclature">
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<paragraph id="8BD136FCCE7F7B60FFB1FE4AFDD4FE47" blockId="3.[87,638,474,494]" box="[87,638,474,494]" pageId="3" pageNumber="38">
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<emphasis id="B91AEAEECE7F7B60FFB1FE4AFDD4FE47" box="[87,638,474,494]" italics="true" pageId="3" pageNumber="38">
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2.4. Compounds identified in root exudates of
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<taxonomicName id="4C6E4D7FCE7F7B60FDF3FE4AFDD4FE47" ID-CoL="G26R" box="[533,638,474,494]" class="Magnoliopsida" family="Brassicaceae" genus="Arabidopsis" kingdom="Plantae" order="Brassicales" pageId="3" pageNumber="38" phylum="Tracheophyta" rank="species" species="thaliana">A. thaliana</taxonomicName>
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</emphasis>
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<subSubSection id="C3746577CE7F7B6BFFB1FD82FB43FCDB" lastPageId="8" lastPageNumber="43" pageId="3" pageNumber="38" type="description">
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<paragraph id="8BD136FCCE7F7B60FFB1FD82FDBCFD8F" blockId="3.[87,757,530,1415]" box="[87,534,530,550]" pageId="3" pageNumber="38">
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<heading id="D0998190CE7F7B60FFB1FD82FDBCFD8F" box="[87,534,530,550]" fontSize="8" level="3" pageId="3" pageNumber="38" reason="8">
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<emphasis id="B91AEAEECE7F7B60FFB1FD82FDBCFD8F" box="[87,534,530,550]" italics="true" pageId="3" pageNumber="38">2.4.1. Nucleosides, amino acids and dipeptides</emphasis>
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</heading>
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</paragraph>
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<paragraph id="8BD136FCCE7F7B60FF90FDBFFE98FBFD" blockId="3.[87,757,530,1415]" pageId="3" pageNumber="38">
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Although the established method was not intended to target polar metabolites, several polar aromatic compounds including three nucleosides (
|
||
<emphasis id="B91AEAEECE7F7B60FEF1FDF7FE97FDD3" bold="true" box="[279,317,615,634]" pageId="3" pageNumber="38">1–3</emphasis>
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), two deoxynucleosides (
|
||
<emphasis id="B91AEAEECE7F7B60FDD9FDF7FDE6FDD3" bold="true" box="[575,588,615,634]" pageId="3" pageNumber="38">4</emphasis>
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||
,
|
||
<emphasis id="B91AEAEECE7F7B60FDB1FDF7FDCEFDD3" bold="true" box="[599,612,615,634]" pageId="3" pageNumber="38">5</emphasis>
|
||
), a nucleoside derivative (
|
||
<emphasis id="B91AEAEECE7F7B60FF2FFD12FF7CFD3C" bold="true" box="[201,214,642,661]" pageId="3" pageNumber="38">6</emphasis>
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||
) and the aromatic amino acids Phe (
|
||
<emphasis id="B91AEAEECE7F7B60FDA7FD13FDE4FD3F" bold="true" box="[577,590,643,662]" pageId="3" pageNumber="38">7</emphasis>
|
||
), Tyr (
|
||
<emphasis id="B91AEAEECE7F7B60FD68FD12FD31FD3C" bold="true" box="[654,667,642,661]" pageId="3" pageNumber="38">8</emphasis>
|
||
) and Trp (
|
||
<emphasis id="B91AEAEECE7F7B60FFB9FD0EFFC6FD18" bold="true" box="[95,108,670,689]" pageId="3" pageNumber="38">9</emphasis>
|
||
) were detected in root exudates of
|
||
<taxonomicName id="4C6E4D7FCE7F7B60FE28FD0DFD9EFD18" box="[462,564,669,689]" class="Magnoliopsida" family="Brassicaceae" genus="Arabidopsis" kingdom="Plantae" order="Brassicales" pageId="3" pageNumber="38" phylum="Tracheophyta" rank="species" species="thaliana">
|
||
<emphasis id="B91AEAEECE7F7B60FE28FD0DFD9EFD18" box="[462,564,669,689]" italics="true" pageId="3" pageNumber="38">A. thaliana</emphasis>
|
||
</taxonomicName>
|
||
. In addition, a simple β- carboline alkaloid (
|
||
<emphasis id="B91AEAEECE7F7B60FEB3FD2AFEC4FD64" bold="true" box="[341,366,698,717]" pageId="3" pageNumber="38">10</emphasis>
|
||
) previously reported to accumulate in tomato fruits (
|
||
<bibRefCitation id="EFFF4B0DCE7F7B60FF0CFD46FE0FFD40" author="Yahara, S. & Uda, N. & Yoshio, E. & Yae, E." box="[234,421,726,746]" pageId="3" pageNumber="38" pagination="500 - 502" refId="ref13834" refString="Yahara, S., Uda, N., Yoshio, E., Yae, E., 2004. Steroidal alkaloid glycosides from tomato (Lycopersicon esculentum). J. Nat. Prod. 67, 500 - 502." type="journal article" year="2004">Yahara et al., 2004</bibRefCitation>
|
||
) was identified using a synthetic reference compound prepared from Trp and formaldehyde (
|
||
<bibRefCitation id="EFFF4B0DCE7F7B60FD53FD62FF78FC88" author="Tilstra, L. & Sattler, M. C. & Cherry, W. R. & Barkley, M. D." pageId="3" pageNumber="38" pagination="9176 - 9182" refId="ref13537" refString="Tilstra, L., Sattler, M. C., Cherry, W. R., Barkley, M. D., 1990. Fluorescence of a rotationally constrained tryptophan derivative, 3 - carboxy- 1,2,3,4 - tetrahydro- 2 - carboline. J. Am. Chem. Soc. 112, 9176 - 9182." type="journal article" year="1990">Tilstra et al., 1990</bibRefCitation>
|
||
). While other proteinogenic amino acids were not detected using the established analytical method, the more hydrophobic side chain-elongated Met homologs (
|
||
<emphasis id="B91AEAEECE7F7B60FDC1FCD6FDEAFCF0" bold="true" box="[551,576,838,857]" pageId="3" pageNumber="38">11</emphasis>
|
||
,
|
||
<emphasis id="B91AEAEECE7F7B60FDA9FCD6FDC2FCF0" bold="true" box="[591,616,838,857]" pageId="3" pageNumber="38">12</emphasis>
|
||
) and their
|
||
<emphasis id="B91AEAEECE7F7B60FD07FCD5FD46FCF0" box="[737,748,837,857]" italics="true" pageId="3" pageNumber="38">S</emphasis>
|
||
- oxides (
|
||
<emphasis id="B91AEAEECE7F7B60FF4EFCF2FF6BFCDC" bold="true" box="[168,193,866,885]" pageId="3" pageNumber="38">13</emphasis>
|
||
,
|
||
<emphasis id="B91AEAEECE7F7B60FF28FCF2FF4DFCDC" bold="true" box="[206,231,866,885]" pageId="3" pageNumber="38">14</emphasis>
|
||
) were putatively identified based on the elemental composition, the presence of three exchangeable protons and the occurrence of characteristic neutral losses of 46.01 Da (HCOOH) and 48.00 Da (
|
||
<collectingCountry id="F379766CCE7F7B60FF0FFC26FEA3FC60" box="[233,265,950,969]" name="Switzerland" pageId="3" pageNumber="38">CH</collectingCountry>
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<subScript id="17EA34B9CE7F7B60FEEFFC2EFEB8FC63" attach="both" box="[265,274,958,970]" fontSize="5" pageId="3" pageNumber="38">3</subScript>
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SH)/64.00 Da (
|
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<collectingCountry id="F379766CCE7F7B60FE45FC26FE69FC60" box="[419,451,950,969]" name="Switzerland" pageId="3" pageNumber="38">CH</collectingCountry>
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<subScript id="17EA34B9CE7F7B60FE25FC2EFE66FC63" attach="both" box="[451,460,958,970]" fontSize="5" pageId="3" pageNumber="38">3</subScript>
|
||
SOH) in the CID mass spectra of the [M+H]
|
||
<superScript id="7C1B9BB4CE7F7B60FF01FC5EFF5AFC73" attach="left" box="[231,240,974,986]" fontSize="5" pageId="3" pageNumber="38">+</superScript>
|
||
ions. Compounds
|
||
<emphasis id="B91AEAEECE7F7B60FE58FC41FE54FC4D" bold="true" box="[446,510,977,997]" pageId="3" pageNumber="38">11–14</emphasis>
|
||
represent biosynthetic intermediates of corresponding ω- methylsulfinylalkyl/ω- methylthioalkyl glucosinolates of chain length 7 and 8 which are known constituents in roots of the accession Col-0 (
|
||
<bibRefCitation id="EFFF4B0DCE7F7B60FDCBFBB5FD5BFB91" author="Brown, P. D. & Tokuhisa, J. G. & Reichelt, M. & Gershenzon, J." box="[557,753,1061,1080]" pageId="3" pageNumber="38" pagination="471 - 481" refId="ref11119" refString="Brown, P. D., Tokuhisa, J. G., Reichelt, M., Gershenzon, J., 2003. Variation of glucosinolate accumulation among different organs and developmental stages of Arabidopsis thaliana. Phytochemistry 62, 471 - 481." type="journal article" year="2003">Brown et al., 2003</bibRefCitation>
|
||
;
|
||
<bibRefCitation id="EFFF4B0DCE7F7B60FFB1FBD1FE8EFBFD" author="Petersen, B. L. & Chen, S. & Hansen, C. H. & Olsen, C. E. & Halkier, B. A." box="[87,292,1089,1108]" pageId="3" pageNumber="38" pagination="562 - 571" refId="ref13096" refString="Petersen, B. L., Chen, S., Hansen, C. H., Olsen, C. E., Halkier, B. A., 2002. Composition and content of glucosinolates in developing Arabidopsis thaliana. Planta 214, 562 - 571." type="journal article" year="2002">Petersen et al., 2002</bibRefCitation>
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||
).
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE7F7B60FF90FBCDFE0CFA2E" blockId="3.[87,757,530,1415]" pageId="3" pageNumber="38">
|
||
Beside nucleosides and amino acids, an array of 20 dipeptides (
|
||
<emphasis id="B91AEAEECE7F7B60FFB9FBE9FF34FB25" bold="true" box="[95,158,1145,1164]" pageId="3" pageNumber="38">15–34</emphasis>
|
||
) composed of the amino acids Gly, Val, Leu, Ile, Pro, Phe and Tyr was identified in root exudates. Structural assignments are in agreement with the elemental composition, the number of exchangeable protons and the occurrence of characteristic y-type fragment ions upon CID of the [M+H]
|
||
<superScript id="7C1B9BB4CE7F7B60FE3CFB74FE49FB59" attach="left" box="[474,483,1252,1264]" fontSize="5" pageId="3" pageNumber="38">+</superScript>
|
||
ions. To discriminate Leufrom Ile-containing peptides, a total of 16 dipeptides were synthesized and used for authentication. The spectrum of dipeptides detected in root exudates matches the set of 14 dipeptides reported to accumulate in roots of
|
||
<taxonomicName id="4C6E4D7FCE7F7B60FE52FAC7FDB1FAC2" box="[436,539,1367,1387]" class="Magnoliopsida" family="Brassicaceae" genus="Arabidopsis" kingdom="Plantae" order="Brassicales" pageId="3" pageNumber="38" phylum="Tracheophyta" rank="species" species="thaliana">
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<emphasis id="B91AEAEECE7F7B60FE52FAC7FDB1FAC2" box="[436,539,1367,1387]" italics="true" pageId="3" pageNumber="38">A. thaliana</emphasis>
|
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</taxonomicName>
|
||
in a cell-type specific manner (
|
||
<bibRefCitation id="EFFF4B0DCE7F7B60FF53FAE4FE33FA2E" author="Moussaieff, A. & Rogachev, I. & Brodsky, L. & Malitsky, S. & Toal, T. W. & Belcher, H. & Yativ, M. & Brady, S. M. & Benfey, P. N. & Aharoni, A." box="[181,409,1396,1415]" pageId="3" pageNumber="38" pagination="1232 - 1241" refId="ref12825" refString="Moussaieff, A., Rogachev, I., Brodsky, L., Malitsky, S., Toal, T. W., Belcher, H., Yativ, M., Brady, S. M., Benfey, P. N., Aharoni, A., 2013. High-resolution metabolic mapping of cell types in plant roots. Proc. Natl. Acad. Sci. U. S. A. 110, E 1232 - 1241." type="journal article" year="2013">Moussaieff et al., 2013</bibRefCitation>
|
||
).
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE7F7B60FFB1FA28FD66FA65" blockId="3.[87,757,1464,2015]" box="[87,716,1464,1484]" pageId="3" pageNumber="38">
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<heading id="D0998190CE7F7B60FFB1FA28FD66FA65" box="[87,716,1464,1484]" fontSize="8" level="3" pageId="3" pageNumber="38" reason="8">
|
||
<emphasis id="B91AEAEECE7F7B60FFB1FA28FD66FA65" box="[87,716,1464,1484]" italics="true" pageId="3" pageNumber="38">2.4.2. Degradation products of methionine-derived glucosinolates</emphasis>
|
||
</heading>
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE7F7B60FF90FA45FA68FF4C" blockId="3.[87,757,1464,2015]" lastBlockId="3.[805,1474,182,230]" pageId="3" pageNumber="38">
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||
Met-derived glucosinolates are the predominating phytoanticipins in most organs of
|
||
<taxonomicName id="4C6E4D7FCE7F7B60FEDEFA60FE35F9AD" box="[312,415,1520,1540]" class="Magnoliopsida" family="Brassicaceae" genus="Arabidopsis" kingdom="Plantae" order="Brassicales" pageId="3" pageNumber="38" phylum="Tracheophyta" rank="species" species="thaliana">
|
||
<emphasis id="B91AEAEECE7F7B60FEDEFA60FE35F9AD" box="[312,415,1520,1540]" italics="true" pageId="3" pageNumber="38">A. thaliana</emphasis>
|
||
</taxonomicName>
|
||
. Despite their significant accumulation level in root tissue (
|
||
<bibRefCitation id="EFFF4B0DCE7F7B60FEB9F99EFDB3F989" author="Brown, P. D. & Tokuhisa, J. G. & Reichelt, M. & Gershenzon, J." box="[351,537,1549,1569]" pageId="3" pageNumber="38" pagination="471 - 481" refId="ref11119" refString="Brown, P. D., Tokuhisa, J. G., Reichelt, M., Gershenzon, J., 2003. Variation of glucosinolate accumulation among different organs and developmental stages of Arabidopsis thaliana. Phytochemistry 62, 471 - 481." type="journal article" year="2003">Brown et al., 2003</bibRefCitation>
|
||
;
|
||
<bibRefCitation id="EFFF4B0DCE7F7B60FDC5F99EFD46F989" author="Petersen, B. L. & Chen, S. & Hansen, C. H. & Olsen, C. E. & Halkier, B. A." box="[547,748,1549,1569]" pageId="3" pageNumber="38" pagination="562 - 571" refId="ref13096" refString="Petersen, B. L., Chen, S., Hansen, C. H., Olsen, C. E., Halkier, B. A., 2002. Composition and content of glucosinolates in developing Arabidopsis thaliana. Planta 214, 562 - 571." type="journal article" year="2002">Petersen et al., 2002</bibRefCitation>
|
||
) glucosinolates were not consistently detected in root exudates using the established experimental setup, which is in contrast to a previous study on root exudates of
|
||
<taxonomicName id="4C6E4D7FCE7F7B60FE1CF9F0FF65F939" authority="(Schreiner et al., 2011)" baseAuthorityName="Schreiner" baseAuthorityYear="2011" class="Magnoliopsida" family="Brassicaceae" genus="Brassica" kingdom="Plantae" order="Brassicales" pageId="3" pageNumber="38" phylum="Tracheophyta" rank="species" species="rapa">
|
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<emphasis id="B91AEAEECE7F7B60FE1CF9F0FD2BF9DD" box="[506,641,1632,1652]" italics="true" pageId="3" pageNumber="38">Brassica rapa</emphasis>
|
||
(
|
||
<bibRefCitation id="EFFF4B0DCE7F7B60FD70F9F1FF6CF939" author="Schreiner, M. & Krumbein, A. & Knorr, D. & Smetanska, I." pageId="3" pageNumber="38" pagination="1400 - 1405" refId="ref13388" refString="Schreiner, M., Krumbein, A., Knorr, D., Smetanska, I., 2011. Enhanced glucosinolates in root exudates of Brassica rapa ssp. rapa mediated by salicylic acid and methyl jasmonate. J. Agric. Food Chem. 59, 1400 - 1405." type="journal article" year="2011">Schreiner et al., 2011</bibRefCitation>
|
||
)
|
||
</taxonomicName>
|
||
. Instead of glucosinolates, a set of 8 putative glucosinolate degradation products (
|
||
<emphasis id="B91AEAEECE7F7B60FE91F909FE1CF905" bold="true" box="[375,438,1689,1708]" pageId="3" pageNumber="38">35–42</emphasis>
|
||
) derived from 8-methylthiooctyl, 8-methylsulfinyloctyl and 7-methylsulfinylheptyl gluco sinolate were identified based on the occurrence of characteristic neutral losses of 48.00 Da and 64.00 Da upon CID of the [M+H]
|
||
<superScript id="7C1B9BB4CE7F7B60FD0AF979FD5FF95C" attach="none" box="[748,757,1769,1781]" fontSize="5" pageId="3" pageNumber="38">+</superScript>
|
||
ions which are indicative for methylthio and methylsulfinyl moieties, respectively. Among them, classical glucosinolate breakdown products known to be produced upon tissue damage were found including two nitriles (
|
||
<emphasis id="B91AEAEECE7F7B60FEA7F8CCFEF0F8C6" bold="true" box="[321,346,1884,1903]" pageId="3" pageNumber="38">35</emphasis>
|
||
,
|
||
<emphasis id="B91AEAEECE7F7B60FE80F8CCFED5F8C6" bold="true" box="[358,383,1884,1903]" pageId="3" pageNumber="38">36</emphasis>
|
||
) and an isothiocyanate (
|
||
<emphasis id="B91AEAEECE7F7B60FD9AF8CCFD3FF8C6" bold="true" box="[636,661,1884,1903]" pageId="3" pageNumber="38">37</emphasis>
|
||
). Related to these compounds, a carboxylic acid (
|
||
<emphasis id="B91AEAEECE7F7B60FE16F8E8FDA3F822" bold="true" box="[496,521,1912,1931]" pageId="3" pageNumber="38">38</emphasis>
|
||
) and its amide (
|
||
<emphasis id="B91AEAEECE7F7B60FD50F8E8FD65F822" bold="true" box="[694,719,1912,1931]" pageId="3" pageNumber="38">39</emphasis>
|
||
) as well as three amines (
|
||
<emphasis id="B91AEAEECE7F7B60FEA2F803FE29F80F" bold="true" box="[324,387,1939,1959]" pageId="3" pageNumber="38">40–42</emphasis>
|
||
) were identified. It was suggested, that these compounds represent glucosinolate breakdown products, which are formed in intact tissue by either nitrilase-mediated hydrolysis of nitriles or by degradation of isothiocyanate–glutathione conjugates (
|
||
<bibRefCitation id="EFFF4B0DCE7F7B60FC2EFF42FB31FF4C" author="Bednarek, P. & Pislewska-Bednarek, M. & Svatos, A. & Schneider, B. & Doubsky, J. & Mansurova, M. & Humphry, M. & Consonni, C. & Panstruga, R. & Sanchez-Vallet, A. & Molina, A. & Schulze-Lefert, P." box="[968,1179,210,230]" pageId="3" pageNumber="38" pagination="101 - 106" refId="ref10822" refString="Bednarek, P., Pislewska-Bednarek, M., Svatos, A., Schneider, B., Doubsky, J., Mansurova, M., Humphry, M., Consonni, C., Panstruga, R., Sanchez-Vallet, A., Molina, A., Schulze-Lefert, P., 2009. A glucosinolate metabolism pathway in living plant cells mediates broad-spectrum antifungal defense. Science 323, 101 - 106." type="journal article" year="2009">Bednarek et al., 2009</bibRefCitation>
|
||
;
|
||
<bibRefCitation id="EFFF4B0DCE7F7B60FB42FF42FA1EFF4C" author="Wittstock, U. & Burow, M." box="[1188,1460,210,230]" pageId="3" pageNumber="38" pagination="0134" refId="ref13803" refString="Wittstock, U., Burow, M., 2010. Glucosinolate breakdown in Arabidopsis: mechanism, regulation and biological significance. Arabidopsis Book 8, e 0134." type="journal article" year="2010">Wittstock and Burow, 2010</bibRefCitation>
|
||
).
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE7F7B60FCC3FE99FBB9FE90" blockId="3.[805,1475,265,1262]" pageId="3" pageNumber="38">
|
||
<heading id="D0998190CE7F7B60FCC3FE99FBB9FE90" centered="true" fontSize="8" level="3" pageId="3" pageNumber="38" reason="8">
|
||
<emphasis id="B91AEAEECE7F7B60FCC3FE99FBB9FE90" italics="true" pageId="3" pageNumber="38">2.4.3. Degradation products of tryptophan-derived glucosinolates and other indolic compounds</emphasis>
|
||
</heading>
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE7F7B60FCA2FED2FCCEFC5B" blockId="3.[805,1475,265,1262]" pageId="3" pageNumber="38">
|
||
In addition to aliphatic glucosinolates indolic glucosinolates accumulate in
|
||
<taxonomicName id="4C6E4D7FCE7F7B60FC5EFECDFBB4FED8" box="[952,1054,349,369]" class="Magnoliopsida" family="Brassicaceae" genus="Arabidopsis" kingdom="Plantae" order="Brassicales" pageId="3" pageNumber="38" phylum="Tracheophyta" rank="species" species="thaliana">
|
||
<emphasis id="B91AEAEECE7F7B60FC5EFECDFBB4FED8" box="[952,1054,349,369]" italics="true" pageId="3" pageNumber="38">A. thaliana</emphasis>
|
||
</taxonomicName>
|
||
and, in particular in roots, relatively large amounts of these compounds are found (
|
||
<bibRefCitation id="EFFF4B0DCE7F7B60FB32FEEAFA39FE24" author="Brown, P. D. & Tokuhisa, J. G. & Reichelt, M. & Gershenzon, J." box="[1236,1427,377,397]" pageId="3" pageNumber="38" pagination="471 - 481" refId="ref11119" refString="Brown, P. D., Tokuhisa, J. G., Reichelt, M., Gershenzon, J., 2003. Variation of glucosinolate accumulation among different organs and developmental stages of Arabidopsis thaliana. Phytochemistry 62, 471 - 481." type="journal article" year="2003">Brown et al., 2003</bibRefCitation>
|
||
). As observed for Met-derived glucosinolates, the major Trp-derived glucosinolates of roots (indol-3-yl methyl, 4-methoxy and 1-methoxyindol-3-yl methyl glucosinolate) were absent in root exudates. Again, corresponding degradation products including indol-3- ylmethyl amine (
|
||
<emphasis id="B91AEAEECE7F7B60FC36FD95FC43FDB1" bold="true" box="[976,1001,517,536]" pageId="3" pageNumber="38">43</emphasis>
|
||
), its 4-methoxy (
|
||
<emphasis id="B91AEAEECE7F7B60FB71FD95FB1AFDB1" bold="true" box="[1175,1200,517,536]" pageId="3" pageNumber="38">44</emphasis>
|
||
) and 1-methoxy derivative (
|
||
<emphasis id="B91AEAEECE7F7B60FCCBFDB1FCECFD9D" bold="true" box="[813,838,545,564]" pageId="3" pageNumber="38">45</emphasis>
|
||
) were detected. Here, isomers
|
||
<emphasis id="B91AEAEECE7F7B60FB64FDB1FB31FD9D" bold="true" box="[1154,1179,545,564]" pageId="3" pageNumber="38">44</emphasis>
|
||
and
|
||
<emphasis id="B91AEAEECE7F7B60FB28FDB1FB4DFD9D" bold="true" box="[1230,1255,545,564]" pageId="3" pageNumber="38">45</emphasis>
|
||
can be discriminated based on the number of exchangeable protons determined for the dominating [M+H-NH
|
||
<subScript id="17EA34B9CE7F7B60FBE3FDF2FBA4FDC7" attach="left" box="[1029,1038,610,622]" fontSize="5" pageId="3" pageNumber="38">3</subScript>
|
||
]
|
||
<superScript id="7C1B9BB4CE7F7B60FBF0FDC5FBB5FDC8" attach="none" box="[1046,1055,597,609]" fontSize="5" pageId="3" pageNumber="38">+</superScript>
|
||
-
|
||
<typeStatus id="54D5885ECE7F7B60FBC0FDC9FBFEFDC5" box="[1062,1108,601,620]" pageId="3" pageNumber="38">type</typeStatus>
|
||
in-source fragment ion. Amine
|
||
<emphasis id="B91AEAEECE7F7B60FA4FFDC9FA68FDC5" bold="true" box="[1449,1474,601,620]" pageId="3" pageNumber="38">43</emphasis>
|
||
was recently identified as a product of the atypical myrosinase PENETRATION2 (
|
||
<emphasis id="B91AEAEECE7F7B60FC30FD1FFB94FD0A" box="[982,1086,655,675]" italics="true" pageId="3" pageNumber="38">
|
||
At
|
||
<quantity id="4C969B19CE7F7B60FC0DFD1FFBAEFD0A" box="[1003,1028,655,675]" metricMagnitude="-3" metricUnit="kg" metricValue="2.0" pageId="3" pageNumber="38" unit="g" value="2.0">2g</quantity>
|
||
44490
|
||
</emphasis>
|
||
) which is involved in an inducible pre-invasion resistance mechanism conferring broad-spectrum resistance to fungal pathogens (
|
||
<bibRefCitation id="EFFF4B0DCE7F7B60FB8CFD58FAE9FD72" author="Bednarek, P. & Pislewska-Bednarek, M. & Svatos, A. & Schneider, B. & Doubsky, J. & Mansurova, M. & Humphry, M. & Consonni, C. & Panstruga, R. & Sanchez-Vallet, A. & Molina, A. & Schulze-Lefert, P." box="[1130,1347,712,732]" pageId="3" pageNumber="38" pagination="101 - 106" refId="ref10822" refString="Bednarek, P., Pislewska-Bednarek, M., Svatos, A., Schneider, B., Doubsky, J., Mansurova, M., Humphry, M., Consonni, C., Panstruga, R., Sanchez-Vallet, A., Molina, A., Schulze-Lefert, P., 2009. A glucosinolate metabolism pathway in living plant cells mediates broad-spectrum antifungal defense. Science 323, 101 - 106." type="journal article" year="2009">Bednarek et al., 2009</bibRefCitation>
|
||
;
|
||
<bibRefCitation id="EFFF4B0DCE7F7B60FAA8FD58FCFDFD5E" author="Lipka, V. & Dittgen, J. & Bednarek, P. & Bhat, R. & Wiermer, M. & Stein, M. & Landtag, J. & Brandt, W. & Rosahl, S. & Scheel, D. & Llorente, F. & Molina, A. & Parker, J. & Somerville, S. & Schulze-Lefert, P." pageId="3" pageNumber="38" pagination="1180 - 1183" refId="ref12194" refString="Lipka, V., Dittgen, J., Bednarek, P., Bhat, R., Wiermer, M., Stein, M., Landtag, J., Brandt, W., Rosahl, S., Scheel, D., Llorente, F., Molina, A., Parker, J., Somerville, S., Schulze-Lefert, P., 2005. Pre- and postinvasion defenses both contribute to nonhost resistance in Arabidopsis. Science 310, 1180 - 1183." type="journal article" year="2005">Lipka et al., 2005</bibRefCitation>
|
||
). In addition, further indolic compounds were identified in root exudates including indole-3-carbaldehyde (
|
||
<emphasis id="B91AEAEECE7F7B60FAE9FC90FA82FCBA" bold="true" box="[1295,1320,768,787]" pageId="3" pageNumber="38">46</emphasis>
|
||
), 4-hydroxyindole-3-carbaldehyde (
|
||
<emphasis id="B91AEAEECE7F7B60FBE1FC8CFB8AFC86" bold="true" box="[1031,1056,796,815]" pageId="3" pageNumber="38">47</emphasis>
|
||
), indole-3-carboxylic acid (
|
||
<emphasis id="B91AEAEECE7F7B60FAA7FC8CFAF0FC86" bold="true" box="[1345,1370,796,815]" pageId="3" pageNumber="38">48</emphasis>
|
||
), a malonyl-glucoside of 6-hydroxyindole-3-carboxylic acid (
|
||
<emphasis id="B91AEAEECE7F7B60FAAAFCA8FACFFCE2" bold="true" box="[1356,1381,824,843]" pageId="3" pageNumber="38">49</emphasis>
|
||
) and an unknown indole derivative (
|
||
<emphasis id="B91AEAEECE7F7B60FBBCFCC4FBD9FCCE" bold="true" box="[1114,1139,852,871]" pageId="3" pageNumber="38">50</emphasis>
|
||
). Compounds
|
||
<emphasis id="B91AEAEECE7F7B60FAF3FCC4FAFEFCCE" bold="true" box="[1301,1364,852,871]" pageId="3" pageNumber="38">46–49</emphasis>
|
||
represent known metabolites which constitutively accumulate (in case of
|
||
<emphasis id="B91AEAEECE7F7B60FCC3FC1BFC94FC37" bold="true" box="[805,830,907,926]" pageId="3" pageNumber="38">47</emphasis>
|
||
and
|
||
<emphasis id="B91AEAEECE7F7B60FC96FC1BFC23FC37" bold="true" box="[880,905,907,926]" pageId="3" pageNumber="38">48</emphasis>
|
||
as glucose conjugates) in leaf and root tissue of
|
||
<taxonomicName id="4C6E4D7FCE7F7B60FA93FC1AFCE3FC13" class="Magnoliopsida" family="Brassicaceae" genus="Arabidopsis" kingdom="Plantae" order="Brassicales" pageId="3" pageNumber="38" phylum="Tracheophyta" rank="species" species="thaliana">
|
||
<emphasis id="B91AEAEECE7F7B60FA93FC1AFCE3FC13" italics="true" pageId="3" pageNumber="38">A. thaliana</emphasis>
|
||
</taxonomicName>
|
||
and exhibit a pathogen-inducible accumulation pattern (
|
||
<bibRefCitation id="EFFF4B0DCE7F7B60FCCBFC53FBB8FC7F" author="Bednarek, P. & Schneider, B. & Svatos, A. & Oldham, N. J. & Hahlbrock, K." box="[813,1042,963,983]" pageId="3" pageNumber="38" pagination="1058 - 1070" refId="ref10904" refString="Bednarek, P., Schneider, B., Svatos, A., Oldham, N. J., Hahlbrock, K., 2005. Structural complexity, differential response to infection, and tissue specificity of indolic and phenylpropanoid secondary metabolism in Arabidopsis roots. Plant Physiol. 138, 1058 - 1070." type="journal article" year="2005">Bednarek et al., 2005</bibRefCitation>
|
||
;
|
||
<bibRefCitation id="EFFF4B0DCE7F7B60FBC4FC53FB55FC7F" author="Bottcher, C. & Chapman, A. & Fellermeier, F. & Choudhary, M. & Scheel, D. & Glawischnig, E." box="[1058,1279,963,983]" pageId="3" pageNumber="38" pagination="841 - 853" refId="ref11013" refString="Bottcher, C., Chapman, A., Fellermeier, F., Choudhary, M., Scheel, D., Glawischnig, E., 2014. The biosynthetic pathway of indole- 3 - carbaldehyde and indole- 3 - carboxylic acid derivatives in Arabidopsis. Plant Physiol. 165, 841 - 853." type="journal article" year="2014">Bottcher et al., 2014</bibRefCitation>
|
||
;
|
||
<bibRefCitation id="EFFF4B0DCE7F7B60FAE9FC53FCFDFC5B" author="Hagemeier, J. & Schneider, B. & Oldham, N. J. & Hahlbrock, K." pageId="3" pageNumber="38" pagination="753 - 758" refId="ref11669" refString="Hagemeier, J., Schneider, B., Oldham, N. J., Hahlbrock, K., 2001. Accumulation of soluble and wall-bound indolic metabolites in Arabidopsis thaliana leaves infected with virulent or avirulent Pseudomonas syringae pathovar tomato strains. Proc. Natl. Acad. Sci. U. S. A. 98, 753 - 758." type="journal article" year="2001">Hagemeier et al., 2001</bibRefCitation>
|
||
).
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE7F7B60FCA2FC6CFB50FB47" blockId="3.[805,1475,265,1262]" pageId="3" pageNumber="38">
|
||
It should be noted that camalexin, the major indolic phytoalexin of
|
||
<taxonomicName id="4C6E4D7FCE7F7B60FCD9FB86FC02FB83" box="[831,936,1046,1066]" class="Magnoliopsida" family="Brassicaceae" genus="Arabidopsis" kingdom="Plantae" order="Brassicales" pageId="3" pageNumber="38" phylum="Tracheophyta" rank="species" species="thaliana">
|
||
<emphasis id="B91AEAEECE7F7B60FCD9FB86FC02FB83" box="[831,936,1046,1066]" italics="true" pageId="3" pageNumber="38">A. thaliana</emphasis>
|
||
</taxonomicName>
|
||
, was not detected as root exudate in sterile nutrient solutions. In accordance to literature data describing the exudation of this phytoalexin following treatment with a conserved 22- amino-acid peptide from bacterial flagellin (flg22) (
|
||
<bibRefCitation id="EFFF4B0DCE7F7B60FAA5FBFBFCFDFB33" author="Millet, Y. A. & Danna, C. H. & Clay, N. K. & Songnuan, W. & Simon, M. D. & Werck-Reichhart, D. & Ausubel, F. M." pageId="3" pageNumber="38" pagination="973 - 990" refId="ref12592" refString="Millet, Y. A., Danna, C. H., Clay, N. K., Songnuan, W., Simon, M. D., Werck-Reichhart, D., Ausubel, F. M., 2010. Innate immune responses activated in Arabidopsis roots by microbe-associated molecular patterns. Plant Cell 22, 973 - 990." type="journal article" year="2010">Millet et al., 2010</bibRefCitation>
|
||
), camalexin became clearly detectable when analyzing microbially contaminated nutrient solutions. This suggests that the camalexin level could be used as an additional marker to judge the sterility of the hydroponic culture system.
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE7F7B60FCC3FA81FA9DFA8C" blockId="3.[805,1475,1297,2015]" box="[805,1335,1297,1317]" pageId="3" pageNumber="38">
|
||
<heading id="D0998190CE7F7B60FCC3FA81FA9DFA8C" box="[805,1335,1297,1317]" fontSize="8" level="3" pageId="3" pageNumber="38" reason="8">
|
||
<emphasis id="B91AEAEECE7F7B60FCC3FA81FA9DFA8C" box="[805,1335,1297,1317]" italics="true" pageId="3" pageNumber="38">2.4.4. Salicylic and jasmonic acid degradation products</emphasis>
|
||
</heading>
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE7F7B60FCA2FABEFA68F877" blockId="3.[805,1475,1297,2015]" pageId="3" pageNumber="38">
|
||
Based on their elemental composition and the occurrence of consecutive neutral losses of 132.04 Da (C
|
||
<subScript id="17EA34B9CE7F7B60FB0EFAC3FB5BFAF6" attach="both" box="[1256,1265,1363,1375]" fontSize="5" pageId="3" pageNumber="38">5</subScript>
|
||
H
|
||
<subScript id="17EA34B9CE7F7B60FAE4FAC3FAA1FAF6" attach="both" box="[1282,1291,1363,1375]" fontSize="5" pageId="3" pageNumber="38">8</subScript>
|
||
O
|
||
<subScript id="17EA34B9CE7F7B60FAFDFAC3FA8EFAF6" attach="left" box="[1307,1316,1363,1375]" fontSize="5" pageId="3" pageNumber="38">4</subScript>
|
||
) and 43.99 Da (CO
|
||
<subScript id="17EA34B9CE7F7B60FCAFFAFFFCF8FAD2" attach="left" box="[841,850,1391,1403]" fontSize="5" pageId="3" pageNumber="38">2</subScript>
|
||
) upon CID of the [M
|
||
<emphasis id="B91AEAEECE7F7B60FBCCFAF5FB91FAD0" box="[1066,1083,1381,1401]" italics="true" pageId="3" pageNumber="38">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE7F7B60FBB5FAF1FBF5FAC7" box="[1107,1119,1377,1390]" italics="true" pageId="3" pageNumber="38">
|
||
<superScript id="7C1B9BB4CE7F7B60FBB5FAF1FBF5FAC7" attach="left" box="[1107,1119,1377,1390]" fontSize="5" pageId="3" pageNumber="38">–</superScript>
|
||
</emphasis>
|
||
ions, two exuded compounds (
|
||
<emphasis id="B91AEAEECE7F7B60FA42FAF6FA17FAD0" bold="true" box="[1444,1469,1382,1401]" pageId="3" pageNumber="38">51</emphasis>
|
||
,
|
||
<emphasis id="B91AEAEECE7F7B60FCC3FA11FC94FA3D" bold="true" box="[805,830,1409,1428]" pageId="3" pageNumber="38">52</emphasis>
|
||
) were annotated as dihydroxybenzoic acid (DHBA) pentosides. Pentoside
|
||
<emphasis id="B91AEAEECE7F7B60FC76FA0DFC03FA19" bold="true" box="[912,937,1437,1456]" pageId="3" pageNumber="38">51</emphasis>
|
||
was identified as 2,3-DHBA 3-
|
||
<emphasis id="B91AEAEECE7F7B60FB08FA0CFB57FA19" box="[1262,1277,1436,1456]" italics="true" pageId="3" pageNumber="38">O</emphasis>
|
||
-β- D- xyloside using an authenticated standard (
|
||
<bibRefCitation id="EFFF4B0DCE7F7B60FBDAFA29FB56FA65" author="Bartsch, M. & Bednarek, P. & Vivancos, P. D. & Schneider, B. & von Roepenack-Lahaye, E. & Foyer, C. H. & Kombrink, E. & Scheel, D. & Parker, J. E." box="[1084,1276,1465,1485]" pageId="3" pageNumber="38" pagination="25654 - 25665" refId="ref10736" refString="Bartsch, M., Bednarek, P., Vivancos, P. D., Schneider, B., von Roepenack-Lahaye, E., Foyer, C. H., Kombrink, E., Scheel, D., Parker, J. E., 2010. Accumulation of isochorismate-derived 2,3 - dihydroxybenzoic 3 - O-beta-D- xyloside in Arabidopsis resistance to pathogens and ageing of leaves. J. Biol. Chem. 285, 25654 - 25665." type="journal article" year="2010">Bartsch et al., 2010</bibRefCitation>
|
||
) whereas the other was annotated as 2,5-DHBA conjugate based on acid-catalyzed hydrolysis experiments. As recently shown, both DHBA pentosides represent the major salicylic acid catabolites in young and senescent
|
||
<taxonomicName id="4C6E4D7FCE7F7B60FCBCF9B8FC6CF995" box="[858,966,1576,1596]" class="Magnoliopsida" family="Brassicaceae" genus="Arabidopsis" kingdom="Plantae" order="Brassicales" pageId="3" pageNumber="38" phylum="Tracheophyta" rank="species" species="thaliana">
|
||
<emphasis id="B91AEAEECE7F7B60FCBCF9B8FC6CF995" box="[858,966,1576,1596]" italics="true" pageId="3" pageNumber="38">A. thaliana</emphasis>
|
||
</taxonomicName>
|
||
rosette leaves (
|
||
<bibRefCitation id="EFFF4B0DCE7F7B60FB95F9B9FA98F995" author="Zhang, K. & Halitschke, R. & Yin, C. & Liu, C. J. & Gan, S. S." box="[1139,1330,1577,1597]" pageId="3" pageNumber="38" pagination="14807 - 14812" refId="ref13948" refString="Zhang, K., Halitschke, R., Yin, C., Liu, C. J., Gan, S. S., 2013. Salicylic acid 3 - hydroxylase regulates Arabidopsis leaf longevity by mediating salicylic acid catabolism. Proc. Natl. Acad. Sci. U. S. A. 110, 14807 - 14812." type="journal article" year="2013">Zhang et al., 2013</bibRefCitation>
|
||
). In addition, another plant hormone catabolite (
|
||
<emphasis id="B91AEAEECE7F7B60FB68F9D5FB0DF9F1" bold="true" box="[1166,1191,1605,1624]" pageId="3" pageNumber="38">53</emphasis>
|
||
) was detected in root exudates (Supplementary Fig. 5A). The CID mass spectrum obtained from the [M
|
||
<emphasis id="B91AEAEECE7F7B60FC44F9ECFC19F939" box="[930,947,1660,1680]" italics="true" pageId="3" pageNumber="38">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE7F7B60FC2DF9E8FC7DF92C" box="[971,983,1656,1669]" italics="true" pageId="3" pageNumber="38">
|
||
<superScript id="7C1B9BB4CE7F7B60FC2DF9E8FC7DF92C" attach="left" box="[971,983,1656,1669]" fontSize="5" pageId="3" pageNumber="38">–</superScript>
|
||
</emphasis>
|
||
ion of
|
||
<emphasis id="B91AEAEECE7F7B60FBC4F9EDFB91F939" bold="true" box="[1058,1083,1661,1680]" pageId="3" pageNumber="38">53</emphasis>
|
||
exhibited a prominent neutral loss of 79.96 Da (SO
|
||
<subScript id="17EA34B9CE7F7B60FC4DF932FC1EF907" attach="left" box="[939,948,1698,1710]" fontSize="5" pageId="3" pageNumber="38">3</subScript>
|
||
) and a corresponding fragment ion at
|
||
<emphasis id="B91AEAEECE7F7B60FABDF908FAC4F905" box="[1371,1390,1688,1708]" italics="true" pageId="3" pageNumber="38">m</emphasis>
|
||
/
|
||
<emphasis id="B91AEAEECE7F7B60FA93F908FAD5F905" box="[1397,1407,1688,1708]" italics="true" pageId="3" pageNumber="38">z</emphasis>
|
||
96.96 (HSO
|
||
<subScript id="17EA34B9CE7F7B60FCBEF92EFCCBF963" attach="left" box="[856,865,1726,1738]" fontSize="5" pageId="3" pageNumber="38">4</subScript>
|
||
<emphasis id="B91AEAEECE7F7B60FCBEF920FCCEF914" box="[856,868,1712,1725]" italics="true" pageId="3" pageNumber="38">
|
||
<superScript id="7C1B9BB4CE7F7B60FCBEF920FCCEF914" attach="left" box="[856,868,1712,1725]" fontSize="5" pageId="3" pageNumber="38">–</superScript>
|
||
</emphasis>
|
||
) indicating the presence of a sulfate moiety (Supplementary Fig. 5B). The elemental composition of
|
||
<emphasis id="B91AEAEECE7F7B60FB5AF940FB7FF94A" bold="true" box="[1212,1237,1744,1763]" pageId="3" pageNumber="38">53</emphasis>
|
||
was determined to be C
|
||
<subScript id="17EA34B9CE7F7B60FCD4F965FCEEF8A8" attach="both" box="[818,836,1781,1793]" fontSize="5" pageId="3" pageNumber="38">12</subScript>
|
||
H
|
||
<subScript id="17EA34B9CE7F7B60FCB3F965FCCDF8A8" attach="right" box="[853,871,1781,1793]" fontSize="5" pageId="3" pageNumber="38">20</subScript>
|
||
O
|
||
<subScript id="17EA34B9CE7F7B60FC91F966FC2AF8AB" attach="both" box="[887,896,1782,1794]" fontSize="5" pageId="3" pageNumber="38">7</subScript>
|
||
S suggesting that this compound might represent a sulfated dihydro-hydroxyjasmonic acid derivative. To prove this hypothesis,
|
||
<taxonomicName id="4C6E4D7FCE7F7B60FC7AF8B3FBA8F89E" box="[924,1026,1827,1847]" class="Magnoliopsida" family="Brassicaceae" genus="Arabidopsis" kingdom="Plantae" order="Brassicales" pageId="3" pageNumber="38" phylum="Tracheophyta" rank="species" species="thaliana">
|
||
<emphasis id="B91AEAEECE7F7B60FC7AF8B3FBA8F89E" box="[924,1026,1827,1847]" italics="true" pageId="3" pageNumber="38">A. thaliana</emphasis>
|
||
</taxonomicName>
|
||
seedlings were grown in liquid culture, treated for 24 h with [2-D
|
||
<subScript id="17EA34B9CE7F7B60FBE3F8D9FBA4F8FC" attach="left" box="[1029,1038,1865,1877]" fontSize="5" pageId="3" pageNumber="38">2</subScript>
|
||
]-jasmonic acid, extracted and analyzed by UPLC/ESI-QTOFMS. Following this treatment,
|
||
<emphasis id="B91AEAEECE7F7B60FB0AF8CCFAAFF8C6" bold="true" box="[1260,1285,1884,1903]" pageId="3" pageNumber="38">53</emphasis>
|
||
and its deuterated isotopolgue became detectable (Supplementary Fig. 5C). On-line H/ D exchange experiments revealed the presence of two exchangeable protons (Supplementary Fig. 5D). Thus, compound
|
||
<emphasis id="B91AEAEECE7F7B60FA94F83FFA21F86B" bold="true" box="[1394,1419,1967,1986]" pageId="3" pageNumber="38">53</emphasis>
|
||
possesses a saturated side chain and a ring keto group rather than
|
||
</paragraph>
|
||
<caption id="DF116674CE787B67FF8DFFE3FF15FF06" pageId="4" pageNumber="39" startId="4.[107,151,115,129]" targetBox="[130,1843,195,1448]" targetIsTable="true" targetPageId="4">
|
||
<paragraph id="8BD136FCCE787B67FF8DFFE3FF15FF06" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FF8DFFE3FF0DFF28" bold="true" box="[107,167,115,129]" pageId="4" pageNumber="39">Table 1</emphasis>
|
||
Annotated compounds reproducibly detected by UPLC/ESI-QTOFMS in solid-phase extracted nutrient solution of hydroponically grown
|
||
<emphasis id="B91AEAEECE787B67FB76FF19FA83FF31" box="[1168,1321,137,152]" italics="true" pageId="4" pageNumber="39">Arabidopsis thaliana</emphasis>
|
||
Col-0. Nutrient solution was collected overaone-week period from six-week-old plants.
|
||
</paragraph>
|
||
</caption>
|
||
<paragraph id="8BD136FCCE787B67FF64FF57FA47FA0F" pageId="4" pageNumber="39">
|
||
<table id="F96EC45CCE78849CFF64FF53F899FA01" box="[130,1843,195,1448]" colsContinueIn="5.[130,1914,126,1422]" gridcols="9" gridrows="53" pageId="4" pageNumber="39">
|
||
<tr id="355E34BECE78849CFF64FF53F899FF5E" box="[130,1843,195,247]" gridrow="0" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FF53FF34FF5E" box="[130,158,195,247]" gridcol="0" gridrow="0" pageId="4" pageNumber="39">No.</th>
|
||
<th id="768F5DC2CE78849CFF51FF53FDACFF5E" box="[183,518,195,247]" gridcol="1" gridrow="0" pageId="4" pageNumber="39">Compound</th>
|
||
<th id="768F5DC2CE78849CFD9EFF53FD24FF5E" box="[632,654,195,247]" gridcol="2" gridrow="0" pageId="4" pageNumber="39">vl1</th>
|
||
<th id="768F5DC2CE78849CFD43FF53FD6EFF5E" box="[677,708,195,247]" gridcol="3" gridrow="0" pageId="4" pageNumber="39">tr [s]</th>
|
||
<th id="768F5DC2CE78849CFD18FF53FCC8FF5E" box="[766,866,195,247]" gridcol="4" gridrow="0" pageId="4" pageNumber="39">Elemental composition</th>
|
||
<th id="768F5DC2CE78849CFC2BFF53FB95FF5E" box="[973,1087,195,247]" gridcol="5" gridrow="0" pageId="4" pageNumber="39">Quantifier ion Type</th>
|
||
<th id="768F5DC2CE78849CFBB6FF53FB22FF5E" box="[1104,1160,195,247]" gridcol="6" gridrow="0" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FBB6FF78FBF5FF5E" box="[1104,1119,232,247]" italics="true" pageId="4" pageNumber="39">m</emphasis>
|
||
/
|
||
<emphasis id="B91AEAEECE787B67FB80FF78FBC4FF5E" box="[1126,1134,232,247]" italics="true" pageId="4" pageNumber="39">z</emphasis>
|
||
</th>
|
||
<th id="768F5DC2CE78849CFB78FF53FA95FF5E" box="[1182,1343,195,247]" gridcol="7" gridrow="0" pageId="4" pageNumber="39"># exchang. protons2</th>
|
||
<th id="768F5DC2CE78849CFAB1FF53F899FF5E" box="[1367,1843,195,247]" gridcol="8" gridrow="0" pageId="4" pageNumber="39">
|
||
Observed fragment ions upon CID3
|
||
<emphasis id="B91AEAEECE787B67FABAFF4DFAC1FF45" box="[1372,1387,221,236]" italics="true" pageId="4" pageNumber="39">m</emphasis>
|
||
/
|
||
<emphasis id="B91AEAEECE787B67FA94FF4DFAD0FF45" box="[1394,1402,221,236]" italics="true" pageId="4" pageNumber="39">z</emphasis>
|
||
, precursor ion marked in bold
|
||
</th>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FE97F899FEB2" box="[130,1843,263,283]" gridrow="1" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FE97FF34FEB2" box="[130,158,263,283]" gridcol="0" gridrow="1" pageId="4" pageNumber="39">1</th>
|
||
<td id="768F5DC2CE78849CFF51FE97FDACFEB2" box="[183,518,263,283]" gridcol="1" gridrow="1" pageId="4" pageNumber="39">Adenosine</td>
|
||
<td id="768F5DC2CE78849CFD9EFE97FD24FEB2" box="[632,654,263,283]" gridcol="2" gridrow="1" pageId="4" pageNumber="39">S</td>
|
||
<td id="768F5DC2CE78849CFD43FE97FD6EFEB2" box="[677,708,263,283]" gridcol="3" gridrow="1" pageId="4" pageNumber="39">44</td>
|
||
<td id="768F5DC2CE78849CFD18FE97FCC8FEB2" box="[766,866,263,283]" gridcol="4" gridrow="1" pageId="4" pageNumber="39">C10H13N5O4</td>
|
||
<td id="768F5DC2CE78849CFC2BFE97FB95FEB2" box="[973,1087,263,283]" gridcol="5" gridrow="1" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FE97FB22FEB2" box="[1104,1160,263,283]" gridcol="6" gridrow="1" pageId="4" pageNumber="39">268.10</td>
|
||
<td id="768F5DC2CE78849CFB78FE97FA95FEB2" box="[1182,1343,263,283]" gridcol="7" gridrow="1" pageId="4" pageNumber="39">5</td>
|
||
<td id="768F5DC2CE78849CFAB1FE97F899FEB2" box="[1367,1843,263,283]" gridcol="8" gridrow="1" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FE9AFADCFEB1" bold="true" box="[1367,1398,266,280]" pageId="4" pageNumber="39">268</emphasis>
|
||
, 136
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FE8CF899FE9B" box="[130,1843,284,306]" gridrow="2" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FE8CFF34FE9B" box="[130,158,284,306]" gridcol="0" gridrow="2" pageId="4" pageNumber="39">2</th>
|
||
<td id="768F5DC2CE78849CFF51FE8CFDACFE9B" box="[183,518,284,306]" gridcol="1" gridrow="2" pageId="4" pageNumber="39">Guanosine</td>
|
||
<td id="768F5DC2CE78849CFD9EFE8CFD24FE9B" box="[632,654,284,306]" gridcol="2" gridrow="2" pageId="4" pageNumber="39">S</td>
|
||
<td id="768F5DC2CE78849CFD43FE8CFD6EFE9B" box="[677,708,284,306]" gridcol="3" gridrow="2" pageId="4" pageNumber="39">46</td>
|
||
<td id="768F5DC2CE78849CFD18FE8CFCC8FE9B" box="[766,866,284,306]" gridcol="4" gridrow="2" pageId="4" pageNumber="39">C10H13N5O5</td>
|
||
<td id="768F5DC2CE78849CFC2BFE8CFB95FE9B" box="[973,1087,284,306]" gridcol="5" gridrow="2" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FC02FEB0FC5BFE86" box="[996,1009,288,303]" italics="true" pageId="4" pageNumber="39">–</emphasis>
|
||
<emphasis id="B91AEAEECE787B67FBE3FE8CFBA5FE8E" box="[1029,1039,284,295]" italics="true" pageId="4" pageNumber="39">–</emphasis>
|
||
[M H]
|
||
</td>
|
||
<td id="768F5DC2CE78849CFBB6FE8CFB22FE9B" box="[1104,1160,284,306]" gridcol="6" gridrow="2" pageId="4" pageNumber="39">282.08</td>
|
||
<td id="768F5DC2CE78849CFB78FE8CFA95FE9B" box="[1182,1343,284,306]" gridcol="7" gridrow="2" pageId="4" pageNumber="39">6</td>
|
||
<td id="768F5DC2CE78849CFAB1FE8CF899FE9B" box="[1367,1843,284,306]" gridcol="8" gridrow="2" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FEB1FADCFE86" bold="true" box="[1367,1398,289,303]" pageId="4" pageNumber="39">282</emphasis>
|
||
, 150, 133
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FEA3F899FEE1" box="[130,1843,307,328]" gridrow="3" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FEA3FF34FEE1" box="[130,158,307,328]" gridcol="0" gridrow="3" pageId="4" pageNumber="39">3</th>
|
||
<td id="768F5DC2CE78849CFF51FEA3FDACFEE1" box="[183,518,307,328]" gridcol="1" gridrow="3" pageId="4" pageNumber="39">Uridine</td>
|
||
<td id="768F5DC2CE78849CFD9EFEA3FD24FEE1" box="[632,654,307,328]" gridcol="2" gridrow="3" pageId="4" pageNumber="39">S</td>
|
||
<td id="768F5DC2CE78849CFD43FEA3FD6EFEE1" box="[677,708,307,328]" gridcol="3" gridrow="3" pageId="4" pageNumber="39">41</td>
|
||
<td id="768F5DC2CE78849CFD18FEA3FCC8FEE1" box="[766,866,307,328]" gridcol="4" gridrow="3" pageId="4" pageNumber="39">C9H12N2O6</td>
|
||
<td id="768F5DC2CE78849CFC2BFEA3FB95FEE1" box="[973,1087,307,328]" gridcol="5" gridrow="3" pageId="4" pageNumber="39">
|
||
[M
|
||
<emphasis id="B91AEAEECE787B67FC02FEA7FC5BFEEF" box="[996,1009,311,326]" italics="true" pageId="4" pageNumber="39">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE787B67FBE3FEA3FBA5FE97" box="[1029,1039,307,318]" italics="true" pageId="4" pageNumber="39">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE78849CFBB6FEA3FB22FEE1" box="[1104,1160,307,328]" gridcol="6" gridrow="3" pageId="4" pageNumber="39">243.06</td>
|
||
<td id="768F5DC2CE78849CFB78FEA3FA95FEE1" box="[1182,1343,307,328]" gridcol="7" gridrow="3" pageId="4" pageNumber="39">4</td>
|
||
<td id="768F5DC2CE78849CFAB1FEA3F899FEE1" box="[1367,1843,307,328]" gridcol="8" gridrow="3" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FEA8FADCFEEF" bold="true" box="[1367,1398,312,326]" pageId="4" pageNumber="39">243</emphasis>
|
||
, 200, 153, 152, 140, 122, 110
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FEDBF899FEF6" box="[130,1843,331,351]" gridrow="4" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FEDBFF34FEF6" box="[130,158,331,351]" gridcol="0" gridrow="4" pageId="4" pageNumber="39">4</th>
|
||
<td id="768F5DC2CE78849CFF51FEDBFDACFEF6" box="[183,518,331,351]" gridcol="1" gridrow="4" pageId="4" pageNumber="39">
|
||
2
|
||
<emphasis id="B91AEAEECE787B67FF27FEDCFF6FFEFF" box="[193,197,332,342]" italics="true" pageId="4" pageNumber="39">0</emphasis>
|
||
-Deoxyadenosine
|
||
</td>
|
||
<td id="768F5DC2CE78849CFD9EFEDBFD24FEF6" box="[632,654,331,351]" gridcol="2" gridrow="4" pageId="4" pageNumber="39">S</td>
|
||
<td id="768F5DC2CE78849CFD43FEDBFD6EFEF6" box="[677,708,331,351]" gridcol="3" gridrow="4" pageId="4" pageNumber="39">46</td>
|
||
<td id="768F5DC2CE78849CFD18FEDBFCC8FEF6" box="[766,866,331,351]" gridcol="4" gridrow="4" pageId="4" pageNumber="39">C10H13N5O3</td>
|
||
<td id="768F5DC2CE78849CFC2BFEDBFB95FEF6" box="[973,1087,331,351]" gridcol="5" gridrow="4" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FEDBFB22FEF6" box="[1104,1160,331,351]" gridcol="6" gridrow="4" pageId="4" pageNumber="39">252.11</td>
|
||
<td id="768F5DC2CE78849CFB78FEDBFA95FEF6" box="[1182,1343,331,351]" gridcol="7" gridrow="4" pageId="4" pageNumber="39">4</td>
|
||
<td id="768F5DC2CE78849CFAB1FEDBF899FEF6" box="[1367,1843,331,351]" gridcol="8" gridrow="4" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FEDFFADCFEF4" bold="true" box="[1367,1398,335,349]" pageId="4" pageNumber="39">252</emphasis>
|
||
, 136, 117
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FEF1F899FEDF" box="[130,1843,353,374]" gridrow="5" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FEF1FF34FEDF" box="[130,158,353,374]" gridcol="0" gridrow="5" pageId="4" pageNumber="39">5</th>
|
||
<td id="768F5DC2CE78849CFF51FEF1FDACFEDF" box="[183,518,353,374]" gridcol="1" gridrow="5" pageId="4" pageNumber="39">Thymidine</td>
|
||
<td id="768F5DC2CE78849CFD9EFEF1FD24FEDF" box="[632,654,353,374]" gridcol="2" gridrow="5" pageId="4" pageNumber="39">S</td>
|
||
<td id="768F5DC2CE78849CFD43FEF1FD6EFEDF" box="[677,708,353,374]" gridcol="3" gridrow="5" pageId="4" pageNumber="39">77</td>
|
||
<td id="768F5DC2CE78849CFD18FEF1FCC8FEDF" box="[766,866,353,374]" gridcol="4" gridrow="5" pageId="4" pageNumber="39">C10H14N2O5</td>
|
||
<td id="768F5DC2CE78849CFC2BFEF1FB95FEDF" box="[973,1087,353,374]" gridcol="5" gridrow="5" pageId="4" pageNumber="39">
|
||
[M
|
||
<emphasis id="B91AEAEECE787B67FC02FEF5FC5BFEDD" box="[996,1009,357,372]" italics="true" pageId="4" pageNumber="39">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE787B67FBE3FEF1FBA5FEC5" box="[1029,1039,353,364]" italics="true" pageId="4" pageNumber="39">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE78849CFBB6FEF1FB22FEDF" box="[1104,1160,353,374]" gridcol="6" gridrow="5" pageId="4" pageNumber="39">241.08</td>
|
||
<td id="768F5DC2CE78849CFB78FEF1FA95FEDF" box="[1182,1343,353,374]" gridcol="7" gridrow="5" pageId="4" pageNumber="39">3</td>
|
||
<td id="768F5DC2CE78849CFAB1FEF1F899FEDF" box="[1367,1843,353,374]" gridcol="8" gridrow="5" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FEF6FADCFEDD" bold="true" box="[1367,1398,358,372]" pageId="4" pageNumber="39">241</emphasis>
|
||
, 198, 151, 125
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FEE9F899FE24" box="[130,1843,377,397]" gridrow="6" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FEE9FF34FE24" box="[130,158,377,397]" gridcol="0" gridrow="6" pageId="4" pageNumber="39">6</th>
|
||
<td id="768F5DC2CE78849CFF51FEE9FDACFE24" box="[183,518,377,397]" gridcol="1" gridrow="6" pageId="4" pageNumber="39">
|
||
2
|
||
<emphasis id="B91AEAEECE787B67FF27FEE9FF73FE22" box="[193,217,377,395]" italics="true" pageId="4" pageNumber="39">0-O</emphasis>
|
||
-Methyladenosine
|
||
</td>
|
||
<td id="768F5DC2CE78849CFD9EFEE9FD24FE24" box="[632,654,377,397]" gridcol="2" gridrow="6" pageId="4" pageNumber="39">S</td>
|
||
<td id="768F5DC2CE78849CFD43FEE9FD6EFE24" box="[677,708,377,397]" gridcol="3" gridrow="6" pageId="4" pageNumber="39">64</td>
|
||
<td id="768F5DC2CE78849CFD18FEE9FCC8FE24" box="[766,866,377,397]" gridcol="4" gridrow="6" pageId="4" pageNumber="39">C11H15N5O4</td>
|
||
<td id="768F5DC2CE78849CFC2BFEE9FB95FE24" box="[973,1087,377,397]" gridcol="5" gridrow="6" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FEE9FB22FE24" box="[1104,1160,377,397]" gridcol="6" gridrow="6" pageId="4" pageNumber="39">282.12</td>
|
||
<td id="768F5DC2CE78849CFB78FEE9FA95FE24" box="[1182,1343,377,397]" gridcol="7" gridrow="6" pageId="4" pageNumber="39">4</td>
|
||
<td id="768F5DC2CE78849CFAB1FEE9F899FE24" box="[1367,1843,377,397]" gridcol="8" gridrow="6" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FEECFADCFE23" bold="true" box="[1367,1398,380,394]" pageId="4" pageNumber="39">282</emphasis>
|
||
, 136
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FE00F899FE0D" box="[130,1843,400,420]" gridrow="7" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FE00FF34FE0D" box="[130,158,400,420]" gridcol="0" gridrow="7" pageId="4" pageNumber="39">7</th>
|
||
<td id="768F5DC2CE78849CFF51FE00FDACFE0D" box="[183,518,400,420]" gridcol="1" gridrow="7" pageId="4" pageNumber="39">Phe</td>
|
||
<td id="768F5DC2CE78849CFD9EFE00FD24FE0D" box="[632,654,400,420]" gridcol="2" gridrow="7" pageId="4" pageNumber="39">S</td>
|
||
<td id="768F5DC2CE78849CFD43FE00FD6EFE0D" box="[677,708,400,420]" gridcol="3" gridrow="7" pageId="4" pageNumber="39">75</td>
|
||
<td id="768F5DC2CE78849CFD18FE00FCC8FE0D" box="[766,866,400,420]" gridcol="4" gridrow="7" pageId="4" pageNumber="39">C9H11NO2</td>
|
||
<td id="768F5DC2CE78849CFC2BFE00FB95FE0D" box="[973,1087,400,420]" gridcol="5" gridrow="7" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FE00FB22FE0D" box="[1104,1160,400,420]" gridcol="6" gridrow="7" pageId="4" pageNumber="39">166.09</td>
|
||
<td id="768F5DC2CE78849CFB78FE00FA95FE0D" box="[1182,1343,400,420]" gridcol="7" gridrow="7" pageId="4" pageNumber="39">3</td>
|
||
<td id="768F5DC2CE78849CFAB1FE00F899FE0D" box="[1367,1843,400,420]" gridcol="8" gridrow="7" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FE03FADCFE08" bold="true" box="[1367,1398,403,417]" pageId="4" pageNumber="39">166</emphasis>
|
||
, 149, 131, 120, 107, 103
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FE36F899FE12" box="[130,1843,422,443]" gridrow="8" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FE36FF34FE12" box="[130,158,422,443]" gridcol="0" gridrow="8" pageId="4" pageNumber="39">8</th>
|
||
<td id="768F5DC2CE78849CFF51FE36FDACFE12" box="[183,518,422,443]" gridcol="1" gridrow="8" pageId="4" pageNumber="39">Tyr</td>
|
||
<td id="768F5DC2CE78849CFD9EFE36FD24FE12" box="[632,654,422,443]" gridcol="2" gridrow="8" pageId="4" pageNumber="39">S</td>
|
||
<td id="768F5DC2CE78849CFD43FE36FD6EFE12" box="[677,708,422,443]" gridcol="3" gridrow="8" pageId="4" pageNumber="39">42</td>
|
||
<td id="768F5DC2CE78849CFD18FE36FCC8FE12" box="[766,866,422,443]" gridcol="4" gridrow="8" pageId="4" pageNumber="39">C9H11NO3</td>
|
||
<td id="768F5DC2CE78849CFC2BFE36FB95FE12" box="[973,1087,422,443]" gridcol="5" gridrow="8" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FE36FB22FE12" box="[1104,1160,422,443]" gridcol="6" gridrow="8" pageId="4" pageNumber="39">182.08</td>
|
||
<td id="768F5DC2CE78849CFB78FE36FA95FE12" box="[1182,1343,422,443]" gridcol="7" gridrow="8" pageId="4" pageNumber="39">4</td>
|
||
<td id="768F5DC2CE78849CFAB1FE36F899FE12" box="[1367,1843,422,443]" gridcol="8" gridrow="8" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FE3AFADCFE11" bold="true" box="[1367,1398,426,440]" pageId="4" pageNumber="39">182</emphasis>
|
||
, 165, 147, 136, 123, 119, 91
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FE2DF899FE7B" box="[130,1843,445,466]" gridrow="9" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FE2DFF34FE7B" box="[130,158,445,466]" gridcol="0" gridrow="9" pageId="4" pageNumber="39">9</th>
|
||
<td id="768F5DC2CE78849CFF51FE2DFDACFE7B" box="[183,518,445,466]" gridcol="1" gridrow="9" pageId="4" pageNumber="39">Trp</td>
|
||
<td id="768F5DC2CE78849CFD9EFE2DFD24FE7B" box="[632,654,445,466]" gridcol="2" gridrow="9" pageId="4" pageNumber="39">S</td>
|
||
<td id="768F5DC2CE78849CFD43FE2DFD6EFE7B" box="[677,708,445,466]" gridcol="3" gridrow="9" pageId="4" pageNumber="39">144</td>
|
||
<td id="768F5DC2CE78849CFD18FE2DFCC8FE7B" box="[766,866,445,466]" gridcol="4" gridrow="9" pageId="4" pageNumber="39">C11H12N2O2</td>
|
||
<td id="768F5DC2CE78849CFC2BFE2DFB95FE7B" box="[973,1087,445,466]" gridcol="5" gridrow="9" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FE2DFB22FE7B" box="[1104,1160,445,466]" gridcol="6" gridrow="9" pageId="4" pageNumber="39">205.10</td>
|
||
<td id="768F5DC2CE78849CFB78FE2DFA95FE7B" box="[1182,1343,445,466]" gridcol="7" gridrow="9" pageId="4" pageNumber="39">4</td>
|
||
<td id="768F5DC2CE78849CFAB1FE2DF899FE7B" box="[1367,1843,445,466]" gridcol="8" gridrow="9" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FE51FADCFE66" bold="true" box="[1367,1398,449,463]" pageId="4" pageNumber="39">205</emphasis>
|
||
, 188, 159, 132
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FE44F899FE41" box="[130,1843,468,488]" gridrow="10" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FE44FF34FE41" box="[130,158,468,488]" gridcol="0" gridrow="10" pageId="4" pageNumber="39">10</th>
|
||
<td id="768F5DC2CE78849CFF51FE44FDACFE41" box="[183,518,468,488]" gridcol="1" gridrow="10" pageId="4" pageNumber="39">3-Carboxy-1,2,3,4-tetrahydro-β- carboline</td>
|
||
<td id="768F5DC2CE78849CFD9EFE44FD24FE41" box="[632,654,468,488]" gridcol="2" gridrow="10" pageId="4" pageNumber="39">S</td>
|
||
<td id="768F5DC2CE78849CFD43FE44FD6EFE41" box="[677,708,468,488]" gridcol="3" gridrow="10" pageId="4" pageNumber="39">187</td>
|
||
<td id="768F5DC2CE78849CFD18FE44FCC8FE41" box="[766,866,468,488]" gridcol="4" gridrow="10" pageId="4" pageNumber="39">C12H12N2O2</td>
|
||
<td id="768F5DC2CE78849CFC2BFE44FB95FE41" box="[973,1087,468,488]" gridcol="5" gridrow="10" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FE44FB22FE41" box="[1104,1160,468,488]" gridcol="6" gridrow="10" pageId="4" pageNumber="39">217.10</td>
|
||
<td id="768F5DC2CE78849CFB78FE44FA95FE41" box="[1182,1343,468,488]" gridcol="7" gridrow="10" pageId="4" pageNumber="39">3</td>
|
||
<td id="768F5DC2CE78849CFAB1FE44F899FE41" box="[1367,1843,468,488]" gridcol="8" gridrow="10" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FE48FADCFE4F" bold="true" box="[1367,1398,472,486]" pageId="4" pageNumber="39">217</emphasis>
|
||
, 188, 173, 171, 144, 132
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FE7BF899FE56" box="[130,1843,491,511]" gridrow="11" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FE7BFF34FE56" box="[130,158,491,511]" gridcol="0" gridrow="11" pageId="4" pageNumber="39">11</th>
|
||
<td id="768F5DC2CE78849CFF51FE7BFDACFE56" box="[183,518,491,511]" gridcol="1" gridrow="11" pageId="4" pageNumber="39">Pentahomo-Met</td>
|
||
<td id="768F5DC2CE78849CFD9EFE7BFD24FE56" box="[632,654,491,511]" gridcol="2" gridrow="11" pageId="4" pageNumber="39">I</td>
|
||
<td id="768F5DC2CE78849CFD43FE7BFD6EFE56" box="[677,708,491,511]" gridcol="3" gridrow="11" pageId="4" pageNumber="39">276</td>
|
||
<td id="768F5DC2CE78849CFD18FE7BFCC8FE56" box="[766,866,491,511]" gridcol="4" gridrow="11" pageId="4" pageNumber="39">C10H21NO2S</td>
|
||
<td id="768F5DC2CE78849CFC2BFE7BFB95FE56" box="[973,1087,491,511]" gridcol="5" gridrow="11" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FE7BFB22FE56" box="[1104,1160,491,511]" gridcol="6" gridrow="11" pageId="4" pageNumber="39">220.14</td>
|
||
<td id="768F5DC2CE78849CFB78FE7BFA95FE56" box="[1182,1343,491,511]" gridcol="7" gridrow="11" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FB78FE7EFB01FE54" box="[1182,1195,494,509]" italics="true" pageId="4" pageNumber="39">–</emphasis>
|
||
a
|
||
</td>
|
||
<td id="768F5DC2CE78849CFAB1FE7BF899FE56" box="[1367,1843,491,511]" gridcol="8" gridrow="11" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FE7FFADCFE54" bold="true" box="[1367,1398,495,509]" pageId="4" pageNumber="39">220</emphasis>
|
||
, 174, 126, 109
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FD92F899FDBF" box="[130,1843,514,534]" gridrow="12" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FD92FF34FDBF" box="[130,158,514,534]" gridcol="0" gridrow="12" pageId="4" pageNumber="39">12</th>
|
||
<td id="768F5DC2CE78849CFF51FD92FDACFDBF" box="[183,518,514,534]" gridcol="1" gridrow="12" pageId="4" pageNumber="39">Hexahomo-Met</td>
|
||
<td id="768F5DC2CE78849CFD9EFD92FD24FDBF" box="[632,654,514,534]" gridcol="2" gridrow="12" pageId="4" pageNumber="39">I</td>
|
||
<td id="768F5DC2CE78849CFD43FD92FD6EFDBF" box="[677,708,514,534]" gridcol="3" gridrow="12" pageId="4" pageNumber="39">327</td>
|
||
<td id="768F5DC2CE78849CFD18FD92FCC8FDBF" box="[766,866,514,534]" gridcol="4" gridrow="12" pageId="4" pageNumber="39">C11H23NO2S</td>
|
||
<td id="768F5DC2CE78849CFC2BFD92FB95FDBF" box="[973,1087,514,534]" gridcol="5" gridrow="12" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FD92FB22FDBF" box="[1104,1160,514,534]" gridcol="6" gridrow="12" pageId="4" pageNumber="39">234.15</td>
|
||
<td id="768F5DC2CE78849CFB78FD92FA95FDBF" box="[1182,1343,514,534]" gridcol="7" gridrow="12" pageId="4" pageNumber="39">3</td>
|
||
<td id="768F5DC2CE78849CFAB1FD92F899FDBF" box="[1367,1843,514,534]" gridcol="8" gridrow="12" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FD96FADCFDBD" bold="true" box="[1367,1398,518,532]" pageId="4" pageNumber="39">234</emphasis>
|
||
, 188, 140, 123
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FD89F899FD84" box="[130,1843,537,557]" gridrow="13" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FD89FF34FD84" box="[130,158,537,557]" gridcol="0" gridrow="13" pageId="4" pageNumber="39">13</th>
|
||
<td id="768F5DC2CE78849CFF51FD89FDACFD84" box="[183,518,537,557]" gridcol="1" gridrow="13" pageId="4" pageNumber="39">
|
||
Pentahomo-Met
|
||
<emphasis id="B91AEAEECE787B67FED9FD8BFEEDFD82" box="[319,327,539,555]" italics="true" pageId="4" pageNumber="39">S</emphasis>
|
||
-Oxide
|
||
</td>
|
||
<td id="768F5DC2CE78849CFD9EFD89FD24FD84" box="[632,654,537,557]" gridcol="2" gridrow="13" pageId="4" pageNumber="39">I</td>
|
||
<td id="768F5DC2CE78849CFD43FD89FD6EFD84" box="[677,708,537,557]" gridcol="3" gridrow="13" pageId="4" pageNumber="39">86</td>
|
||
<td id="768F5DC2CE78849CFD18FD89FCC8FD84" box="[766,866,537,557]" gridcol="4" gridrow="13" pageId="4" pageNumber="39">C10H21NO3S</td>
|
||
<td id="768F5DC2CE78849CFC2BFD89FB95FD84" box="[973,1087,537,557]" gridcol="5" gridrow="13" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FD89FB22FD84" box="[1104,1160,537,557]" gridcol="6" gridrow="13" pageId="4" pageNumber="39">236.13</td>
|
||
<td id="768F5DC2CE78849CFB78FD89FA95FD84" box="[1182,1343,537,557]" gridcol="7" gridrow="13" pageId="4" pageNumber="39">3</td>
|
||
<td id="768F5DC2CE78849CFAB1FD89F899FD84" box="[1367,1843,537,557]" gridcol="8" gridrow="13" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FD8CFADCFD83" bold="true" box="[1367,1398,540,554]" pageId="4" pageNumber="39">236</emphasis>
|
||
, 190, 172, 126
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FDA0F899FDED" box="[130,1843,560,580]" gridrow="14" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FDA0FF34FDED" box="[130,158,560,580]" gridcol="0" gridrow="14" pageId="4" pageNumber="39">14</th>
|
||
<td id="768F5DC2CE78849CFF51FDA0FDACFDED" box="[183,518,560,580]" gridcol="1" gridrow="14" pageId="4" pageNumber="39">
|
||
Hexahomo-Met
|
||
<emphasis id="B91AEAEECE787B67FEDDFDA2FEEEFDEB" box="[315,324,562,578]" italics="true" pageId="4" pageNumber="39">S</emphasis>
|
||
-Oxide
|
||
</td>
|
||
<td id="768F5DC2CE78849CFD9EFDA0FD24FDED" box="[632,654,560,580]" gridcol="2" gridrow="14" pageId="4" pageNumber="39">I</td>
|
||
<td id="768F5DC2CE78849CFD43FDA0FD6EFDED" box="[677,708,560,580]" gridcol="3" gridrow="14" pageId="4" pageNumber="39">164</td>
|
||
<td id="768F5DC2CE78849CFD18FDA0FCC8FDED" box="[766,866,560,580]" gridcol="4" gridrow="14" pageId="4" pageNumber="39">C11H23NO3S</td>
|
||
<td id="768F5DC2CE78849CFC2BFDA0FB95FDED" box="[973,1087,560,580]" gridcol="5" gridrow="14" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FDA0FB22FDED" box="[1104,1160,560,580]" gridcol="6" gridrow="14" pageId="4" pageNumber="39">250.15</td>
|
||
<td id="768F5DC2CE78849CFB78FDA0FA95FDED" box="[1182,1343,560,580]" gridcol="7" gridrow="14" pageId="4" pageNumber="39">3</td>
|
||
<td id="768F5DC2CE78849CFAB1FDA0F899FDED" box="[1367,1843,560,580]" gridcol="8" gridrow="14" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FDA3FADCFDE8" bold="true" box="[1367,1398,563,577]" pageId="4" pageNumber="39">250</emphasis>
|
||
, 204, 186, 140
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FDD6F899FDF2" box="[130,1843,582,603]" gridrow="15" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FDD6FF34FDF2" box="[130,158,582,603]" gridcol="0" gridrow="15" pageId="4" pageNumber="39">15</th>
|
||
<td id="768F5DC2CE78849CFF51FDD6FDACFDF2" box="[183,518,582,603]" gridcol="1" gridrow="15" pageId="4" pageNumber="39">H-Phe-Gly-OH</td>
|
||
<td id="768F5DC2CE78849CFD9EFDD6FD24FDF2" box="[632,654,582,603]" gridcol="2" gridrow="15" pageId="4" pageNumber="39">I</td>
|
||
<td id="768F5DC2CE78849CFD43FDD6FD6EFDF2" box="[677,708,582,603]" gridcol="3" gridrow="15" pageId="4" pageNumber="39">99</td>
|
||
<td id="768F5DC2CE78849CFD18FDD6FCC8FDF2" box="[766,866,582,603]" gridcol="4" gridrow="15" pageId="4" pageNumber="39">C11H14N2O3</td>
|
||
<td id="768F5DC2CE78849CFC2BFDD6FB95FDF2" box="[973,1087,582,603]" gridcol="5" gridrow="15" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FDD6FB22FDF2" box="[1104,1160,582,603]" gridcol="6" gridrow="15" pageId="4" pageNumber="39">223.11</td>
|
||
<td id="768F5DC2CE78849CFB78FDD6FA95FDF2" box="[1182,1343,582,603]" gridcol="7" gridrow="15" pageId="4" pageNumber="39">4</td>
|
||
<td id="768F5DC2CE78849CFAB1FDD6F899FDF2" box="[1367,1843,582,603]" gridcol="8" gridrow="15" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FDDAFADCFDF1" bold="true" box="[1367,1398,586,600]" pageId="4" pageNumber="39">223</emphasis>
|
||
, 120, 103
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FDCDF899FDDB" box="[130,1843,605,626]" gridrow="16" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FDCDFF34FDDB" box="[130,158,605,626]" gridcol="0" gridrow="16" pageId="4" pageNumber="39">16</th>
|
||
<td id="768F5DC2CE78849CFF51FDCDFDACFDDB" box="[183,518,605,626]" gridcol="1" gridrow="16" pageId="4" pageNumber="39">H-Gly-Phe-OH</td>
|
||
<td id="768F5DC2CE78849CFD9EFDCDFD24FDDB" box="[632,654,605,626]" gridcol="2" gridrow="16" pageId="4" pageNumber="39">I</td>
|
||
<td id="768F5DC2CE78849CFD43FDCDFD6EFDDB" box="[677,708,605,626]" gridcol="3" gridrow="16" pageId="4" pageNumber="39">138</td>
|
||
<td id="768F5DC2CE78849CFD18FDCDFCC8FDDB" box="[766,866,605,626]" gridcol="4" gridrow="16" pageId="4" pageNumber="39">C11H14N2O3</td>
|
||
<td id="768F5DC2CE78849CFC2BFDCDFB95FDDB" box="[973,1087,605,626]" gridcol="5" gridrow="16" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FDCDFB22FDDB" box="[1104,1160,605,626]" gridcol="6" gridrow="16" pageId="4" pageNumber="39">223.11</td>
|
||
<td id="768F5DC2CE78849CFB78FDCDFA95FDDB" box="[1182,1343,605,626]" gridcol="7" gridrow="16" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FB78FDF0FB01FDC6" box="[1182,1195,608,623]" italics="true" pageId="4" pageNumber="39">–</emphasis>
|
||
a
|
||
</td>
|
||
<td id="768F5DC2CE78849CFAB1FDCDF899FDDB" box="[1367,1843,605,626]" gridcol="8" gridrow="16" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FDF1FADCFDC6" bold="true" box="[1367,1398,609,623]" pageId="4" pageNumber="39">223</emphasis>
|
||
, 177, 166, 120
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FDE4F899FD21" box="[130,1843,628,648]" gridrow="17" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FDE4FF34FD21" box="[130,158,628,648]" gridcol="0" gridrow="17" pageId="4" pageNumber="39">17</th>
|
||
<td id="768F5DC2CE78849CFF51FDE4FDACFD21" box="[183,518,628,648]" gridcol="1" gridrow="17" pageId="4" pageNumber="39">H-Ile-Val-OH</td>
|
||
<td id="768F5DC2CE78849CFD9EFDE4FD24FD21" box="[632,654,628,648]" gridcol="2" gridrow="17" pageId="4" pageNumber="39">S,L</td>
|
||
<td id="768F5DC2CE78849CFD43FDE4FD6EFD21" box="[677,708,628,648]" gridcol="3" gridrow="17" pageId="4" pageNumber="39">114</td>
|
||
<td id="768F5DC2CE78849CFD18FDE4FCC8FD21" box="[766,866,628,648]" gridcol="4" gridrow="17" pageId="4" pageNumber="39">C11H22N2O3</td>
|
||
<td id="768F5DC2CE78849CFC2BFDE4FB95FD21" box="[973,1087,628,648]" gridcol="5" gridrow="17" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FDE4FB22FD21" box="[1104,1160,628,648]" gridcol="6" gridrow="17" pageId="4" pageNumber="39">231.17</td>
|
||
<td id="768F5DC2CE78849CFB78FDE4FA95FD21" box="[1182,1343,628,648]" gridcol="7" gridrow="17" pageId="4" pageNumber="39">4</td>
|
||
<td id="768F5DC2CE78849CFAB1FDE4F899FD21" box="[1367,1843,628,648]" gridcol="8" gridrow="17" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FDE8FADCFD2F" bold="true" box="[1367,1398,632,646]" pageId="4" pageNumber="39">231</emphasis>
|
||
, 213, 185, 118, 86
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FD1BF899FD36" box="[130,1843,651,671]" gridrow="18" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FD1BFF34FD36" box="[130,158,651,671]" gridcol="0" gridrow="18" pageId="4" pageNumber="39">18</th>
|
||
<td id="768F5DC2CE78849CFF51FD1BFDACFD36" box="[183,518,651,671]" gridcol="1" gridrow="18" pageId="4" pageNumber="39">H-Val-Ile-OH</td>
|
||
<td id="768F5DC2CE78849CFD9EFD1BFD24FD36" box="[632,654,651,671]" gridcol="2" gridrow="18" pageId="4" pageNumber="39">S,L</td>
|
||
<td id="768F5DC2CE78849CFD43FD1BFD6EFD36" box="[677,708,651,671]" gridcol="3" gridrow="18" pageId="4" pageNumber="39">135</td>
|
||
<td id="768F5DC2CE78849CFD18FD1BFCC8FD36" box="[766,866,651,671]" gridcol="4" gridrow="18" pageId="4" pageNumber="39">C11H22N2O3</td>
|
||
<td id="768F5DC2CE78849CFC2BFD1BFB95FD36" box="[973,1087,651,671]" gridcol="5" gridrow="18" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FD1BFB22FD36" box="[1104,1160,651,671]" gridcol="6" gridrow="18" pageId="4" pageNumber="39">231.17</td>
|
||
<td id="768F5DC2CE78849CFB78FD1BFA95FD36" box="[1182,1343,651,671]" gridcol="7" gridrow="18" pageId="4" pageNumber="39">4</td>
|
||
<td id="768F5DC2CE78849CFAB1FD1BF899FD36" box="[1367,1843,651,671]" gridcol="8" gridrow="18" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FD1FFADCFD34" bold="true" box="[1367,1398,655,669]" pageId="4" pageNumber="39">231</emphasis>
|
||
, 213, 185, 132, 86, 72
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FD32F899FD1F" box="[130,1843,674,694]" gridrow="19" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FD32FF34FD1F" box="[130,158,674,694]" gridcol="0" gridrow="19" pageId="4" pageNumber="39">19</th>
|
||
<td id="768F5DC2CE78849CFF51FD32FDACFD1F" box="[183,518,674,694]" gridcol="1" gridrow="19" pageId="4" pageNumber="39">H-Leu-Val-OH</td>
|
||
<td id="768F5DC2CE78849CFD9EFD32FD24FD1F" box="[632,654,674,694]" gridcol="2" gridrow="19" pageId="4" pageNumber="39">S,L</td>
|
||
<td id="768F5DC2CE78849CFD43FD32FD6EFD1F" box="[677,708,674,694]" gridcol="3" gridrow="19" pageId="4" pageNumber="39">139</td>
|
||
<td id="768F5DC2CE78849CFD18FD32FCC8FD1F" box="[766,866,674,694]" gridcol="4" gridrow="19" pageId="4" pageNumber="39">C11H22N2O3</td>
|
||
<td id="768F5DC2CE78849CFC2BFD32FB95FD1F" box="[973,1087,674,694]" gridcol="5" gridrow="19" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FD32FB22FD1F" box="[1104,1160,674,694]" gridcol="6" gridrow="19" pageId="4" pageNumber="39">231.17</td>
|
||
<td id="768F5DC2CE78849CFB78FD32FA95FD1F" box="[1182,1343,674,694]" gridcol="7" gridrow="19" pageId="4" pageNumber="39">4</td>
|
||
<td id="768F5DC2CE78849CFAB1FD32F899FD1F" box="[1367,1843,674,694]" gridcol="8" gridrow="19" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FD35FADCFD1A" bold="true" box="[1367,1398,677,691]" pageId="4" pageNumber="39">231</emphasis>
|
||
, 213, 185, 118, 86
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FD29F899FD64" box="[130,1843,697,717]" gridrow="20" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FD29FF34FD64" box="[130,158,697,717]" gridcol="0" gridrow="20" pageId="4" pageNumber="39">20</th>
|
||
<td id="768F5DC2CE78849CFF51FD29FDACFD64" box="[183,518,697,717]" gridcol="1" gridrow="20" pageId="4" pageNumber="39">H-Val-Leu-OH</td>
|
||
<td id="768F5DC2CE78849CFD9EFD29FD24FD64" box="[632,654,697,717]" gridcol="2" gridrow="20" pageId="4" pageNumber="39">S,L</td>
|
||
<td id="768F5DC2CE78849CFD43FD29FD6EFD64" box="[677,708,697,717]" gridcol="3" gridrow="20" pageId="4" pageNumber="39">159</td>
|
||
<td id="768F5DC2CE78849CFD18FD29FCC8FD64" box="[766,866,697,717]" gridcol="4" gridrow="20" pageId="4" pageNumber="39">C11H22N2O3</td>
|
||
<td id="768F5DC2CE78849CFC2BFD29FB95FD64" box="[973,1087,697,717]" gridcol="5" gridrow="20" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FD29FB22FD64" box="[1104,1160,697,717]" gridcol="6" gridrow="20" pageId="4" pageNumber="39">231.17</td>
|
||
<td id="768F5DC2CE78849CFB78FD29FA95FD64" box="[1182,1343,697,717]" gridcol="7" gridrow="20" pageId="4" pageNumber="39">4</td>
|
||
<td id="768F5DC2CE78849CFAB1FD29F899FD64" box="[1367,1843,697,717]" gridcol="8" gridrow="20" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FD2CFADCFD63" bold="true" box="[1367,1398,700,714]" pageId="4" pageNumber="39">231</emphasis>
|
||
, 213, 185, 132, 86, 72
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FD40F899FD4D" box="[130,1843,720,740]" gridrow="21" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FD40FF34FD4D" box="[130,158,720,740]" gridcol="0" gridrow="21" pageId="4" pageNumber="39">21</th>
|
||
<td id="768F5DC2CE78849CFF51FD40FDACFD4D" box="[183,518,720,740]" gridcol="1" gridrow="21" pageId="4" pageNumber="39">H-Leu-Pro-OH</td>
|
||
<td id="768F5DC2CE78849CFD9EFD40FD24FD4D" box="[632,654,720,740]" gridcol="2" gridrow="21" pageId="4" pageNumber="39">S</td>
|
||
<td id="768F5DC2CE78849CFD43FD40FD6EFD4D" box="[677,708,720,740]" gridcol="3" gridrow="21" pageId="4" pageNumber="39">154</td>
|
||
<td id="768F5DC2CE78849CFD18FD40FCC8FD4D" box="[766,866,720,740]" gridcol="4" gridrow="21" pageId="4" pageNumber="39">C11H20N2O3</td>
|
||
<td id="768F5DC2CE78849CFC2BFD40FB95FD4D" box="[973,1087,720,740]" gridcol="5" gridrow="21" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FD40FB22FD4D" box="[1104,1160,720,740]" gridcol="6" gridrow="21" pageId="4" pageNumber="39">229.15</td>
|
||
<td id="768F5DC2CE78849CFB78FD40FA95FD4D" box="[1182,1343,720,740]" gridcol="7" gridrow="21" pageId="4" pageNumber="39">3</td>
|
||
<td id="768F5DC2CE78849CFAB1FD40F899FD4D" box="[1367,1843,720,740]" gridcol="8" gridrow="21" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FD43FADCFD48" bold="true" box="[1367,1398,723,737]" pageId="4" pageNumber="39">229</emphasis>
|
||
, 116, 86
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FD76F899FD52" box="[130,1843,742,763]" gridrow="22" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FD76FF34FD52" box="[130,158,742,763]" gridcol="0" gridrow="22" pageId="4" pageNumber="39">22</th>
|
||
<td id="768F5DC2CE78849CFF51FD76FDACFD52" box="[183,518,742,763]" gridcol="1" gridrow="22" pageId="4" pageNumber="39">H-Leu-Tyr-OH</td>
|
||
<td id="768F5DC2CE78849CFD9EFD76FD24FD52" box="[632,654,742,763]" gridcol="2" gridrow="22" pageId="4" pageNumber="39">S,L</td>
|
||
<td id="768F5DC2CE78849CFD43FD76FD6EFD52" box="[677,708,742,763]" gridcol="3" gridrow="22" pageId="4" pageNumber="39">166</td>
|
||
<td id="768F5DC2CE78849CFD18FD76FCC8FD52" box="[766,866,742,763]" gridcol="4" gridrow="22" pageId="4" pageNumber="39">C15H22N2O4</td>
|
||
<td id="768F5DC2CE78849CFC2BFD76FB95FD52" box="[973,1087,742,763]" gridcol="5" gridrow="22" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FD76FB22FD52" box="[1104,1160,742,763]" gridcol="6" gridrow="22" pageId="4" pageNumber="39">295.17</td>
|
||
<td id="768F5DC2CE78849CFB78FD76FA95FD52" box="[1182,1343,742,763]" gridcol="7" gridrow="22" pageId="4" pageNumber="39">5</td>
|
||
<td id="768F5DC2CE78849CFAB1FD76F899FD52" box="[1367,1843,742,763]" gridcol="8" gridrow="22" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FD7AFADCFD51" bold="true" box="[1367,1398,746,760]" pageId="4" pageNumber="39">295</emphasis>
|
||
, 277, 249, 182, 165, 136, 86
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FD6DF899FCB8" box="[130,1843,765,785]" gridrow="23" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FD6DFF34FCB8" box="[130,158,765,785]" gridcol="0" gridrow="23" pageId="4" pageNumber="39">23</th>
|
||
<td id="768F5DC2CE78849CFF51FD6DFDACFCB8" box="[183,518,765,785]" gridcol="1" gridrow="23" pageId="4" pageNumber="39">H-Tyr-Ile-OH</td>
|
||
<td id="768F5DC2CE78849CFD9EFD6DFD24FCB8" box="[632,654,765,785]" gridcol="2" gridrow="23" pageId="4" pageNumber="39">S</td>
|
||
<td id="768F5DC2CE78849CFD43FD6DFD6EFCB8" box="[677,708,765,785]" gridcol="3" gridrow="23" pageId="4" pageNumber="39">174</td>
|
||
<td id="768F5DC2CE78849CFD18FD6DFCC8FCB8" box="[766,866,765,785]" gridcol="4" gridrow="23" pageId="4" pageNumber="39">C15H22N2O4</td>
|
||
<td id="768F5DC2CE78849CFC2BFD6DFB95FCB8" box="[973,1087,765,785]" gridcol="5" gridrow="23" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FD6DFB22FCB8" box="[1104,1160,765,785]" gridcol="6" gridrow="23" pageId="4" pageNumber="39">295.17</td>
|
||
<td id="768F5DC2CE78849CFB78FD6DFA95FCB8" box="[1182,1343,765,785]" gridcol="7" gridrow="23" pageId="4" pageNumber="39">5</td>
|
||
<td id="768F5DC2CE78849CFAB1FD6DF899FCB8" box="[1367,1843,765,785]" gridcol="8" gridrow="23" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FC91FADCFCA6" bold="true" box="[1367,1398,769,783]" pageId="4" pageNumber="39">295</emphasis>
|
||
, 278, 277, 250, 249, 136, 132, 130, 121, 119
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FC84F899FC81" box="[130,1843,788,808]" gridrow="24" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FC84FF34FC81" box="[130,158,788,808]" gridcol="0" gridrow="24" pageId="4" pageNumber="39">24</th>
|
||
<td id="768F5DC2CE78849CFF51FC84FDACFC81" box="[183,518,788,808]" gridcol="1" gridrow="24" pageId="4" pageNumber="39">H-Tyr-Leu-OH</td>
|
||
<td id="768F5DC2CE78849CFD9EFC84FD24FC81" box="[632,654,788,808]" gridcol="2" gridrow="24" pageId="4" pageNumber="39">S</td>
|
||
<td id="768F5DC2CE78849CFD43FC84FD6EFC81" box="[677,708,788,808]" gridcol="3" gridrow="24" pageId="4" pageNumber="39">192</td>
|
||
<td id="768F5DC2CE78849CFD18FC84FCC8FC81" box="[766,866,788,808]" gridcol="4" gridrow="24" pageId="4" pageNumber="39">C15H22N2O4</td>
|
||
<td id="768F5DC2CE78849CFC2BFC84FB95FC81" box="[973,1087,788,808]" gridcol="5" gridrow="24" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FC84FB22FC81" box="[1104,1160,788,808]" gridcol="6" gridrow="24" pageId="4" pageNumber="39">295.17</td>
|
||
<td id="768F5DC2CE78849CFB78FC84FA95FC81" box="[1182,1343,788,808]" gridcol="7" gridrow="24" pageId="4" pageNumber="39">5</td>
|
||
<td id="768F5DC2CE78849CFAB1FC84F899FC81" box="[1367,1843,788,808]" gridcol="8" gridrow="24" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FC88FADCFC8F" bold="true" box="[1367,1398,792,806]" pageId="4" pageNumber="39">295</emphasis>
|
||
, 278, 277, 250, 249, 136, 132, 130, 121, 119
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FCBBF899FC96" box="[130,1843,811,831]" gridrow="25" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FCBBFF34FC96" box="[130,158,811,831]" gridcol="0" gridrow="25" pageId="4" pageNumber="39">25</th>
|
||
<td id="768F5DC2CE78849CFF51FCBBFDACFC96" box="[183,518,811,831]" gridcol="1" gridrow="25" pageId="4" pageNumber="39">H-Phe-Val-OH</td>
|
||
<td id="768F5DC2CE78849CFD9EFCBBFD24FC96" box="[632,654,811,831]" gridcol="2" gridrow="25" pageId="4" pageNumber="39">I</td>
|
||
<td id="768F5DC2CE78849CFD43FCBBFD6EFC96" box="[677,708,811,831]" gridcol="3" gridrow="25" pageId="4" pageNumber="39">179</td>
|
||
<td id="768F5DC2CE78849CFD18FCBBFCC8FC96" box="[766,866,811,831]" gridcol="4" gridrow="25" pageId="4" pageNumber="39">C14H 20N2O3</td>
|
||
<td id="768F5DC2CE78849CFC2BFCBBFB95FC96" box="[973,1087,811,831]" gridcol="5" gridrow="25" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FCBBFB22FC96" box="[1104,1160,811,831]" gridcol="6" gridrow="25" pageId="4" pageNumber="39">265.15</td>
|
||
<td id="768F5DC2CE78849CFB78FCBBFA95FC96" box="[1182,1343,811,831]" gridcol="7" gridrow="25" pageId="4" pageNumber="39">4</td>
|
||
<td id="768F5DC2CE78849CFAB1FCBBF899FC96" box="[1367,1843,811,831]" gridcol="8" gridrow="25" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FCBFFADCFC94" bold="true" box="[1367,1398,815,829]" pageId="4" pageNumber="39">265</emphasis>
|
||
, 219, 120, 118
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FCD2F899FCFF" box="[130,1843,834,854]" gridrow="26" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FCD2FF34FCFF" box="[130,158,834,854]" gridcol="0" gridrow="26" pageId="4" pageNumber="39">26</th>
|
||
<td id="768F5DC2CE78849CFF51FCD2FDACFCFF" box="[183,518,834,854]" gridcol="1" gridrow="26" pageId="4" pageNumber="39">H-Val-Phe-OH</td>
|
||
<td id="768F5DC2CE78849CFD9EFCD2FD24FCFF" box="[632,654,834,854]" gridcol="2" gridrow="26" pageId="4" pageNumber="39">I</td>
|
||
<td id="768F5DC2CE78849CFD43FCD2FD6EFCFF" box="[677,708,834,854]" gridcol="3" gridrow="26" pageId="4" pageNumber="39">196</td>
|
||
<td id="768F5DC2CE78849CFD18FCD2FCC8FCFF" box="[766,866,834,854]" gridcol="4" gridrow="26" pageId="4" pageNumber="39">C14H20N2O3</td>
|
||
<td id="768F5DC2CE78849CFC2BFCD2FB95FCFF" box="[973,1087,834,854]" gridcol="5" gridrow="26" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FCD2FB22FCFF" box="[1104,1160,834,854]" gridcol="6" gridrow="26" pageId="4" pageNumber="39">265.15</td>
|
||
<td id="768F5DC2CE78849CFB78FCD2FA95FCFF" box="[1182,1343,834,854]" gridcol="7" gridrow="26" pageId="4" pageNumber="39">4</td>
|
||
<td id="768F5DC2CE78849CFAB1FCD2F899FCFF" box="[1367,1843,834,854]" gridcol="8" gridrow="26" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FCD5FADCFCFA" bold="true" box="[1367,1398,837,851]" pageId="4" pageNumber="39">265</emphasis>
|
||
, 219, 166, 120, 72
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FCC9F899FCC4" box="[130,1843,857,877]" gridrow="27" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FCC9FF34FCC4" box="[130,158,857,877]" gridcol="0" gridrow="27" pageId="4" pageNumber="39">27</th>
|
||
<td id="768F5DC2CE78849CFF51FCC9FDACFCC4" box="[183,518,857,877]" gridcol="1" gridrow="27" pageId="4" pageNumber="39">H-Ile-Ile-OH</td>
|
||
<td id="768F5DC2CE78849CFD9EFCC9FD24FCC4" box="[632,654,857,877]" gridcol="2" gridrow="27" pageId="4" pageNumber="39">S,L</td>
|
||
<td id="768F5DC2CE78849CFD43FCC9FD6EFCC4" box="[677,708,857,877]" gridcol="3" gridrow="27" pageId="4" pageNumber="39">185</td>
|
||
<td id="768F5DC2CE78849CFD18FCC9FCC8FCC4" box="[766,866,857,877]" gridcol="4" gridrow="27" pageId="4" pageNumber="39">C12H24N2O3</td>
|
||
<td id="768F5DC2CE78849CFC2BFCC9FB95FCC4" box="[973,1087,857,877]" gridcol="5" gridrow="27" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FCC9FB22FCC4" box="[1104,1160,857,877]" gridcol="6" gridrow="27" pageId="4" pageNumber="39">245.19</td>
|
||
<td id="768F5DC2CE78849CFB78FCC9FA95FCC4" box="[1182,1343,857,877]" gridcol="7" gridrow="27" pageId="4" pageNumber="39">4</td>
|
||
<td id="768F5DC2CE78849CFAB1FCC9F899FCC4" box="[1367,1843,857,877]" gridcol="8" gridrow="27" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FCCCFADCFCC3" bold="true" box="[1367,1398,860,874]" pageId="4" pageNumber="39">245</emphasis>
|
||
, 199, 132, 86
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FCFFF899FC2D" box="[130,1843,879,900]" gridrow="28" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FCFFFF34FC2D" box="[130,158,879,900]" gridcol="0" gridrow="28" pageId="4" pageNumber="39">28</th>
|
||
<td id="768F5DC2CE78849CFF51FCFFFDACFC2D" box="[183,518,879,900]" gridcol="1" gridrow="28" pageId="4" pageNumber="39">H-Leu-Ile-OH</td>
|
||
<td id="768F5DC2CE78849CFD9EFCFFFD24FC2D" box="[632,654,879,900]" gridcol="2" gridrow="28" pageId="4" pageNumber="39">S,L</td>
|
||
<td id="768F5DC2CE78849CFD43FCFFFD6EFC2D" box="[677,708,879,900]" gridcol="3" gridrow="28" pageId="4" pageNumber="39">199</td>
|
||
<td id="768F5DC2CE78849CFD18FCFFFCC8FC2D" box="[766,866,879,900]" gridcol="4" gridrow="28" pageId="4" pageNumber="39">C12H24N2O3</td>
|
||
<td id="768F5DC2CE78849CFC2BFCFFFB95FC2D" box="[973,1087,879,900]" gridcol="5" gridrow="28" pageId="4" pageNumber="39">+ [M+H]</td>
|
||
<td id="768F5DC2CE78849CFBB6FCFFFB22FC2D" box="[1104,1160,879,900]" gridcol="6" gridrow="28" pageId="4" pageNumber="39">245.19</td>
|
||
<td id="768F5DC2CE78849CFB78FCFFFA95FC2D" box="[1182,1343,879,900]" gridcol="7" gridrow="28" pageId="4" pageNumber="39">4</td>
|
||
<td id="768F5DC2CE78849CFAB1FCFFF899FC2D" box="[1367,1843,879,900]" gridcol="8" gridrow="28" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FCE3FADCFC28" bold="true" box="[1367,1398,883,897]" pageId="4" pageNumber="39">245</emphasis>
|
||
, 199, 132, 86
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FC16F899FC32" box="[130,1843,902,923]" gridrow="29" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FC16FF34FC32" box="[130,158,902,923]" gridcol="0" gridrow="29" pageId="4" pageNumber="39">29</th>
|
||
<td id="768F5DC2CE78849CFF51FC16FDACFC32" box="[183,518,902,923]" gridcol="1" gridrow="29" pageId="4" pageNumber="39">H-Ile-Leu-OH</td>
|
||
<td id="768F5DC2CE78849CFD9EFC16FD24FC32" box="[632,654,902,923]" gridcol="2" gridrow="29" pageId="4" pageNumber="39">S,L</td>
|
||
<td id="768F5DC2CE78849CFD43FC16FD6EFC32" box="[677,708,902,923]" gridcol="3" gridrow="29" pageId="4" pageNumber="39">204</td>
|
||
<td id="768F5DC2CE78849CFD18FC16FCC8FC32" box="[766,866,902,923]" gridcol="4" gridrow="29" pageId="4" pageNumber="39">C12H24N2O3</td>
|
||
<td id="768F5DC2CE78849CFC2BFC16FB95FC32" box="[973,1087,902,923]" gridcol="5" gridrow="29" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FC16FB22FC32" box="[1104,1160,902,923]" gridcol="6" gridrow="29" pageId="4" pageNumber="39">245.19</td>
|
||
<td id="768F5DC2CE78849CFB78FC16FA95FC32" box="[1182,1343,902,923]" gridcol="7" gridrow="29" pageId="4" pageNumber="39">4</td>
|
||
<td id="768F5DC2CE78849CFAB1FC16F899FC32" box="[1367,1843,902,923]" gridcol="8" gridrow="29" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FC1AFADCFC31" bold="true" box="[1367,1398,906,920]" pageId="4" pageNumber="39">245</emphasis>
|
||
, 199, 132, 86
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FC0DF899FC18" box="[130,1843,925,945]" gridrow="30" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FC0DFF34FC18" box="[130,158,925,945]" gridcol="0" gridrow="30" pageId="4" pageNumber="39">30</th>
|
||
<td id="768F5DC2CE78849CFF51FC0DFDACFC18" box="[183,518,925,945]" gridcol="1" gridrow="30" pageId="4" pageNumber="39">H-Leu-Leu-OH</td>
|
||
<td id="768F5DC2CE78849CFD9EFC0DFD24FC18" box="[632,654,925,945]" gridcol="2" gridrow="30" pageId="4" pageNumber="39">S,L</td>
|
||
<td id="768F5DC2CE78849CFD43FC0DFD6EFC18" box="[677,708,925,945]" gridcol="3" gridrow="30" pageId="4" pageNumber="39">217</td>
|
||
<td id="768F5DC2CE78849CFD18FC0DFCC8FC18" box="[766,866,925,945]" gridcol="4" gridrow="30" pageId="4" pageNumber="39">C12H24N2O3</td>
|
||
<td id="768F5DC2CE78849CFC2BFC0DFB95FC18" box="[973,1087,925,945]" gridcol="5" gridrow="30" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FC0DFB22FC18" box="[1104,1160,925,945]" gridcol="6" gridrow="30" pageId="4" pageNumber="39">245.19</td>
|
||
<td id="768F5DC2CE78849CFB78FC0DFA95FC18" box="[1182,1343,925,945]" gridcol="7" gridrow="30" pageId="4" pageNumber="39">4</td>
|
||
<td id="768F5DC2CE78849CFAB1FC0DF899FC18" box="[1367,1843,925,945]" gridcol="8" gridrow="30" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FC31FADCFC06" bold="true" box="[1367,1398,929,943]" pageId="4" pageNumber="39">245</emphasis>
|
||
, 199, 132, 86
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FC24F899FC61" box="[130,1843,948,968]" gridrow="31" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FC24FF34FC61" box="[130,158,948,968]" gridcol="0" gridrow="31" pageId="4" pageNumber="39">31</th>
|
||
<td id="768F5DC2CE78849CFF51FC24FDACFC61" box="[183,518,948,968]" gridcol="1" gridrow="31" pageId="4" pageNumber="39">H-Phe-Ile-OH</td>
|
||
<td id="768F5DC2CE78849CFD9EFC24FD24FC61" box="[632,654,948,968]" gridcol="2" gridrow="31" pageId="4" pageNumber="39">S,L</td>
|
||
<td id="768F5DC2CE78849CFD43FC24FD6EFC61" box="[677,708,948,968]" gridcol="3" gridrow="31" pageId="4" pageNumber="39">226</td>
|
||
<td id="768F5DC2CE78849CFD18FC24FCC8FC61" box="[766,866,948,968]" gridcol="4" gridrow="31" pageId="4" pageNumber="39">C15H22N2O3</td>
|
||
<td id="768F5DC2CE78849CFC2BFC24FB95FC61" box="[973,1087,948,968]" gridcol="5" gridrow="31" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FC24FB22FC61" box="[1104,1160,948,968]" gridcol="6" gridrow="31" pageId="4" pageNumber="39">279.17</td>
|
||
<td id="768F5DC2CE78849CFB78FC24FA95FC61" box="[1182,1343,948,968]" gridcol="7" gridrow="31" pageId="4" pageNumber="39">4</td>
|
||
<td id="768F5DC2CE78849CFAB1FC24F899FC61" box="[1367,1843,948,968]" gridcol="8" gridrow="31" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FC28FADCFC6F" bold="true" box="[1367,1398,952,966]" pageId="4" pageNumber="39">279</emphasis>
|
||
, 262, 261, 233, 132, 120, 86
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FC5BF899FC76" box="[130,1843,971,991]" gridrow="32" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FC5BFF34FC76" box="[130,158,971,991]" gridcol="0" gridrow="32" pageId="4" pageNumber="39">32</th>
|
||
<td id="768F5DC2CE78849CFF51FC5BFDACFC76" box="[183,518,971,991]" gridcol="1" gridrow="32" pageId="4" pageNumber="39">H-Ile-Phe-OH</td>
|
||
<td id="768F5DC2CE78849CFD9EFC5BFD24FC76" box="[632,654,971,991]" gridcol="2" gridrow="32" pageId="4" pageNumber="39">S,L</td>
|
||
<td id="768F5DC2CE78849CFD43FC5BFD6EFC76" box="[677,708,971,991]" gridcol="3" gridrow="32" pageId="4" pageNumber="39">235</td>
|
||
<td id="768F5DC2CE78849CFD18FC5BFCC8FC76" box="[766,866,971,991]" gridcol="4" gridrow="32" pageId="4" pageNumber="39">C15H22N2O3</td>
|
||
<td id="768F5DC2CE78849CFC2BFC5BFB95FC76" box="[973,1087,971,991]" gridcol="5" gridrow="32" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FC5BFB22FC76" box="[1104,1160,971,991]" gridcol="6" gridrow="32" pageId="4" pageNumber="39">279.17</td>
|
||
<td id="768F5DC2CE78849CFB78FC5BFA95FC76" box="[1182,1343,971,991]" gridcol="7" gridrow="32" pageId="4" pageNumber="39">4</td>
|
||
<td id="768F5DC2CE78849CFAB1FC5BF899FC76" box="[1367,1843,971,991]" gridcol="8" gridrow="32" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FC5EFADCFC75" bold="true" box="[1367,1398,974,988]" pageId="4" pageNumber="39">279</emphasis>
|
||
, 261, 233, 166, 120, 86
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FC72F899FC5F" box="[130,1843,994,1014]" gridrow="33" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FC72FF34FC5F" box="[130,158,994,1014]" gridcol="0" gridrow="33" pageId="4" pageNumber="39">33</th>
|
||
<td id="768F5DC2CE78849CFF51FC72FDACFC5F" box="[183,518,994,1014]" gridcol="1" gridrow="33" pageId="4" pageNumber="39">H-Phe-Leu-OH</td>
|
||
<td id="768F5DC2CE78849CFD9EFC72FD24FC5F" box="[632,654,994,1014]" gridcol="2" gridrow="33" pageId="4" pageNumber="39">S,L</td>
|
||
<td id="768F5DC2CE78849CFD43FC72FD6EFC5F" box="[677,708,994,1014]" gridcol="3" gridrow="33" pageId="4" pageNumber="39">247</td>
|
||
<td id="768F5DC2CE78849CFD18FC72FCC8FC5F" box="[766,866,994,1014]" gridcol="4" gridrow="33" pageId="4" pageNumber="39">C15H22N2O3</td>
|
||
<td id="768F5DC2CE78849CFC2BFC72FB95FC5F" box="[973,1087,994,1014]" gridcol="5" gridrow="33" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FC72FB22FC5F" box="[1104,1160,994,1014]" gridcol="6" gridrow="33" pageId="4" pageNumber="39">279.17</td>
|
||
<td id="768F5DC2CE78849CFB78FC72FA95FC5F" box="[1182,1343,994,1014]" gridcol="7" gridrow="33" pageId="4" pageNumber="39">4</td>
|
||
<td id="768F5DC2CE78849CFAB1FC72F899FC5F" box="[1367,1843,994,1014]" gridcol="8" gridrow="33" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FC75FADCFC5A" bold="true" box="[1367,1398,997,1011]" pageId="4" pageNumber="39">279</emphasis>
|
||
, 262, 261, 233, 132, 120, 86
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FC69F899FBA4" box="[130,1843,1017,1037]" gridrow="34" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FC69FF34FBA4" box="[130,158,1017,1037]" gridcol="0" gridrow="34" pageId="4" pageNumber="39">34</th>
|
||
<td id="768F5DC2CE78849CFF51FC69FDACFBA4" box="[183,518,1017,1037]" gridcol="1" gridrow="34" pageId="4" pageNumber="39">H-Leu-Phe -OH</td>
|
||
<td id="768F5DC2CE78849CFD9EFC69FD24FBA4" box="[632,654,1017,1037]" gridcol="2" gridrow="34" pageId="4" pageNumber="39">S,L</td>
|
||
<td id="768F5DC2CE78849CFD43FC69FD6EFBA4" box="[677,708,1017,1037]" gridcol="3" gridrow="34" pageId="4" pageNumber="39">249</td>
|
||
<td id="768F5DC2CE78849CFD18FC69FCC8FBA4" box="[766,866,1017,1037]" gridcol="4" gridrow="34" pageId="4" pageNumber="39">C15H22N2O3</td>
|
||
<td id="768F5DC2CE78849CFC2BFC69FB95FBA4" box="[973,1087,1017,1037]" gridcol="5" gridrow="34" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FC69FB22FBA4" box="[1104,1160,1017,1037]" gridcol="6" gridrow="34" pageId="4" pageNumber="39">279.17</td>
|
||
<td id="768F5DC2CE78849CFB78FC69FA95FBA4" box="[1182,1343,1017,1037]" gridcol="7" gridrow="34" pageId="4" pageNumber="39">4</td>
|
||
<td id="768F5DC2CE78849CFAB1FC69F899FBA4" box="[1367,1843,1017,1037]" gridcol="8" gridrow="34" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FC6CFADCFBA3" bold="true" box="[1367,1398,1020,1034]" pageId="4" pageNumber="39">279</emphasis>
|
||
, 261, 233, 166, 120, 86
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FB9FF899FB8D" box="[130,1843,1039,1060]" gridrow="35" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FB9FFF34FB8D" box="[130,158,1039,1060]" gridcol="0" gridrow="35" pageId="4" pageNumber="39">35</th>
|
||
<td id="768F5DC2CE78849CFF51FB9FFDACFB8D" box="[183,518,1039,1060]" gridcol="1" gridrow="35" pageId="4" pageNumber="39">7-MeSO-Heptyl-CN</td>
|
||
<td id="768F5DC2CE78849CFD9EFB9FFD24FB8D" box="[632,654,1039,1060]" gridcol="2" gridrow="35" pageId="4" pageNumber="39">I,L</td>
|
||
<td id="768F5DC2CE78849CFD43FB9FFD6EFB8D" box="[677,708,1039,1060]" gridcol="3" gridrow="35" pageId="4" pageNumber="39">266</td>
|
||
<td id="768F5DC2CE78849CFD18FB9FFCC8FB8D" box="[766,866,1039,1060]" gridcol="4" gridrow="35" pageId="4" pageNumber="39">C9H17NOS</td>
|
||
<td id="768F5DC2CE78849CFC2BFB9FFB95FB8D" box="[973,1087,1039,1060]" gridcol="5" gridrow="35" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FB9FFB22FB8D" box="[1104,1160,1039,1060]" gridcol="6" gridrow="35" pageId="4" pageNumber="39">188.11</td>
|
||
<td id="768F5DC2CE78849CFB78FB9FFA95FB8D" box="[1182,1343,1039,1060]" gridcol="7" gridrow="35" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FB78FB82FB01FB88" box="[1182,1195,1042,1057]" italics="true" pageId="4" pageNumber="39">–</emphasis>
|
||
a
|
||
</td>
|
||
<td id="768F5DC2CE78849CFAB1FB9FF899FB8D" box="[1367,1843,1039,1060]" gridcol="8" gridrow="35" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FB83FADCFB88" bold="true" box="[1367,1398,1043,1057]" pageId="4" pageNumber="39">188</emphasis>
|
||
, 124, 107, 105, 96, 91, 82, 81, 79, 77, 65
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FBB6F899FB92" box="[130,1843,1062,1083]" gridrow="36" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FBB6FF34FB92" box="[130,158,1062,1083]" gridcol="0" gridrow="36" pageId="4" pageNumber="39">36</th>
|
||
<td id="768F5DC2CE78849CFF51FBB6FDACFB92" box="[183,518,1062,1083]" gridcol="1" gridrow="36" pageId="4" pageNumber="39">8-MeSO-Octyl-CN</td>
|
||
<td id="768F5DC2CE78849CFD9EFBB6FD24FB92" box="[632,654,1062,1083]" gridcol="2" gridrow="36" pageId="4" pageNumber="39">I,L</td>
|
||
<td id="768F5DC2CE78849CFD43FBB6FD6EFB92" box="[677,708,1062,1083]" gridcol="3" gridrow="36" pageId="4" pageNumber="39">323</td>
|
||
<td id="768F5DC2CE78849CFD18FBB6FCC8FB92" box="[766,866,1062,1083]" gridcol="4" gridrow="36" pageId="4" pageNumber="39">C10H19NOS</td>
|
||
<td id="768F5DC2CE78849CFC2BFBB6FB95FB92" box="[973,1087,1062,1083]" gridcol="5" gridrow="36" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FBB6FB22FB92" box="[1104,1160,1062,1083]" gridcol="6" gridrow="36" pageId="4" pageNumber="39">202.13</td>
|
||
<td id="768F5DC2CE78849CFB78FBB6FA95FB92" box="[1182,1343,1062,1083]" gridcol="7" gridrow="36" pageId="4" pageNumber="39">0</td>
|
||
<td id="768F5DC2CE78849CFAB1FBB6F899FB92" box="[1367,1843,1062,1083]" gridcol="8" gridrow="36" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FBBAFADCFB91" bold="true" box="[1367,1398,1066,1080]" pageId="4" pageNumber="39">202</emphasis>
|
||
, 138, 121, 110, 105, 96, 95, 93, 91, 82, 81, 79, 77, 65
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FBADF899FBF8" box="[130,1843,1085,1105]" gridrow="37" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FBADFF34FBF8" box="[130,158,1085,1105]" gridcol="0" gridrow="37" pageId="4" pageNumber="39">37</th>
|
||
<td id="768F5DC2CE78849CFF51FBADFDACFBF8" box="[183,518,1085,1105]" gridcol="1" gridrow="37" pageId="4" pageNumber="39">8-MeSO-Octyl-NCS</td>
|
||
<td id="768F5DC2CE78849CFD9EFBADFD24FBF8" box="[632,654,1085,1105]" gridcol="2" gridrow="37" pageId="4" pageNumber="39">S,L</td>
|
||
<td id="768F5DC2CE78849CFD43FBADFD6EFBF8" box="[677,708,1085,1105]" gridcol="3" gridrow="37" pageId="4" pageNumber="39">483</td>
|
||
<td id="768F5DC2CE78849CFD18FBADFCC8FBF8" box="[766,866,1085,1105]" gridcol="4" gridrow="37" pageId="4" pageNumber="39">C10H19NOS2</td>
|
||
<td id="768F5DC2CE78849CFC2BFBADFB95FBF8" box="[973,1087,1085,1105]" gridcol="5" gridrow="37" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FBADFB22FBF8" box="[1104,1160,1085,1105]" gridcol="6" gridrow="37" pageId="4" pageNumber="39">234.10</td>
|
||
<td id="768F5DC2CE78849CFB78FBADFA95FBF8" box="[1182,1343,1085,1105]" gridcol="7" gridrow="37" pageId="4" pageNumber="39">0</td>
|
||
<td id="768F5DC2CE78849CFAB1FBADF899FBF8" box="[1367,1843,1085,1105]" gridcol="8" gridrow="37" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FBD1FADCFBE6" bold="true" box="[1367,1398,1089,1103]" pageId="4" pageNumber="39">234</emphasis>
|
||
, 175, 170, 161, 137, 136, 128, 122, 114,108, 69, 65, 55
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FBC4F899FBC1" box="[130,1843,1108,1128]" gridrow="38" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FBC4FF34FBC1" box="[130,158,1108,1128]" gridcol="0" gridrow="38" pageId="4" pageNumber="39">38</th>
|
||
<td id="768F5DC2CE78849CFF51FBC4FDACFBC1" box="[183,518,1108,1128]" gridcol="1" gridrow="38" pageId="4" pageNumber="39">8-MeSO-Octyl-CO2H</td>
|
||
<td id="768F5DC2CE78849CFD9EFBC4FD24FBC1" box="[632,654,1108,1128]" gridcol="2" gridrow="38" pageId="4" pageNumber="39">S,L</td>
|
||
<td id="768F5DC2CE78849CFD43FBC4FD6EFBC1" box="[677,708,1108,1128]" gridcol="3" gridrow="38" pageId="4" pageNumber="39">296</td>
|
||
<td id="768F5DC2CE78849CFD18FBC4FCC8FBC1" box="[766,866,1108,1128]" gridcol="4" gridrow="38" pageId="4" pageNumber="39">C10H20O3S</td>
|
||
<td id="768F5DC2CE78849CFC2BFBC4FB95FBC1" box="[973,1087,1108,1128]" gridcol="5" gridrow="38" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FBC4FB22FBC1" box="[1104,1160,1108,1128]" gridcol="6" gridrow="38" pageId="4" pageNumber="39">221.12</td>
|
||
<td id="768F5DC2CE78849CFB78FBC4FA95FBC1" box="[1182,1343,1108,1128]" gridcol="7" gridrow="38" pageId="4" pageNumber="39">1</td>
|
||
<td id="768F5DC2CE78849CFAB1FBC4F899FBC1" box="[1367,1843,1108,1128]" gridcol="8" gridrow="38" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FBC8FADCFBCF" bold="true" box="[1367,1398,1112,1126]" pageId="4" pageNumber="39">221</emphasis>
|
||
, 203, 175, 139, 137, 121, 119, 111, 109, 95, 93
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FBFBF899FBD6" box="[130,1843,1131,1151]" gridrow="39" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FBFBFF34FBD6" box="[130,158,1131,1151]" gridcol="0" gridrow="39" pageId="4" pageNumber="39">39</th>
|
||
<td id="768F5DC2CE78849CFF51FBFBFDACFBD6" box="[183,518,1131,1151]" gridcol="1" gridrow="39" pageId="4" pageNumber="39">8-MeSO-Octyl-CONH2</td>
|
||
<td id="768F5DC2CE78849CFD9EFBFBFD24FBD6" box="[632,654,1131,1151]" gridcol="2" gridrow="39" pageId="4" pageNumber="39">I</td>
|
||
<td id="768F5DC2CE78849CFD43FBFBFD6EFBD6" box="[677,708,1131,1151]" gridcol="3" gridrow="39" pageId="4" pageNumber="39">233</td>
|
||
<td id="768F5DC2CE78849CFD18FBFBFCC8FBD6" box="[766,866,1131,1151]" gridcol="4" gridrow="39" pageId="4" pageNumber="39">C10H21NO2S</td>
|
||
<td id="768F5DC2CE78849CFC2BFBFBFB95FBD6" box="[973,1087,1131,1151]" gridcol="5" gridrow="39" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FBFBFB22FBD6" box="[1104,1160,1131,1151]" gridcol="6" gridrow="39" pageId="4" pageNumber="39">220.14</td>
|
||
<td id="768F5DC2CE78849CFB78FBFBFA95FBD6" box="[1182,1343,1131,1151]" gridcol="7" gridrow="39" pageId="4" pageNumber="39">2</td>
|
||
<td id="768F5DC2CE78849CFAB1FBFBF899FBD6" box="[1367,1843,1131,1151]" gridcol="8" gridrow="39" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FBFEFADCFBD5" bold="true" box="[1367,1398,1134,1148]" pageId="4" pageNumber="39">220</emphasis>
|
||
, 203, 175, 139, 137, 121
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FB12F899FB3F" box="[130,1843,1154,1174]" gridrow="40" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FB12FF34FB3F" box="[130,158,1154,1174]" gridcol="0" gridrow="40" pageId="4" pageNumber="39">40</th>
|
||
<td id="768F5DC2CE78849CFF51FB12FDACFB3F" box="[183,518,1154,1174]" gridcol="1" gridrow="40" pageId="4" pageNumber="39">7-MeSO-Heptyl-NH2</td>
|
||
<td id="768F5DC2CE78849CFD9EFB12FD24FB3F" box="[632,654,1154,1174]" gridcol="2" gridrow="40" pageId="4" pageNumber="39">S</td>
|
||
<td id="768F5DC2CE78849CFD43FB12FD6EFB3F" box="[677,708,1154,1174]" gridcol="3" gridrow="40" pageId="4" pageNumber="39">61</td>
|
||
<td id="768F5DC2CE78849CFD18FB12FCC8FB3F" box="[766,866,1154,1174]" gridcol="4" gridrow="40" pageId="4" pageNumber="39">C8H19NOS</td>
|
||
<td id="768F5DC2CE78849CFC2BFB12FB95FB3F" box="[973,1087,1154,1174]" gridcol="5" gridrow="40" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FB12FB22FB3F" box="[1104,1160,1154,1174]" gridcol="6" gridrow="40" pageId="4" pageNumber="39">178.13</td>
|
||
<td id="768F5DC2CE78849CFB78FB12FA95FB3F" box="[1182,1343,1154,1174]" gridcol="7" gridrow="40" pageId="4" pageNumber="39">2</td>
|
||
<td id="768F5DC2CE78849CFAB1FB12F899FB3F" box="[1367,1843,1154,1174]" gridcol="8" gridrow="40" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FB15FADCFB3A" bold="true" box="[1367,1398,1157,1171]" pageId="4" pageNumber="39">178</emphasis>
|
||
, 161, 160, 114, 112, 97, 95
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FB09F899FB04" box="[130,1843,1177,1197]" gridrow="41" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FB09FF34FB04" box="[130,158,1177,1197]" gridcol="0" gridrow="41" pageId="4" pageNumber="39">41</th>
|
||
<td id="768F5DC2CE78849CFF51FB09FDACFB04" box="[183,518,1177,1197]" gridcol="1" gridrow="41" pageId="4" pageNumber="39">8-MeSO-Octyl-NH2</td>
|
||
<td id="768F5DC2CE78849CFD9EFB09FD24FB04" box="[632,654,1177,1197]" gridcol="2" gridrow="41" pageId="4" pageNumber="39">S,L</td>
|
||
<td id="768F5DC2CE78849CFD43FB09FD6EFB04" box="[677,708,1177,1197]" gridcol="3" gridrow="41" pageId="4" pageNumber="39">133</td>
|
||
<td id="768F5DC2CE78849CFD18FB09FCC8FB04" box="[766,866,1177,1197]" gridcol="4" gridrow="41" pageId="4" pageNumber="39">C9H21NOS</td>
|
||
<td id="768F5DC2CE78849CFC2BFB09FB95FB04" box="[973,1087,1177,1197]" gridcol="5" gridrow="41" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FB09FB22FB04" box="[1104,1160,1177,1197]" gridcol="6" gridrow="41" pageId="4" pageNumber="39">192.14</td>
|
||
<td id="768F5DC2CE78849CFB78FB09FA95FB04" box="[1182,1343,1177,1197]" gridcol="7" gridrow="41" pageId="4" pageNumber="39">2</td>
|
||
<td id="768F5DC2CE78849CFAB1FB09F899FB04" box="[1367,1843,1177,1197]" gridcol="8" gridrow="41" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FB0CFADCFB03" bold="true" box="[1367,1398,1180,1194]" pageId="4" pageNumber="39">192</emphasis>
|
||
, 175, 174, 128, 111, 109, 97
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FB3FF899FB6D" box="[130,1843,1199,1220]" gridrow="42" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FB3FFF34FB6D" box="[130,158,1199,1220]" gridcol="0" gridrow="42" pageId="4" pageNumber="39">42</th>
|
||
<td id="768F5DC2CE78849CFF51FB3FFDACFB6D" box="[183,518,1199,1220]" gridcol="1" gridrow="42" pageId="4" pageNumber="39">8-MeS-Octyl-NH2</td>
|
||
<td id="768F5DC2CE78849CFD9EFB3FFD24FB6D" box="[632,654,1199,1220]" gridcol="2" gridrow="42" pageId="4" pageNumber="39">I</td>
|
||
<td id="768F5DC2CE78849CFD43FB3FFD6EFB6D" box="[677,708,1199,1220]" gridcol="3" gridrow="42" pageId="4" pageNumber="39">311</td>
|
||
<td id="768F5DC2CE78849CFD18FB3FFCC8FB6D" box="[766,866,1199,1220]" gridcol="4" gridrow="42" pageId="4" pageNumber="39">C9H21NS</td>
|
||
<td id="768F5DC2CE78849CFC2BFB3FFB95FB6D" box="[973,1087,1199,1220]" gridcol="5" gridrow="42" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FB3FFB22FB6D" box="[1104,1160,1199,1220]" gridcol="6" gridrow="42" pageId="4" pageNumber="39">176.15</td>
|
||
<td id="768F5DC2CE78849CFB78FB3FFA95FB6D" box="[1182,1343,1199,1220]" gridcol="7" gridrow="42" pageId="4" pageNumber="39">2</td>
|
||
<td id="768F5DC2CE78849CFAB1FB3FF899FB6D" box="[1367,1843,1199,1220]" gridcol="8" gridrow="42" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FB23FADCFB68" bold="true" box="[1367,1398,1203,1217]" pageId="4" pageNumber="39">176</emphasis>
|
||
, 159, 128, 111, 103
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FB56F899FB73" box="[130,1843,1222,1242]" gridrow="43" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FB56FF34FB73" box="[130,158,1222,1242]" gridcol="0" gridrow="43" pageId="4" pageNumber="39">43</th>
|
||
<td id="768F5DC2CE78849CFF51FB56FDACFB73" box="[183,518,1222,1242]" gridcol="1" gridrow="43" pageId="4" pageNumber="39">Indol-3-ylmethylamine (I3CH2NH2)</td>
|
||
<td id="768F5DC2CE78849CFD9EFB56FD24FB73" box="[632,654,1222,1242]" gridcol="2" gridrow="43" pageId="4" pageNumber="39">S,L</td>
|
||
<td id="768F5DC2CE78849CFD43FB56FD6EFB73" box="[677,708,1222,1242]" gridcol="3" gridrow="43" pageId="4" pageNumber="39">111</td>
|
||
<td id="768F5DC2CE78849CFD18FB56FCC8FB73" box="[766,866,1222,1242]" gridcol="4" gridrow="43" pageId="4" pageNumber="39">C9H10N2</td>
|
||
<td id="768F5DC2CE78849CFC2BFB56FB95FB73" box="[973,1087,1222,1242]" gridcol="5" gridrow="43" pageId="4" pageNumber="39">[M+H-NH] + 3</td>
|
||
<td id="768F5DC2CE78849CFBB6FB56FB22FB73" box="[1104,1160,1222,1242]" gridcol="6" gridrow="43" pageId="4" pageNumber="39">130.07</td>
|
||
<td id="768F5DC2CE78849CFB78FB56FA95FB73" box="[1182,1343,1222,1242]" gridcol="7" gridrow="43" pageId="4" pageNumber="39">1b</td>
|
||
<td id="768F5DC2CE78849CFAB1FB56F899FB73" box="[1367,1843,1222,1242]" gridcol="8" gridrow="43" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FB5AFADCFB71" bold="true" box="[1367,1398,1226,1240]" pageId="4" pageNumber="39">130</emphasis>
|
||
, 128, 103, 77
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FB4DF899FB58" box="[130,1843,1245,1265]" gridrow="44" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FB4DFF34FB58" box="[130,158,1245,1265]" gridcol="0" gridrow="44" pageId="4" pageNumber="39">44</th>
|
||
<td id="768F5DC2CE78849CFF51FB4DFDACFB58" box="[183,518,1245,1265]" gridcol="1" gridrow="44" pageId="4" pageNumber="39">4-MeO-I3CH2NH2</td>
|
||
<td id="768F5DC2CE78849CFD9EFB4DFD24FB58" box="[632,654,1245,1265]" gridcol="2" gridrow="44" pageId="4" pageNumber="39">S</td>
|
||
<td id="768F5DC2CE78849CFD43FB4DFD6EFB58" box="[677,708,1245,1265]" gridcol="3" gridrow="44" pageId="4" pageNumber="39">192</td>
|
||
<td id="768F5DC2CE78849CFD18FB4DFCC8FB58" box="[766,866,1245,1265]" gridcol="4" gridrow="44" pageId="4" pageNumber="39">C10H12N2O</td>
|
||
<td id="768F5DC2CE78849CFC2BFB4DFB95FB58" box="[973,1087,1245,1265]" gridcol="5" gridrow="44" pageId="4" pageNumber="39">[M+H-NH] + 3</td>
|
||
<td id="768F5DC2CE78849CFBB6FB4DFB22FB58" box="[1104,1160,1245,1265]" gridcol="6" gridrow="44" pageId="4" pageNumber="39">160.08</td>
|
||
<td id="768F5DC2CE78849CFB78FB4DFA95FB58" box="[1182,1343,1245,1265]" gridcol="7" gridrow="44" pageId="4" pageNumber="39">1b</td>
|
||
<td id="768F5DC2CE78849CFAB1FB4DF899FB58" box="[1367,1843,1245,1265]" gridcol="8" gridrow="44" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FB71FADCFB46" bold="true" box="[1367,1398,1249,1263]" pageId="4" pageNumber="39">160</emphasis>
|
||
, 148, 145, 132, 130, 117
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FB64F899FAA1" box="[130,1843,1268,1288]" gridrow="45" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FB64FF34FAA1" box="[130,158,1268,1288]" gridcol="0" gridrow="45" pageId="4" pageNumber="39">45</th>
|
||
<td id="768F5DC2CE78849CFF51FB64FDACFAA1" box="[183,518,1268,1288]" gridcol="1" gridrow="45" pageId="4" pageNumber="39">1-MeO-I3CH2NH2</td>
|
||
<td id="768F5DC2CE78849CFD9EFB64FD24FAA1" box="[632,654,1268,1288]" gridcol="2" gridrow="45" pageId="4" pageNumber="39">I,L</td>
|
||
<td id="768F5DC2CE78849CFD43FB64FD6EFAA1" box="[677,708,1268,1288]" gridcol="3" gridrow="45" pageId="4" pageNumber="39">223</td>
|
||
<td id="768F5DC2CE78849CFD18FB64FCC8FAA1" box="[766,866,1268,1288]" gridcol="4" gridrow="45" pageId="4" pageNumber="39">C10H12N2O</td>
|
||
<td id="768F5DC2CE78849CFC2BFB64FB95FAA1" box="[973,1087,1268,1288]" gridcol="5" gridrow="45" pageId="4" pageNumber="39">[M+H-NH] + 3</td>
|
||
<td id="768F5DC2CE78849CFBB6FB64FB22FAA1" box="[1104,1160,1268,1288]" gridcol="6" gridrow="45" pageId="4" pageNumber="39">160.08</td>
|
||
<td id="768F5DC2CE78849CFB78FB64FA95FAA1" box="[1182,1343,1268,1288]" gridcol="7" gridrow="45" pageId="4" pageNumber="39">0b</td>
|
||
<td id="768F5DC2CE78849CFAB1FB64F899FAA1" box="[1367,1843,1268,1288]" gridcol="8" gridrow="45" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FB67FADCFAAC" bold="true" box="[1367,1398,1271,1285]" pageId="4" pageNumber="39">160</emphasis>
|
||
, 145, 132, 128, 117
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FA9AF899FAB6" box="[130,1843,1290,1311]" gridrow="46" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FA9AFF34FAB6" box="[130,158,1290,1311]" gridcol="0" gridrow="46" pageId="4" pageNumber="39">46</th>
|
||
<td id="768F5DC2CE78849CFF51FA9AFDACFAB6" box="[183,518,1290,1311]" gridcol="1" gridrow="46" pageId="4" pageNumber="39">Indole-3-carbaldehyde (I3CHO)</td>
|
||
<td id="768F5DC2CE78849CFD9EFA9AFD24FAB6" box="[632,654,1290,1311]" gridcol="2" gridrow="46" pageId="4" pageNumber="39">S</td>
|
||
<td id="768F5DC2CE78849CFD43FA9AFD6EFAB6" box="[677,708,1290,1311]" gridcol="3" gridrow="46" pageId="4" pageNumber="39">289</td>
|
||
<td id="768F5DC2CE78849CFD18FA9AFCC8FAB6" box="[766,866,1290,1311]" gridcol="4" gridrow="46" pageId="4" pageNumber="39">C9H7NO</td>
|
||
<td id="768F5DC2CE78849CFC2BFA9AFB95FAB6" box="[973,1087,1290,1311]" gridcol="5" gridrow="46" pageId="4" pageNumber="39">
|
||
[M
|
||
<emphasis id="B91AEAEECE787B67FC02FA9EFC5BFAB4" box="[996,1009,1294,1309]" italics="true" pageId="4" pageNumber="39">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE787B67FBE3FA9AFBA5FABC" box="[1029,1039,1290,1301]" italics="true" pageId="4" pageNumber="39">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE78849CFBB6FA9AFB22FAB6" box="[1104,1160,1290,1311]" gridcol="6" gridrow="46" pageId="4" pageNumber="39">144.04</td>
|
||
<td id="768F5DC2CE78849CFB78FA9AFA95FAB6" box="[1182,1343,1290,1311]" gridcol="7" gridrow="46" pageId="4" pageNumber="39">1</td>
|
||
<td id="768F5DC2CE78849CFAB1FA9AF899FAB6" box="[1367,1843,1290,1311]" gridcol="8" gridrow="46" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FA9EFADCFAB5" bold="true" box="[1367,1398,1294,1308]" pageId="4" pageNumber="39">144</emphasis>
|
||
, 142, 126, 116, 115
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FAB0F899FA9F" box="[130,1843,1312,1334]" gridrow="47" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FAB0FF34FA9F" box="[130,158,1312,1334]" gridcol="0" gridrow="47" pageId="4" pageNumber="39">47</th>
|
||
<td id="768F5DC2CE78849CFF51FAB0FDACFA9F" box="[183,518,1312,1334]" gridcol="1" gridrow="47" pageId="4" pageNumber="39">4-HO-I3CHO</td>
|
||
<td id="768F5DC2CE78849CFD9EFAB0FD24FA9F" box="[632,654,1312,1334]" gridcol="2" gridrow="47" pageId="4" pageNumber="39">S</td>
|
||
<td id="768F5DC2CE78849CFD43FAB0FD6EFA9F" box="[677,708,1312,1334]" gridcol="3" gridrow="47" pageId="4" pageNumber="39">307</td>
|
||
<td id="768F5DC2CE78849CFD18FAB0FCC8FA9F" box="[766,866,1312,1334]" gridcol="4" gridrow="47" pageId="4" pageNumber="39">C9H7NO2</td>
|
||
<td id="768F5DC2CE78849CFC2BFAB0FB95FA9F" box="[973,1087,1312,1334]" gridcol="5" gridrow="47" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FC02FAB4FC5BFA9A" box="[996,1009,1316,1331]" italics="true" pageId="4" pageNumber="39">–</emphasis>
|
||
<emphasis id="B91AEAEECE787B67FBE3FAB0FBA5FA82" box="[1029,1039,1312,1323]" italics="true" pageId="4" pageNumber="39">–</emphasis>
|
||
[M H]
|
||
</td>
|
||
<td id="768F5DC2CE78849CFBB6FAB0FB22FA9F" box="[1104,1160,1312,1334]" gridcol="6" gridrow="47" pageId="4" pageNumber="39">160.04</td>
|
||
<td id="768F5DC2CE78849CFB78FAB0FA95FA9F" box="[1182,1343,1312,1334]" gridcol="7" gridrow="47" pageId="4" pageNumber="39">2</td>
|
||
<td id="768F5DC2CE78849CFAB1FAB0F899FA9F" box="[1367,1843,1312,1334]" gridcol="8" gridrow="47" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FAB5FADCFA9A" bold="true" box="[1367,1398,1317,1331]" pageId="4" pageNumber="39">160</emphasis>
|
||
, 158, 132, 131, 130, 114, 104, 102
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FAA9F899FAE4" box="[130,1843,1337,1357]" gridrow="48" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FAA9FF34FAE4" box="[130,158,1337,1357]" gridcol="0" gridrow="48" pageId="4" pageNumber="39">48</th>
|
||
<td id="768F5DC2CE78849CFF51FAA9FDACFAE4" box="[183,518,1337,1357]" gridcol="1" gridrow="48" pageId="4" pageNumber="39">Indole-3-carboxylic acid (I3CO2H)</td>
|
||
<td id="768F5DC2CE78849CFD9EFAA9FD24FAE4" box="[632,654,1337,1357]" gridcol="2" gridrow="48" pageId="4" pageNumber="39">S,L</td>
|
||
<td id="768F5DC2CE78849CFD43FAA9FD6EFAE4" box="[677,708,1337,1357]" gridcol="3" gridrow="48" pageId="4" pageNumber="39">284</td>
|
||
<td id="768F5DC2CE78849CFD18FAA9FCC8FAE4" box="[766,866,1337,1357]" gridcol="4" gridrow="48" pageId="4" pageNumber="39">C9H7NO2</td>
|
||
<td id="768F5DC2CE78849CFC2BFAA9FB95FAE4" box="[973,1087,1337,1357]" gridcol="5" gridrow="48" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FAA9FB22FAE4" box="[1104,1160,1337,1357]" gridcol="6" gridrow="48" pageId="4" pageNumber="39">162.06</td>
|
||
<td id="768F5DC2CE78849CFB78FAA9FA95FAE4" box="[1182,1343,1337,1357]" gridcol="7" gridrow="48" pageId="4" pageNumber="39">2</td>
|
||
<td id="768F5DC2CE78849CFAB1FAA9F899FAE4" box="[1367,1843,1337,1357]" gridcol="8" gridrow="48" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FAACFADCFAE3" bold="true" box="[1367,1398,1340,1354]" pageId="4" pageNumber="39">162</emphasis>
|
||
, 144, 118
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FADEF899FACA" box="[130,1843,1358,1379]" gridrow="49" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FADEFF34FACA" box="[130,158,1358,1379]" gridcol="0" gridrow="49" pageId="4" pageNumber="39">49</th>
|
||
<td id="768F5DC2CE78849CFF51FADEFDACFACA" box="[183,518,1358,1379]" gridcol="1" gridrow="49" pageId="4" pageNumber="39">6-(Malonyl-GlcO)-I3CO2H</td>
|
||
<td id="768F5DC2CE78849CFD9EFADEFD24FACA" box="[632,654,1358,1379]" gridcol="2" gridrow="49" pageId="4" pageNumber="39">I,L</td>
|
||
<td id="768F5DC2CE78849CFD43FADEFD6EFACA" box="[677,708,1358,1379]" gridcol="3" gridrow="49" pageId="4" pageNumber="39">194</td>
|
||
<td id="768F5DC2CE78849CFD18FADEFCC8FACA" box="[766,866,1358,1379]" gridcol="4" gridrow="49" pageId="4" pageNumber="39">C18H19NO11</td>
|
||
<td id="768F5DC2CE78849CFC2BFADEFB95FACA" box="[973,1087,1358,1379]" gridcol="5" gridrow="49" pageId="4" pageNumber="39">
|
||
[M-H-CO]
|
||
<emphasis id="B91AEAEECE787B67FBC2FADEFB84FAF0" box="[1060,1070,1358,1369]" italics="true" pageId="4" pageNumber="39">–</emphasis>
|
||
2
|
||
</td>
|
||
<td id="768F5DC2CE78849CFBB6FADEFB22FACA" box="[1104,1160,1358,1379]" gridcol="6" gridrow="49" pageId="4" pageNumber="39">380.10</td>
|
||
<td id="768F5DC2CE78849CFB78FADEFA95FACA" box="[1182,1343,1358,1379]" gridcol="7" gridrow="49" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FB78FAC2FB01FAC8" box="[1182,1195,1362,1377]" italics="true" pageId="4" pageNumber="39">–</emphasis>
|
||
a
|
||
</td>
|
||
<td id="768F5DC2CE78849CFAB1FADEF899FACA" box="[1367,1843,1358,1379]" gridcol="8" gridrow="49" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FAC3FADCFAC8" bold="true" box="[1367,1398,1363,1377]" pageId="4" pageNumber="39">424</emphasis>
|
||
, 380, 338, 320, 218, 176, 175, 132
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FAF6F899FAD3" box="[130,1843,1382,1402]" gridrow="50" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FAF6FF34FAD3" box="[130,158,1382,1402]" gridcol="0" gridrow="50" pageId="4" pageNumber="39">50</th>
|
||
<td id="768F5DC2CE78849CFF51FAF6FDACFAD3" box="[183,518,1382,1402]" gridcol="1" gridrow="50" pageId="4" pageNumber="39">Unknown indole derivative</td>
|
||
<td id="768F5DC2CE78849CFD9EFAF6FD24FAD3" box="[632,654,1382,1402]" gridcol="2" gridrow="50" pageId="4" pageNumber="39">I</td>
|
||
<td id="768F5DC2CE78849CFD43FAF6FD6EFAD3" box="[677,708,1382,1402]" gridcol="3" gridrow="50" pageId="4" pageNumber="39">391</td>
|
||
<td id="768F5DC2CE78849CFD18FAF6FCC8FAD3" box="[766,866,1382,1402]" gridcol="4" gridrow="50" pageId="4" pageNumber="39">C10H9NO3</td>
|
||
<td id="768F5DC2CE78849CFC2BFAF6FB95FAD3" box="[973,1087,1382,1402]" gridcol="5" gridrow="50" pageId="4" pageNumber="39">[M+H] +</td>
|
||
<td id="768F5DC2CE78849CFBB6FAF6FB22FAD3" box="[1104,1160,1382,1402]" gridcol="6" gridrow="50" pageId="4" pageNumber="39">192.07</td>
|
||
<td id="768F5DC2CE78849CFB78FAF6FA95FAD3" box="[1182,1343,1382,1402]" gridcol="7" gridrow="50" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FB78FAF9FB01FAD1" box="[1182,1195,1385,1400]" italics="true" pageId="4" pageNumber="39">–</emphasis>
|
||
a
|
||
</td>
|
||
<td id="768F5DC2CE78849CFAB1FAF6F899FAD3" box="[1367,1843,1382,1402]" gridcol="8" gridrow="50" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FAFAFADCFAD1" bold="true" box="[1367,1398,1386,1400]" pageId="4" pageNumber="39">192</emphasis>
|
||
, 177, 174, 161, 159, 148, 133, 132, 117,116, 105, 104
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FAECF899FA38" box="[130,1843,1404,1425]" gridrow="51" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FAECFF34FA38" box="[130,158,1404,1425]" gridcol="0" gridrow="51" pageId="4" pageNumber="39">51</th>
|
||
<td id="768F5DC2CE78849CFF51FAECFDACFA38" box="[183,518,1404,1425]" gridcol="1" gridrow="51" pageId="4" pageNumber="39">
|
||
2,3-DHBA 3-
|
||
<emphasis id="B91AEAEECE787B67FEFBFAEFFE83FA26" box="[285,297,1407,1423]" italics="true" pageId="4" pageNumber="39">O</emphasis>
|
||
-Xyl
|
||
</td>
|
||
<td id="768F5DC2CE78849CFD9EFAECFD24FA38" box="[632,654,1404,1425]" gridcol="2" gridrow="51" pageId="4" pageNumber="39">S,L</td>
|
||
<td id="768F5DC2CE78849CFD43FAECFD6EFA38" box="[677,708,1404,1425]" gridcol="3" gridrow="51" pageId="4" pageNumber="39">176</td>
|
||
<td id="768F5DC2CE78849CFD18FAECFCC8FA38" box="[766,866,1404,1425]" gridcol="4" gridrow="51" pageId="4" pageNumber="39">C12H14O8</td>
|
||
<td id="768F5DC2CE78849CFC2BFAECFB95FA38" box="[973,1087,1404,1425]" gridcol="5" gridrow="51" pageId="4" pageNumber="39">
|
||
[M
|
||
<emphasis id="B91AEAEECE787B67FC02FA10FC5BFA26" box="[996,1009,1408,1423]" italics="true" pageId="4" pageNumber="39">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE787B67FBE3FAECFBA5FA2E" box="[1029,1039,1404,1415]" italics="true" pageId="4" pageNumber="39">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE78849CFBB6FAECFB22FA38" box="[1104,1160,1404,1425]" gridcol="6" gridrow="51" pageId="4" pageNumber="39">285.06</td>
|
||
<td id="768F5DC2CE78849CFB78FAECFA95FA38" box="[1182,1343,1404,1425]" gridcol="7" gridrow="51" pageId="4" pageNumber="39">5</td>
|
||
<td id="768F5DC2CE78849CFAB1FAECF899FA38" box="[1367,1843,1404,1425]" gridcol="8" gridrow="51" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FA11FADCFA26" bold="true" box="[1367,1398,1409,1423]" pageId="4" pageNumber="39">285</emphasis>
|
||
, 153, 109
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE78849CFF64FA03F899FA01" box="[130,1843,1427,1448]" gridrow="52" pageId="4" pageNumber="39">
|
||
<th id="768F5DC2CE78849CFF64FA03FF34FA01" box="[130,158,1427,1448]" gridcol="0" gridrow="52" pageId="4" pageNumber="39">52</th>
|
||
<td id="768F5DC2CE78849CFF51FA03FDACFA01" box="[183,518,1427,1448]" gridcol="1" gridrow="52" pageId="4" pageNumber="39">2,5-DHBA Pent</td>
|
||
<td id="768F5DC2CE78849CFD9EFA03FD24FA01" box="[632,654,1427,1448]" gridcol="2" gridrow="52" pageId="4" pageNumber="39">I,L</td>
|
||
<td id="768F5DC2CE78849CFD43FA03FD6EFA01" box="[677,708,1427,1448]" gridcol="3" gridrow="52" pageId="4" pageNumber="39">153</td>
|
||
<td id="768F5DC2CE78849CFD18FA03FCC8FA01" box="[766,866,1427,1448]" gridcol="4" gridrow="52" pageId="4" pageNumber="39">C12H14O8</td>
|
||
<td id="768F5DC2CE78849CFC2BFA03FB95FA01" box="[973,1087,1427,1448]" gridcol="5" gridrow="52" pageId="4" pageNumber="39">
|
||
[M
|
||
<emphasis id="B91AEAEECE787B67FC02FA07FC5BFA0F" box="[996,1009,1431,1446]" italics="true" pageId="4" pageNumber="39">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE787B67FBE3FA03FBA5FA37" box="[1029,1039,1427,1438]" italics="true" pageId="4" pageNumber="39">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE78849CFBB6FA03FB22FA01" box="[1104,1160,1427,1448]" gridcol="6" gridrow="52" pageId="4" pageNumber="39">285.06</td>
|
||
<td id="768F5DC2CE78849CFB78FA03FA95FA01" box="[1182,1343,1427,1448]" gridcol="7" gridrow="52" pageId="4" pageNumber="39">5</td>
|
||
<td id="768F5DC2CE78849CFAB1FA03F899FA01" box="[1367,1843,1427,1448]" gridcol="8" gridrow="52" pageId="4" pageNumber="39">
|
||
<emphasis id="B91AEAEECE787B67FAB1FA07FADCFA0C" bold="true" box="[1367,1398,1431,1445]" pageId="4" pageNumber="39">285</emphasis>
|
||
, 153, 152, 108
|
||
</td>
|
||
</tr>
|
||
</table>
|
||
</paragraph>
|
||
<tableNote id="76883772CE787B67F934FA2CF83AFA63" box="[1746,1936,1467,1482]" pageId="4" pageNumber="39">
|
||
<paragraph id="8BD136FCCE787B67F934FA2CF972FA63" box="[1746,1752,1468,1482]" pageId="4" pageNumber="39">(</paragraph>
|
||
<paragraph id="8BD136FCCE787B67F93EFA2BF888FA63" box="[1752,1826,1467,1482]" pageId="4" pageNumber="39">continued</paragraph>
|
||
<paragraph id="8BD136FCCE787B67F8CEFA2BF891FA63" box="[1832,1851,1467,1482]" pageId="4" pageNumber="39">on</paragraph>
|
||
<paragraph id="8BD136FCCE787B67F8A7FA2BF8CBFA63" box="[1857,1889,1467,1482]" pageId="4" pageNumber="39">next</paragraph>
|
||
<paragraph id="8BD136FCCE787B67F880FA2BF823FA63" box="[1894,1929,1467,1482]" pageId="4" pageNumber="39">page</paragraph>
|
||
<paragraph id="8BD136FCCE787B67F86CFA2CF83AFA63" box="[1930,1936,1468,1482]" pageId="4" pageNumber="39">)</paragraph>
|
||
</tableNote>
|
||
<caption id="DF116674CE797B66FF8DFFCDFEA9FFC2" box="[107,259,92,107]" isContinuationCaption="true" pageId="5" pageNumber="40" startId="5.[107,151,93,107]" targetBox="[130,1914,126,1422]" targetIsTable="true" targetPageId="5">
|
||
<paragraph id="8BD136FCCE797B66FF8DFFCDFEA9FFC2" blockId="5.[107,259,92,107]" box="[107,259,92,107]" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FF8DFFCDFF0DFFC2" bold="true" box="[107,167,93,107]" pageId="5" pageNumber="40">Table 1</emphasis>
|
||
(
|
||
<emphasis id="B91AEAEECE797B66FF55FFCCFF57FFC2" box="[179,253,92,107]" italics="true" pageId="5" pageNumber="40">continued</emphasis>
|
||
)
|
||
</paragraph>
|
||
</caption>
|
||
<paragraph id="8BD136FCCE797B66FF64FF12FD6EFA27" pageId="5" pageNumber="40">
|
||
<table id="F96EC45CCE79849CFF64FFEEF8D0FA27" box="[130,1914,126,1422]" colsContinueFrom="4.[130,1843,195,1448]" colsContinueIn="6.[115,320,200,1983]" gridcols="9" gridrows="56" pageId="5" pageNumber="40">
|
||
<tr id="355E34BECE79849CFF64FFEEF8D0FF38" box="[130,1914,126,145]" gridrow="0" pageId="5" pageNumber="40" rowspan-6="1">
|
||
<th id="768F5DC2CE79849CFF64FFEEFF34FF38" box="[130,158,126,145]" gridcol="0" gridrow="0" pageId="5" pageNumber="40">No.</th>
|
||
<th id="768F5DC2CE79849CFF51FFEEFDEAFF38" box="[183,576,126,145]" gridcol="1" gridrow="0" pageId="5" pageNumber="40">Compound</th>
|
||
<th id="768F5DC2CE79849CFD9EFFEEFD24FF38" box="[632,654,126,145]" gridcol="2" gridrow="0" pageId="5" pageNumber="40">vl1</th>
|
||
<th id="768F5DC2CE79849CFD43FFEEFD60FF38" box="[677,714,126,145]" gridcol="3" gridrow="0" pageId="5" pageNumber="40">tr</th>
|
||
<th id="768F5DC2CE79849CFD18FFEEFCCFFF38" box="[766,869,126,145]" gridcol="4" gridrow="0" pageId="5" pageNumber="40">Elemental</th>
|
||
<th id="768F5DC2CE79849CFC2BFFEEFB95FF38" box="[973,1087,126,145]" gridcol="5" gridrow="0" pageId="5" pageNumber="40">Quantifier ion</th>
|
||
<th id="768F5DC2CE79849CFB78FFEEFA95FF38" box="[1182,1343,126,145]" gridcol="7" gridrow="0" pageId="5" pageNumber="40"># exchang. protons2</th>
|
||
<th id="768F5DC2CE79849CFAB1FFEEF8D0FF38" box="[1367,1914,126,145]" gridcol="8" gridrow="0" pageId="5" pageNumber="40">Observed fragment ions upon CID3</th>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FF08F8D0FF1B" box="[130,1914,152,178]" gridrow="1" pageId="5" pageNumber="40" rowspan-0="1" rowspan-1="1" rowspan-2="1" rowspan-7="1">
|
||
<td id="768F5DC2CE79849CFD43FF08FD60FF1B" box="[677,714,152,178]" gridcol="3" gridrow="1" pageId="5" pageNumber="40">[s]</td>
|
||
<td id="768F5DC2CE79849CFD18FF08FCCFFF1B" box="[766,869,152,178]" gridcol="4" gridrow="1" pageId="5" pageNumber="40">composition</td>
|
||
<td id="768F5DC2CE79849CFC2BFF08FB95FF1B" box="[973,1087,152,178]" gridcol="5" gridrow="1" pageId="5" pageNumber="40">Type</td>
|
||
<td id="768F5DC2CE79849CFBB6FF08FB22FF1B" box="[1104,1160,152,178]" gridcol="6" gridrow="1" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FBB6FF33FBF5FF1B" box="[1104,1119,163,178]" italics="true" pageId="5" pageNumber="40">m</emphasis>
|
||
/
|
||
<emphasis id="B91AEAEECE797B66FB80FF33FBC4FF1B" box="[1126,1134,163,178]" italics="true" pageId="5" pageNumber="40">z</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFAB1FF08F8D0FF1B" box="[1367,1914,152,178]" gridcol="8" gridrow="1" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FABAFF08FAC1FF0E" box="[1372,1387,152,167]" italics="true" pageId="5" pageNumber="40">m</emphasis>
|
||
/
|
||
<emphasis id="B91AEAEECE797B66FA94FF08FAD0FF0E" box="[1394,1402,152,167]" italics="true" pageId="5" pageNumber="40">z</emphasis>
|
||
, precursor ion marked in bold
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FF50F8D0FF7F" box="[130,1914,192,214]" gridrow="2" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FF50FF34FF7F" box="[130,158,192,214]" gridcol="0" gridrow="2" pageId="5" pageNumber="40">53</th>
|
||
<td id="768F5DC2CE79849CFF51FF50FDEAFF7F" box="[183,576,192,214]" gridcol="1" gridrow="2" pageId="5" pageNumber="40">9,10-Dihydrohydroxy-JA Sulfate</td>
|
||
<td id="768F5DC2CE79849CFD9EFF50FD24FF7F" box="[632,654,192,214]" gridcol="2" gridrow="2" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FF50FD60FF7F" box="[677,714,192,214]" gridcol="3" gridrow="2" pageId="5" pageNumber="40">222</td>
|
||
<td id="768F5DC2CE79849CFD18FF50FCCFFF7F" box="[766,869,192,214]" gridcol="4" gridrow="2" pageId="5" pageNumber="40">C12H20O7S</td>
|
||
<td id="768F5DC2CE79849CFC2BFF50FB95FF7F" box="[973,1087,192,214]" gridcol="5" gridrow="2" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FC02FF55FC5BFF7D" box="[996,1009,197,212]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
<emphasis id="B91AEAEECE797B66FBE3FF50FBA5FF62" box="[1029,1039,192,203]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
[M H]
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FF50FB22FF7F" box="[1104,1160,192,214]" gridcol="6" gridrow="2" pageId="5" pageNumber="40">307.09</td>
|
||
<td id="768F5DC2CE79849CFB78FF50FA95FF7F" box="[1182,1343,192,214]" gridcol="7" gridrow="2" pageId="5" pageNumber="40">2</td>
|
||
<td id="768F5DC2CE79849CFAB1FF50F8D0FF7F" box="[1367,1914,192,214]" gridcol="8" gridrow="2" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FF55FADCFF7A" bold="true" box="[1367,1398,197,211]" pageId="5" pageNumber="40">307</emphasis>
|
||
, 227, 97
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FF47F8D0FF44" box="[130,1914,215,237]" gridrow="3" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FF47FF34FF44" box="[130,158,215,237]" gridcol="0" gridrow="3" pageId="5" pageNumber="40">54</th>
|
||
<td id="768F5DC2CE79849CFF51FF47FDEAFF44" box="[183,576,215,237]" gridcol="1" gridrow="3" pageId="5" pageNumber="40">Coniferin</td>
|
||
<td id="768F5DC2CE79849CFD9EFF47FD24FF44" box="[632,654,215,237]" gridcol="2" gridrow="3" pageId="5" pageNumber="40">I,L</td>
|
||
<td id="768F5DC2CE79849CFD43FF47FD60FF44" box="[677,714,215,237]" gridcol="3" gridrow="3" pageId="5" pageNumber="40">179</td>
|
||
<td id="768F5DC2CE79849CFD18FF47FCCFFF44" box="[766,869,215,237]" gridcol="4" gridrow="3" pageId="5" pageNumber="40">C16H22O8</td>
|
||
<td id="768F5DC2CE79849CFC2BFF47FB95FF44" box="[973,1087,215,237]" gridcol="5" gridrow="3" pageId="5" pageNumber="40">[M+Na] +</td>
|
||
<td id="768F5DC2CE79849CFBB6FF47FB22FF44" box="[1104,1160,215,237]" gridcol="6" gridrow="3" pageId="5" pageNumber="40">365.12</td>
|
||
<td id="768F5DC2CE79849CFB78FF47FA95FF44" box="[1182,1343,215,237]" gridcol="7" gridrow="3" pageId="5" pageNumber="40">5</td>
|
||
<td id="768F5DC2CE79849CFAB1FF47F8D0FF44" box="[1367,1914,215,237]" gridcol="8" gridrow="3" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FF4CFADCFF43" bold="true" box="[1367,1398,220,234]" pageId="5" pageNumber="40">387</emphasis>
|
||
([M-H+FA]
|
||
<emphasis id="B91AEAEECE797B66FA37FF47FA71FF4B" box="[1489,1499,215,226]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
), 341, 207, 179
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FF7EF8D0FEAA" box="[130,1914,238,259]" gridrow="4" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FF7EFF34FEAA" box="[130,158,238,259]" gridcol="0" gridrow="4" pageId="5" pageNumber="40">55</th>
|
||
<td id="768F5DC2CE79849CFF51FF7EFDEAFEAA" box="[183,576,238,259]" gridcol="1" gridrow="4" pageId="5" pageNumber="40">Syringin</td>
|
||
<td id="768F5DC2CE79849CFD9EFF7EFD24FEAA" box="[632,654,238,259]" gridcol="2" gridrow="4" pageId="5" pageNumber="40">I,L</td>
|
||
<td id="768F5DC2CE79849CFD43FF7EFD60FEAA" box="[677,714,238,259]" gridcol="3" gridrow="4" pageId="5" pageNumber="40">193</td>
|
||
<td id="768F5DC2CE79849CFD18FF7EFCCFFEAA" box="[766,869,238,259]" gridcol="4" gridrow="4" pageId="5" pageNumber="40">C17H24O9</td>
|
||
<td id="768F5DC2CE79849CFC2BFF7EFB95FEAA" box="[973,1087,238,259]" gridcol="5" gridrow="4" pageId="5" pageNumber="40">[M+Na] +</td>
|
||
<td id="768F5DC2CE79849CFBB6FF7EFB22FEAA" box="[1104,1160,238,259]" gridcol="6" gridrow="4" pageId="5" pageNumber="40">395.13</td>
|
||
<td id="768F5DC2CE79849CFB78FF7EFA95FEAA" box="[1182,1343,238,259]" gridcol="7" gridrow="4" pageId="5" pageNumber="40">5</td>
|
||
<td id="768F5DC2CE79849CFAB1FF7EF8D0FEAA" box="[1367,1914,238,259]" gridcol="8" gridrow="4" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FF63FADCFEA8" bold="true" box="[1367,1398,243,257]" pageId="5" pageNumber="40">417</emphasis>
|
||
([M-H+FA]
|
||
<emphasis id="B91AEAEECE797B66FA37FF7EFA71FF50" box="[1489,1499,238,249]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
), 209, 207,194
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FE95F8D0FEB3" box="[130,1914,261,282]" gridrow="5" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FE95FF34FEB3" box="[130,158,261,282]" gridcol="0" gridrow="5" pageId="5" pageNumber="40">56</th>
|
||
<td id="768F5DC2CE79849CFF51FE95FDEAFEB3" box="[183,576,261,282]" gridcol="1" gridrow="5" pageId="5" pageNumber="40">
|
||
G(8-
|
||
<emphasis id="B91AEAEECE797B66FF3DFE98FF4DFEB1" box="[219,231,264,280]" italics="true" pageId="5" pageNumber="40">O</emphasis>
|
||
-4)G
|
||
</td>
|
||
<td id="768F5DC2CE79849CFD9EFE95FD24FEB3" box="[632,654,261,282]" gridcol="2" gridrow="5" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FE95FD60FEB3" box="[677,714,261,282]" gridcol="3" gridrow="5" pageId="5" pageNumber="40">275/</td>
|
||
<td id="768F5DC2CE79849CFD18FE95FCCFFEB3" box="[766,869,261,282]" gridcol="4" gridrow="5" pageId="5" pageNumber="40">C20H24O7</td>
|
||
<td id="768F5DC2CE79849CFC2BFE95FB95FEB3" box="[973,1087,261,282]" gridcol="5" gridrow="5" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FE99FC5BFEB1" box="[996,1009,265,280]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FE95FBA5FEB9" box="[1029,1039,261,272]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FE95FB22FEB3" box="[1104,1160,261,282]" gridcol="6" gridrow="5" pageId="5" pageNumber="40">375.15</td>
|
||
<td id="768F5DC2CE79849CFB78FE95FA95FEB3" box="[1182,1343,261,282]" gridcol="7" gridrow="5" pageId="5" pageNumber="40">4</td>
|
||
<td id="768F5DC2CE79849CFAB1FE95F8D0FEB3" box="[1367,1914,261,282]" gridcol="8" gridrow="5" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FE9AFADCFEB1" bold="true" box="[1367,1398,266,280]" pageId="5" pageNumber="40">375</emphasis>
|
||
, 327, 195, 179, 165
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FEB1F8D0FE86" box="[130,1914,289,303]" gridrow="6" pageId="5" pageNumber="40" rowspan-0="1" rowspan-1="1" rowspan-2="1" rowspan-4="1" rowspan-5="1" rowspan-6="1" rowspan-7="1" rowspan-8="1">
|
||
<td id="768F5DC2CE79849CFD43FEB1FD60FE86" box="[677,714,289,303]" gridcol="3" gridrow="6" pageId="5" pageNumber="40">281</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FEA3F8D0FEE1" box="[130,1914,307,328]" gridrow="7" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FEA3FF34FEE1" box="[130,158,307,328]" gridcol="0" gridrow="7" pageId="5" pageNumber="40">57</th>
|
||
<td id="768F5DC2CE79849CFF51FEA3FDEAFEE1" box="[183,576,307,328]" gridcol="1" gridrow="7" pageId="5" pageNumber="40">
|
||
G(8-
|
||
<emphasis id="B91AEAEECE797B66FF3DFEA6FF4DFEEF" box="[219,231,310,326]" italics="true" pageId="5" pageNumber="40">O</emphasis>
|
||
-4)S Glycerol
|
||
</td>
|
||
<td id="768F5DC2CE79849CFD9EFEA3FD24FEE1" box="[632,654,307,328]" gridcol="2" gridrow="7" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FEA3FD60FEE1" box="[677,714,307,328]" gridcol="3" gridrow="7" pageId="5" pageNumber="40">188/</td>
|
||
<td id="768F5DC2CE79849CFD18FEA3FCCFFEE1" box="[766,869,307,328]" gridcol="4" gridrow="7" pageId="5" pageNumber="40">C21H28O10</td>
|
||
<td id="768F5DC2CE79849CFC2BFEA3FB95FEE1" box="[973,1087,307,328]" gridcol="5" gridrow="7" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FEA7FC5BFEEF" box="[996,1009,311,326]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FEA3FBA5FE97" box="[1029,1039,307,318]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FEA3FB22FEE1" box="[1104,1160,307,328]" gridcol="6" gridrow="7" pageId="5" pageNumber="40">439.16</td>
|
||
<td id="768F5DC2CE79849CFB78FEA3FA95FEE1" box="[1182,1343,307,328]" gridcol="7" gridrow="7" pageId="5" pageNumber="40">6</td>
|
||
<td id="768F5DC2CE79849CFAB1FEA3F8D0FEE1" box="[1367,1914,307,328]" gridcol="8" gridrow="7" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FEA7FADCFEEC" bold="true" box="[1367,1398,311,325]" pageId="5" pageNumber="40">439</emphasis>
|
||
, 391, 243, 195
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FEDEF8D0FEF5" box="[130,1914,334,348]" gridrow="8" pageId="5" pageNumber="40" rowspan-0="1" rowspan-1="1" rowspan-2="1" rowspan-4="1" rowspan-5="1" rowspan-6="1" rowspan-7="1" rowspan-8="1">
|
||
<td id="768F5DC2CE79849CFD43FEDEFD60FEF5" box="[677,714,334,348]" gridcol="3" gridrow="8" pageId="5" pageNumber="40">192</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FEF0F8D0FEDF" box="[130,1914,352,374]" gridrow="9" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FEF0FF34FEDF" box="[130,158,352,374]" gridcol="0" gridrow="9" pageId="5" pageNumber="40">58</th>
|
||
<td id="768F5DC2CE79849CFF51FEF0FDEAFEDF" box="[183,576,352,374]" gridcol="1" gridrow="9" pageId="5" pageNumber="40">G(8-5)G</td>
|
||
<td id="768F5DC2CE79849CFD9EFEF0FD24FEDF" box="[632,654,352,374]" gridcol="2" gridrow="9" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FEF0FD60FEDF" box="[677,714,352,374]" gridcol="3" gridrow="9" pageId="5" pageNumber="40">344</td>
|
||
<td id="768F5DC2CE79849CFD18FEF0FCCFFEDF" box="[766,869,352,374]" gridcol="4" gridrow="9" pageId="5" pageNumber="40">C20H22O6</td>
|
||
<td id="768F5DC2CE79849CFC2BFEF0FB95FEDF" box="[973,1087,352,374]" gridcol="5" gridrow="9" pageId="5" pageNumber="40">
|
||
O]
|
||
<emphasis id="B91AEAEECE797B66FBC1FEF0FB9BFEC2" box="[1063,1073,352,363]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
[M-H-H2
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FEF0FB22FEDF" box="[1104,1160,352,374]" gridcol="6" gridrow="9" pageId="5" pageNumber="40">339.12</td>
|
||
<td id="768F5DC2CE79849CFB78FEF0FA95FEDF" box="[1182,1343,352,374]" gridcol="7" gridrow="9" pageId="5" pageNumber="40">3</td>
|
||
<td id="768F5DC2CE79849CFAB1FEF0F8D0FEDF" box="[1367,1914,352,374]" gridcol="8" gridrow="9" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FEF5FADCFEDA" bold="true" box="[1367,1398,357,371]" pageId="5" pageNumber="40">357</emphasis>
|
||
([M
|
||
<emphasis id="B91AEAEECE797B66FA7EFEF4FA0FFEDA" box="[1432,1445,356,371]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
<emphasis id="B91AEAEECE797B66FA5FFEF0FA69FEC2" box="[1465,1475,352,363]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
), 339, 327, 324 H]
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FEE7F8D0FE24" box="[130,1914,375,397]" gridrow="10" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FEE7FF34FE24" box="[130,158,375,397]" gridcol="0" gridrow="10" pageId="5" pageNumber="40">59</th>
|
||
<td id="768F5DC2CE79849CFF51FEE7FDEAFE24" box="[183,576,375,397]" gridcol="1" gridrow="10" pageId="5" pageNumber="40">S(8-5)G</td>
|
||
<td id="768F5DC2CE79849CFD9EFEE7FD24FE24" box="[632,654,375,397]" gridcol="2" gridrow="10" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FEE7FD60FE24" box="[677,714,375,397]" gridcol="3" gridrow="10" pageId="5" pageNumber="40">340</td>
|
||
<td id="768F5DC2CE79849CFD18FEE7FCCFFE24" box="[766,869,375,397]" gridcol="4" gridrow="10" pageId="5" pageNumber="40">C21H24O7</td>
|
||
<td id="768F5DC2CE79849CFC2BFEE7FB95FE24" box="[973,1087,375,397]" gridcol="5" gridrow="10" pageId="5" pageNumber="40">[M-H-H O] - 2</td>
|
||
<td id="768F5DC2CE79849CFBB6FEE7FB22FE24" box="[1104,1160,375,397]" gridcol="6" gridrow="10" pageId="5" pageNumber="40">369.13</td>
|
||
<td id="768F5DC2CE79849CFB78FEE7FA95FE24" box="[1182,1343,375,397]" gridcol="7" gridrow="10" pageId="5" pageNumber="40">3</td>
|
||
<td id="768F5DC2CE79849CFAB1FEE7F8D0FE24" box="[1367,1914,375,397]" gridcol="8" gridrow="10" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FEECFADCFE23" bold="true" box="[1367,1398,380,394]" pageId="5" pageNumber="40">387</emphasis>
|
||
([M
|
||
<emphasis id="B91AEAEECE797B66FA7EFEEBFA0FFE23" box="[1432,1445,379,394]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FA5FFEE7FA69FE2B" box="[1465,1475,375,386]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
), 369, 357, 354
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FE1EF8D0FE0A" box="[130,1914,398,419]" gridrow="11" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FE1EFF34FE0A" box="[130,158,398,419]" gridcol="0" gridrow="11" pageId="5" pageNumber="40">60</th>
|
||
<td id="768F5DC2CE79849CFF51FE1EFDEAFE0A" box="[183,576,398,419]" gridcol="1" gridrow="11" pageId="5" pageNumber="40">S(8-8)S</td>
|
||
<td id="768F5DC2CE79849CFD9EFE1EFD24FE0A" box="[632,654,398,419]" gridcol="2" gridrow="11" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FE1EFD60FE0A" box="[677,714,398,419]" gridcol="3" gridrow="11" pageId="5" pageNumber="40">377</td>
|
||
<td id="768F5DC2CE79849CFD18FE1EFCCFFE0A" box="[766,869,398,419]" gridcol="4" gridrow="11" pageId="5" pageNumber="40">C22H26O8</td>
|
||
<td id="768F5DC2CE79849CFC2BFE1EFB95FE0A" box="[973,1087,398,419]" gridcol="5" gridrow="11" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FE02FC5BFE08" box="[996,1009,402,417]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FE1EFBA5FE30" box="[1029,1039,398,409]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FE1EFB22FE0A" box="[1104,1160,398,419]" gridcol="6" gridrow="11" pageId="5" pageNumber="40">417.16</td>
|
||
<td id="768F5DC2CE79849CFB78FE1EFA95FE0A" box="[1182,1343,398,419]" gridcol="7" gridrow="11" pageId="5" pageNumber="40">2</td>
|
||
<td id="768F5DC2CE79849CFAB1FE1EF8D0FE0A" box="[1367,1914,398,419]" gridcol="8" gridrow="11" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FE03FADCFE08" bold="true" box="[1367,1398,403,417]" pageId="5" pageNumber="40">417</emphasis>
|
||
, 402, 387, 181, 166
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FE35F8D0FE13" box="[130,1914,421,442]" gridrow="12" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FE35FF34FE13" box="[130,158,421,442]" gridcol="0" gridrow="12" pageId="5" pageNumber="40">61</th>
|
||
<td id="768F5DC2CE79849CFF51FE35FDEAFE13" box="[183,576,421,442]" gridcol="1" gridrow="12" pageId="5" pageNumber="40">Lariciresinol</td>
|
||
<td id="768F5DC2CE79849CFD9EFE35FD24FE13" box="[632,654,421,442]" gridcol="2" gridrow="12" pageId="5" pageNumber="40">S,L</td>
|
||
<td id="768F5DC2CE79849CFD43FE35FD60FE13" box="[677,714,421,442]" gridcol="3" gridrow="12" pageId="5" pageNumber="40">337</td>
|
||
<td id="768F5DC2CE79849CFD18FE35FCCFFE13" box="[766,869,421,442]" gridcol="4" gridrow="12" pageId="5" pageNumber="40">C20H24O6</td>
|
||
<td id="768F5DC2CE79849CFC2BFE35FB95FE13" box="[973,1087,421,442]" gridcol="5" gridrow="12" pageId="5" pageNumber="40">[M-H-</td>
|
||
<td id="768F5DC2CE79849CFBB6FE35FB22FE13" box="[1104,1160,421,442]" gridcol="6" gridrow="12" pageId="5" pageNumber="40">329.14</td>
|
||
<td id="768F5DC2CE79849CFB78FE35FA95FE13" box="[1182,1343,421,442]" gridcol="7" gridrow="12" pageId="5" pageNumber="40">3</td>
|
||
<td id="768F5DC2CE79849CFAB1FE35F8D0FE13" box="[1367,1914,421,442]" gridcol="8" gridrow="12" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FE3AFADCFE11" bold="true" box="[1367,1398,426,440]" pageId="5" pageNumber="40">359</emphasis>
|
||
([M
|
||
<emphasis id="B91AEAEECE797B66FA7EFE39FA0FFE11" box="[1432,1445,425,440]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FA5FFE35FA69FE19" box="[1465,1475,421,432]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
), 344, 329, 192, 178, 175, 164, 160, 159
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FE2CF8D0FE78" box="[130,1914,444,465]" gridrow="13" pageId="5" pageNumber="40" rowspan-0="1" rowspan-1="1" rowspan-2="1" rowspan-3="1" rowspan-4="1" rowspan-6="1" rowspan-7="1" rowspan-8="1">
|
||
<td id="768F5DC2CE79849CFC2BFE2CFB95FE78" box="[973,1087,444,465]" gridcol="5" gridrow="13" pageId="5" pageNumber="40">
|
||
CH O]
|
||
<emphasis id="B91AEAEECE797B66FC19FE2CFBA3FE6E" box="[1023,1033,444,455]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
2
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FE43F8D0FE41" box="[130,1914,467,488]" gridrow="14" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FE43FF34FE41" box="[130,158,467,488]" gridcol="0" gridrow="14" pageId="5" pageNumber="40">62</th>
|
||
<td id="768F5DC2CE79849CFF51FE43FDEAFE41" box="[183,576,467,488]" gridcol="1" gridrow="14" pageId="5" pageNumber="40">Lariciresinol Hex</td>
|
||
<td id="768F5DC2CE79849CFD9EFE43FD24FE41" box="[632,654,467,488]" gridcol="2" gridrow="14" pageId="5" pageNumber="40">I,L</td>
|
||
<td id="768F5DC2CE79849CFD43FE43FD60FE41" box="[677,714,467,488]" gridcol="3" gridrow="14" pageId="5" pageNumber="40">272</td>
|
||
<td id="768F5DC2CE79849CFD18FE43FCCFFE41" box="[766,869,467,488]" gridcol="4" gridrow="14" pageId="5" pageNumber="40">C26H34O11</td>
|
||
<td id="768F5DC2CE79849CFC2BFE43FB95FE41" box="[973,1087,467,488]" gridcol="5" gridrow="14" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FE47FC5BFE4F" box="[996,1009,471,486]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FE43FBA5FE77" box="[1029,1039,467,478]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FE43FB22FE41" box="[1104,1160,467,488]" gridcol="6" gridrow="14" pageId="5" pageNumber="40">521.20</td>
|
||
<td id="768F5DC2CE79849CFB78FE43FA95FE41" box="[1182,1343,467,488]" gridcol="7" gridrow="14" pageId="5" pageNumber="40">6</td>
|
||
<td id="768F5DC2CE79849CFAB1FE43F8D0FE41" box="[1367,1914,467,488]" gridcol="8" gridrow="14" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FE47FADCFE4C" bold="true" box="[1367,1398,471,485]" pageId="5" pageNumber="40">521</emphasis>
|
||
, 359, 329, 192, 178, 175, 160
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FE7AF8D0FE56" box="[130,1914,490,511]" gridrow="15" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FE7AFF34FE56" box="[130,158,490,511]" gridcol="0" gridrow="15" pageId="5" pageNumber="40">63</th>
|
||
<td id="768F5DC2CE79849CFF51FE7AFDEAFE56" box="[183,576,490,511]" gridcol="1" gridrow="15" pageId="5" pageNumber="40">
|
||
G(8-
|
||
<emphasis id="B91AEAEECE797B66FF3DFE7DFF4DFE54" box="[219,231,493,509]" italics="true" pageId="5" pageNumber="40">O</emphasis>
|
||
-4)S(8-5)G
|
||
</td>
|
||
<td id="768F5DC2CE79849CFD9EFE7AFD24FE56" box="[632,654,490,511]" gridcol="2" gridrow="15" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FE7AFD60FE56" box="[677,714,490,511]" gridcol="3" gridrow="15" pageId="5" pageNumber="40">366/</td>
|
||
<td id="768F5DC2CE79849CFD18FE7AFCCFFE56" box="[766,869,490,511]" gridcol="4" gridrow="15" pageId="5" pageNumber="40">C31H36O11</td>
|
||
<td id="768F5DC2CE79849CFC2BFE7AFB95FE56" box="[973,1087,490,511]" gridcol="5" gridrow="15" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FE7EFC5BFE54" box="[996,1009,494,509]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FE7AFBA5FE5C" box="[1029,1039,490,501]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FE7AFB22FE56" box="[1104,1160,490,511]" gridcol="6" gridrow="15" pageId="5" pageNumber="40">583.22</td>
|
||
<td id="768F5DC2CE79849CFB78FE7AFA95FE56" box="[1182,1343,490,511]" gridcol="7" gridrow="15" pageId="5" pageNumber="40">5</td>
|
||
<td id="768F5DC2CE79849CFAB1FE7AF8D0FE56" box="[1367,1914,490,511]" gridcol="8" gridrow="15" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FE7EFADCFE55" bold="true" box="[1367,1398,494,508]" pageId="5" pageNumber="40">583</emphasis>
|
||
, 535, 505, 369, 357, 195, 165
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FD95F8D0FDBA" box="[130,1914,517,531]" gridrow="16" pageId="5" pageNumber="40" rowspan-0="1" rowspan-1="1" rowspan-2="1" rowspan-4="1" rowspan-5="1" rowspan-6="1" rowspan-7="1" rowspan-8="1">
|
||
<td id="768F5DC2CE79849CFD43FD95FD60FDBA" box="[677,714,517,531]" gridcol="3" gridrow="16" pageId="5" pageNumber="40">379</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FD87F8D0FD84" box="[130,1914,535,557]" gridrow="17" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FD87FF34FD84" box="[130,158,535,557]" gridcol="0" gridrow="17" pageId="5" pageNumber="40">64</th>
|
||
<td id="768F5DC2CE79849CFF51FD87FDEAFD84" box="[183,576,535,557]" gridcol="1" gridrow="17" pageId="5" pageNumber="40">
|
||
G(8-
|
||
<emphasis id="B91AEAEECE797B66FF3DFD8AFF4DFD83" box="[219,231,538,554]" italics="true" pageId="5" pageNumber="40">O</emphasis>
|
||
-4)S(8-8)S
|
||
</td>
|
||
<td id="768F5DC2CE79849CFD9EFD87FD24FD84" box="[632,654,535,557]" gridcol="2" gridrow="17" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FD87FD60FD84" box="[677,714,535,557]" gridcol="3" gridrow="17" pageId="5" pageNumber="40">401/</td>
|
||
<td id="768F5DC2CE79849CFD18FD87FCCFFD84" box="[766,869,535,557]" gridcol="4" gridrow="17" pageId="5" pageNumber="40">C32H38O12</td>
|
||
<td id="768F5DC2CE79849CFC2BFD87FB95FD84" box="[973,1087,535,557]" gridcol="5" gridrow="17" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FD8BFC5BFD83" box="[996,1009,539,554]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FD87FBA5FD8B" box="[1029,1039,535,546]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FD87FB22FD84" box="[1104,1160,535,557]" gridcol="6" gridrow="17" pageId="5" pageNumber="40">613.23</td>
|
||
<td id="768F5DC2CE79849CFB78FD87FA95FD84" box="[1182,1343,535,557]" gridcol="7" gridrow="17" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FB78FD8BFB01FD83" box="[1182,1195,539,554]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
a
|
||
</td>
|
||
<td id="768F5DC2CE79849CFAB1FD87F8D0FD84" box="[1367,1914,535,557]" gridcol="8" gridrow="17" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FD8CFADCFD83" bold="true" box="[1367,1398,540,554]" pageId="5" pageNumber="40">613</emphasis>
|
||
, 565, 535, 417, 402, 387, 195, 181, 165, 150
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FDA3F8D0FDE8" box="[130,1914,563,577]" gridrow="18" pageId="5" pageNumber="40" rowspan-0="1" rowspan-1="1" rowspan-2="1" rowspan-4="1" rowspan-5="1" rowspan-6="1" rowspan-7="1" rowspan-8="1">
|
||
<td id="768F5DC2CE79849CFD43FDA3FD60FDE8" box="[677,714,563,577]" gridcol="3" gridrow="18" pageId="5" pageNumber="40">415</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FDD5F8D0FDF3" box="[130,1914,581,602]" gridrow="19" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FDD5FF34FDF3" box="[130,158,581,602]" gridcol="0" gridrow="19" pageId="5" pageNumber="40">65</th>
|
||
<td id="768F5DC2CE79849CFF51FDD5FDEAFDF3" box="[183,576,581,602]" gridcol="1" gridrow="19" pageId="5" pageNumber="40">
|
||
G(8-
|
||
<emphasis id="B91AEAEECE797B66FF3DFDD8FF4DFDF1" box="[219,231,584,600]" italics="true" pageId="5" pageNumber="40">O</emphasis>
|
||
-4)G(8-8)S/G(8-
|
||
<emphasis id="B91AEAEECE797B66FE80FDD8FED8FDF1" box="[358,370,584,600]" italics="true" pageId="5" pageNumber="40">O</emphasis>
|
||
-4)S(8-8)G
|
||
</td>
|
||
<td id="768F5DC2CE79849CFD9EFDD5FD24FDF3" box="[632,654,581,602]" gridcol="2" gridrow="19" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FDD5FD60FDF3" box="[677,714,581,602]" gridcol="3" gridrow="19" pageId="5" pageNumber="40">407/</td>
|
||
<td id="768F5DC2CE79849CFD18FDD5FCCFFDF3" box="[766,869,581,602]" gridcol="4" gridrow="19" pageId="5" pageNumber="40">C31H36O11</td>
|
||
<td id="768F5DC2CE79849CFC2BFDD5FB95FDF3" box="[973,1087,581,602]" gridcol="5" gridrow="19" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FDD9FC5BFDF1" box="[996,1009,585,600]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FDD5FBA5FDF9" box="[1029,1039,581,592]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FDD5FB22FDF3" box="[1104,1160,581,602]" gridcol="6" gridrow="19" pageId="5" pageNumber="40">583.22</td>
|
||
<td id="768F5DC2CE79849CFB78FDD5FA95FDF3" box="[1182,1343,581,602]" gridcol="7" gridrow="19" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FB78FDD9FB01FDF1" box="[1182,1195,585,600]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
a
|
||
</td>
|
||
<td id="768F5DC2CE79849CFAB1FDD5F8D0FDF3" box="[1367,1914,581,602]" gridcol="8" gridrow="19" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FDDAFADCFDF1" bold="true" box="[1367,1398,586,600]" pageId="5" pageNumber="40">583</emphasis>
|
||
, 535, 505, 387, 357, 195, 181, 180, 165, 150
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FDF1F8D0FDC6" box="[130,1914,609,623]" gridrow="20" pageId="5" pageNumber="40" rowspan-0="1" rowspan-1="1" rowspan-2="1" rowspan-4="1" rowspan-5="1" rowspan-6="1" rowspan-7="1" rowspan-8="1">
|
||
<td id="768F5DC2CE79849CFD43FDF1FD60FDC6" box="[677,714,609,623]" gridcol="3" gridrow="20" pageId="5" pageNumber="40">421</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FDE3F8D0FD21" box="[130,1914,627,648]" gridrow="21" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FDE3FF34FD21" box="[130,158,627,648]" gridcol="0" gridrow="21" pageId="5" pageNumber="40">66</th>
|
||
<td id="768F5DC2CE79849CFF51FDE3FDEAFD21" box="[183,576,627,648]" gridcol="1" gridrow="21" pageId="5" pageNumber="40">Esculetin</td>
|
||
<td id="768F5DC2CE79849CFD9EFDE3FD24FD21" box="[632,654,627,648]" gridcol="2" gridrow="21" pageId="5" pageNumber="40">S,L</td>
|
||
<td id="768F5DC2CE79849CFD43FDE3FD60FD21" box="[677,714,627,648]" gridcol="3" gridrow="21" pageId="5" pageNumber="40">201</td>
|
||
<td id="768F5DC2CE79849CFD18FDE3FCCFFD21" box="[766,869,627,648]" gridcol="4" gridrow="21" pageId="5" pageNumber="40">C9H6O4</td>
|
||
<td id="768F5DC2CE79849CFC2BFDE3FB95FD21" box="[973,1087,627,648]" gridcol="5" gridrow="21" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FDE7FC5BFD2F" box="[996,1009,631,646]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FDE3FBA5FDD7" box="[1029,1039,627,638]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FDE3FB22FD21" box="[1104,1160,627,648]" gridcol="6" gridrow="21" pageId="5" pageNumber="40">177.02</td>
|
||
<td id="768F5DC2CE79849CFB78FDE3FA95FD21" box="[1182,1343,627,648]" gridcol="7" gridrow="21" pageId="5" pageNumber="40">2</td>
|
||
<td id="768F5DC2CE79849CFAB1FDE3F8D0FD21" box="[1367,1914,627,648]" gridcol="8" gridrow="21" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FDE7FADCFD2C" bold="true" box="[1367,1398,631,645]" pageId="5" pageNumber="40">177</emphasis>
|
||
, 149, 133, 121, 105, 93, 89, 81, 77
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FD1AF8D0FD36" box="[130,1914,650,671]" gridrow="22" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FD1AFF34FD36" box="[130,158,650,671]" gridcol="0" gridrow="22" pageId="5" pageNumber="40">67</th>
|
||
<td id="768F5DC2CE79849CFF51FD1AFDEAFD36" box="[183,576,650,671]" gridcol="1" gridrow="22" pageId="5" pageNumber="40">Scopoletin</td>
|
||
<td id="768F5DC2CE79849CFD9EFD1AFD24FD36" box="[632,654,650,671]" gridcol="2" gridrow="22" pageId="5" pageNumber="40">S,L</td>
|
||
<td id="768F5DC2CE79849CFD43FD1AFD60FD36" box="[677,714,650,671]" gridcol="3" gridrow="22" pageId="5" pageNumber="40">268</td>
|
||
<td id="768F5DC2CE79849CFD18FD1AFCCFFD36" box="[766,869,650,671]" gridcol="4" gridrow="22" pageId="5" pageNumber="40">C10H8O4</td>
|
||
<td id="768F5DC2CE79849CFC2BFD1AFB95FD36" box="[973,1087,650,671]" gridcol="5" gridrow="22" pageId="5" pageNumber="40">[M+H] +</td>
|
||
<td id="768F5DC2CE79849CFBB6FD1AFB22FD36" box="[1104,1160,650,671]" gridcol="6" gridrow="22" pageId="5" pageNumber="40">193.05</td>
|
||
<td id="768F5DC2CE79849CFB78FD1AFA95FD36" box="[1182,1343,650,671]" gridcol="7" gridrow="22" pageId="5" pageNumber="40">1</td>
|
||
<td id="768F5DC2CE79849CFAB1FD1AF8D0FD36" box="[1367,1914,650,671]" gridcol="8" gridrow="22" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FD1EFADCFD35" bold="true" box="[1367,1398,654,668]" pageId="5" pageNumber="40">191</emphasis>
|
||
([M
|
||
<emphasis id="B91AEAEECE797B66FA7EFD1EFA0FFD34" box="[1432,1445,654,669]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FA5FFD1AFA69FD3C" box="[1465,1475,650,661]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
), 176, 148, 120, 104
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FD30F8D0FD1F" box="[130,1914,672,694]" gridrow="23" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FD30FF34FD1F" box="[130,158,672,694]" gridcol="0" gridrow="23" pageId="5" pageNumber="40">68</th>
|
||
<td id="768F5DC2CE79849CFF51FD30FDEAFD1F" box="[183,576,672,694]" gridcol="1" gridrow="23" pageId="5" pageNumber="40">Esculin</td>
|
||
<td id="768F5DC2CE79849CFD9EFD30FD24FD1F" box="[632,654,672,694]" gridcol="2" gridrow="23" pageId="5" pageNumber="40">S,L</td>
|
||
<td id="768F5DC2CE79849CFD43FD30FD60FD1F" box="[677,714,672,694]" gridcol="3" gridrow="23" pageId="5" pageNumber="40">166</td>
|
||
<td id="768F5DC2CE79849CFD18FD30FCCFFD1F" box="[766,869,672,694]" gridcol="4" gridrow="23" pageId="5" pageNumber="40">C15H16O9</td>
|
||
<td id="768F5DC2CE79849CFC2BFD30FB95FD1F" box="[973,1087,672,694]" gridcol="5" gridrow="23" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FD34FC5BFD1A" box="[996,1009,676,691]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FD30FBA5FD02" box="[1029,1039,672,683]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FD30FB22FD1F" box="[1104,1160,672,694]" gridcol="6" gridrow="23" pageId="5" pageNumber="40">339.07</td>
|
||
<td id="768F5DC2CE79849CFB78FD30FA95FD1F" box="[1182,1343,672,694]" gridcol="7" gridrow="23" pageId="5" pageNumber="40">5</td>
|
||
<td id="768F5DC2CE79849CFAB1FD30F8D0FD1F" box="[1367,1914,672,694]" gridcol="8" gridrow="23" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FD35FADCFD1A" bold="true" box="[1367,1398,677,691]" pageId="5" pageNumber="40">339</emphasis>
|
||
, 177, 133
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FD27F8D0FD64" box="[130,1914,695,717]" gridrow="24" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FD27FF34FD64" box="[130,158,695,717]" gridcol="0" gridrow="24" pageId="5" pageNumber="40">69</th>
|
||
<td id="768F5DC2CE79849CFF51FD27FDEAFD64" box="[183,576,695,717]" gridcol="1" gridrow="24" pageId="5" pageNumber="40">Scopolin</td>
|
||
<td id="768F5DC2CE79849CFD9EFD27FD24FD64" box="[632,654,695,717]" gridcol="2" gridrow="24" pageId="5" pageNumber="40">I,L</td>
|
||
<td id="768F5DC2CE79849CFD43FD27FD60FD64" box="[677,714,695,717]" gridcol="3" gridrow="24" pageId="5" pageNumber="40">196</td>
|
||
<td id="768F5DC2CE79849CFD18FD27FCCFFD64" box="[766,869,695,717]" gridcol="4" gridrow="24" pageId="5" pageNumber="40">C16H18O9</td>
|
||
<td id="768F5DC2CE79849CFC2BFD27FB95FD64" box="[973,1087,695,717]" gridcol="5" gridrow="24" pageId="5" pageNumber="40">
|
||
[M-H+FA]
|
||
<emphasis id="B91AEAEECE797B66FBFBFD27FB8DFD6B" box="[1053,1063,695,706]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FD27FB22FD64" box="[1104,1160,695,717]" gridcol="6" gridrow="24" pageId="5" pageNumber="40">399.09</td>
|
||
<td id="768F5DC2CE79849CFB78FD27FA95FD64" box="[1182,1343,695,717]" gridcol="7" gridrow="24" pageId="5" pageNumber="40">4</td>
|
||
<td id="768F5DC2CE79849CFAB1FD27F8D0FD64" box="[1367,1914,695,717]" gridcol="8" gridrow="24" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FD2CFADCFD63" bold="true" box="[1367,1398,700,714]" pageId="5" pageNumber="40">399</emphasis>
|
||
, 353, 207, 191, 176
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FD5EF8D0FD4A" box="[130,1914,718,739]" gridrow="25" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FD5EFF34FD4A" box="[130,158,718,739]" gridcol="0" gridrow="25" pageId="5" pageNumber="40">70</th>
|
||
<td id="768F5DC2CE79849CFF51FD5EFDEAFD4A" box="[183,576,718,739]" gridcol="1" gridrow="25" pageId="5" pageNumber="40">Scopoletin Hex-Pent</td>
|
||
<td id="768F5DC2CE79849CFD9EFD5EFD24FD4A" box="[632,654,718,739]" gridcol="2" gridrow="25" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FD5EFD60FD4A" box="[677,714,718,739]" gridcol="3" gridrow="25" pageId="5" pageNumber="40">197</td>
|
||
<td id="768F5DC2CE79849CFD18FD5EFCCFFD4A" box="[766,869,718,739]" gridcol="4" gridrow="25" pageId="5" pageNumber="40">C21H26O13</td>
|
||
<td id="768F5DC2CE79849CFC2BFD5EFB95FD4A" box="[973,1087,718,739]" gridcol="5" gridrow="25" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FD42FC5BFD48" box="[996,1009,722,737]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FD5EFBA5FD70" box="[1029,1039,718,729]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FD5EFB22FD4A" box="[1104,1160,718,739]" gridcol="6" gridrow="25" pageId="5" pageNumber="40">485.13</td>
|
||
<td id="768F5DC2CE79849CFB78FD5EFA95FD4A" box="[1182,1343,718,739]" gridcol="7" gridrow="25" pageId="5" pageNumber="40">6</td>
|
||
<td id="768F5DC2CE79849CFAB1FD5EF8D0FD4A" box="[1367,1914,718,739]" gridcol="8" gridrow="25" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FD43FADCFD48" bold="true" box="[1367,1398,723,737]" pageId="5" pageNumber="40">485</emphasis>
|
||
, 191, 176, 148
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FD75F8D0FD53" box="[130,1914,741,762]" gridrow="26" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FD75FF34FD53" box="[130,158,741,762]" gridcol="0" gridrow="26" pageId="5" pageNumber="40">71</th>
|
||
<td id="768F5DC2CE79849CFF51FD75FDEAFD53" box="[183,576,741,762]" gridcol="1" gridrow="26" pageId="5" pageNumber="40">Scopoletin Benzoyl-Hex-Pent</td>
|
||
<td id="768F5DC2CE79849CFD9EFD75FD24FD53" box="[632,654,741,762]" gridcol="2" gridrow="26" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FD75FD60FD53" box="[677,714,741,762]" gridcol="3" gridrow="26" pageId="5" pageNumber="40">329</td>
|
||
<td id="768F5DC2CE79849CFD18FD75FCCFFD53" box="[766,869,741,762]" gridcol="4" gridrow="26" pageId="5" pageNumber="40">C28H30O14</td>
|
||
<td id="768F5DC2CE79849CFC2BFD75FB95FD53" box="[973,1087,741,762]" gridcol="5" gridrow="26" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FD79FC5BFD51" box="[996,1009,745,760]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FD75FBA5FD59" box="[1029,1039,741,752]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FD75FB22FD53" box="[1104,1160,741,762]" gridcol="6" gridrow="26" pageId="5" pageNumber="40">589.16</td>
|
||
<td id="768F5DC2CE79849CFB78FD75FA95FD53" box="[1182,1343,741,762]" gridcol="7" gridrow="26" pageId="5" pageNumber="40">5</td>
|
||
<td id="768F5DC2CE79849CFAB1FD75F8D0FD53" box="[1367,1914,741,762]" gridcol="8" gridrow="26" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FD7AFADCFD51" bold="true" box="[1367,1398,746,760]" pageId="5" pageNumber="40">589</emphasis>
|
||
, 467, 191, 148, 121
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FD6CF8D0FCB8" box="[130,1914,764,785]" gridrow="27" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FD6CFF34FCB8" box="[130,158,764,785]" gridcol="0" gridrow="27" pageId="5" pageNumber="40">72</th>
|
||
<td id="768F5DC2CE79849CFF51FD6CFDEAFCB8" box="[183,576,764,785]" gridcol="1" gridrow="27" pageId="5" pageNumber="40">
|
||
G(8-
|
||
<emphasis id="B91AEAEECE797B66FF3DFD6FFF4DFCA6" box="[219,231,767,783]" italics="true" pageId="5" pageNumber="40">O</emphasis>
|
||
-4)Scopoletin
|
||
</td>
|
||
<td id="768F5DC2CE79849CFD9EFD6CFD24FCB8" box="[632,654,764,785]" gridcol="2" gridrow="27" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FD6CFD60FCB8" box="[677,714,764,785]" gridcol="3" gridrow="27" pageId="5" pageNumber="40">280</td>
|
||
<td id="768F5DC2CE79849CFD18FD6CFCCFFCB8" box="[766,869,764,785]" gridcol="4" gridrow="27" pageId="5" pageNumber="40">C20H20O8</td>
|
||
<td id="768F5DC2CE79849CFC2BFD6CFB95FCB8" box="[973,1087,764,785]" gridcol="5" gridrow="27" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FC90FC5BFCA6" box="[996,1009,768,783]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FD6CFBA5FCAE" box="[1029,1039,764,775]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FD6CFB22FCB8" box="[1104,1160,764,785]" gridcol="6" gridrow="27" pageId="5" pageNumber="40">387.11</td>
|
||
<td id="768F5DC2CE79849CFB78FD6CFA95FCB8" box="[1182,1343,764,785]" gridcol="7" gridrow="27" pageId="5" pageNumber="40">3</td>
|
||
<td id="768F5DC2CE79849CFAB1FD6CF8D0FCB8" box="[1367,1914,764,785]" gridcol="8" gridrow="27" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FC90FADCFCA7" bold="true" box="[1367,1398,768,782]" pageId="5" pageNumber="40">387</emphasis>
|
||
, 339, 195, 191, 176, 165, 150
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FC83F8D0FC81" box="[130,1914,787,808]" gridrow="28" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FC83FF34FC81" box="[130,158,787,808]" gridcol="0" gridrow="28" pageId="5" pageNumber="40">73</th>
|
||
<td id="768F5DC2CE79849CFF51FC83FDEAFC81" box="[183,576,787,808]" gridcol="1" gridrow="28" pageId="5" pageNumber="40">
|
||
G(8-
|
||
<emphasis id="B91AEAEECE797B66FF3DFC86FF4DFC8F" box="[219,231,790,806]" italics="true" pageId="5" pageNumber="40">O</emphasis>
|
||
-4)Esculetin
|
||
</td>
|
||
<td id="768F5DC2CE79849CFD9EFC83FD24FC81" box="[632,654,787,808]" gridcol="2" gridrow="28" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FC83FD60FC81" box="[677,714,787,808]" gridcol="3" gridrow="28" pageId="5" pageNumber="40">377</td>
|
||
<td id="768F5DC2CE79849CFD18FC83FCCFFC81" box="[766,869,787,808]" gridcol="4" gridrow="28" pageId="5" pageNumber="40">C19H16O7</td>
|
||
<td id="768F5DC2CE79849CFC2BFC83FB95FC81" box="[973,1087,787,808]" gridcol="5" gridrow="28" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FC87FC5BFC8F" box="[996,1009,791,806]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FC83FBA5FCB7" box="[1029,1039,787,798]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FC83FB22FC81" box="[1104,1160,787,808]" gridcol="6" gridrow="28" pageId="5" pageNumber="40">355.08</td>
|
||
<td id="768F5DC2CE79849CFB78FC83FA95FC81" box="[1182,1343,787,808]" gridcol="7" gridrow="28" pageId="5" pageNumber="40">2</td>
|
||
<td id="768F5DC2CE79849CFAB1FC83F8D0FC81" box="[1367,1914,787,808]" gridcol="8" gridrow="28" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FC87FADCFC8C" bold="true" box="[1367,1398,791,805]" pageId="5" pageNumber="40">355</emphasis>
|
||
, 337, 325, 179, 177, 176
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FCB9F8D0FC96" box="[130,1914,809,831]" gridrow="29" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FCB9FF34FC96" box="[130,158,809,831]" gridcol="0" gridrow="29" pageId="5" pageNumber="40">74</th>
|
||
<td id="768F5DC2CE79849CFF51FCB9FDEAFC96" box="[183,576,809,831]" gridcol="1" gridrow="29" pageId="5" pageNumber="40">
|
||
S(8-
|
||
<emphasis id="B91AEAEECE797B66FF3EFCBDFF4EFC94" box="[216,228,813,829]" italics="true" pageId="5" pageNumber="40">O</emphasis>
|
||
-4)Esculetin
|
||
</td>
|
||
<td id="768F5DC2CE79849CFD9EFCB9FD24FC96" box="[632,654,809,831]" gridcol="2" gridrow="29" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FCB9FD60FC96" box="[677,714,809,831]" gridcol="3" gridrow="29" pageId="5" pageNumber="40">370</td>
|
||
<td id="768F5DC2CE79849CFD18FCB9FCCFFC96" box="[766,869,809,831]" gridcol="4" gridrow="29" pageId="5" pageNumber="40">C20H18O8</td>
|
||
<td id="768F5DC2CE79849CFC2BFCB9FB95FC96" box="[973,1087,809,831]" gridcol="5" gridrow="29" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FC02FCBDFC5BFC95" box="[996,1009,813,828]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
<emphasis id="B91AEAEECE797B66FBE3FCB9FBA5FC9D" box="[1029,1039,809,820]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
[M H]
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FCB9FB22FC96" box="[1104,1160,809,831]" gridcol="6" gridrow="29" pageId="5" pageNumber="40">385.09</td>
|
||
<td id="768F5DC2CE79849CFB78FCB9FA95FC96" box="[1182,1343,809,831]" gridcol="7" gridrow="29" pageId="5" pageNumber="40">2</td>
|
||
<td id="768F5DC2CE79849CFAB1FCB9F8D0FC96" box="[1367,1914,809,831]" gridcol="8" gridrow="29" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FCBEFADCFC95" bold="true" box="[1367,1398,814,828]" pageId="5" pageNumber="40">385</emphasis>
|
||
, 367, 355, 209, 177, 176
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FCD0F8D0FCFF" box="[130,1914,832,854]" gridrow="30" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FCD0FF34FCFF" box="[130,158,832,854]" gridcol="0" gridrow="30" pageId="5" pageNumber="40">75</th>
|
||
<td id="768F5DC2CE79849CFF51FCD0FDEAFCFF" box="[183,576,832,854]" gridcol="1" gridrow="30" pageId="5" pageNumber="40">Scopoletin dehydrodimer</td>
|
||
<td id="768F5DC2CE79849CFD9EFCD0FD24FCFF" box="[632,654,832,854]" gridcol="2" gridrow="30" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FCD0FD60FCFF" box="[677,714,832,854]" gridcol="3" gridrow="30" pageId="5" pageNumber="40">315</td>
|
||
<td id="768F5DC2CE79849CFD18FCD0FCCFFCFF" box="[766,869,832,854]" gridcol="4" gridrow="30" pageId="5" pageNumber="40">C20H14O8</td>
|
||
<td id="768F5DC2CE79849CFC2BFCD0FB95FCFF" box="[973,1087,832,854]" gridcol="5" gridrow="30" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FCD4FC5BFCFA" box="[996,1009,836,851]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FCD0FBA5FCE2" box="[1029,1039,832,843]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FCD0FB22FCFF" box="[1104,1160,832,854]" gridcol="6" gridrow="30" pageId="5" pageNumber="40">381.06</td>
|
||
<td id="768F5DC2CE79849CFB78FCD0FA95FCFF" box="[1182,1343,832,854]" gridcol="7" gridrow="30" pageId="5" pageNumber="40">2</td>
|
||
<td id="768F5DC2CE79849CFAB1FCD0F8D0FCFF" box="[1367,1914,832,854]" gridcol="8" gridrow="30" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FCD5FADCFCFA" bold="true" box="[1367,1398,837,851]" pageId="5" pageNumber="40">381</emphasis>
|
||
, 366, 337, 325, 322, 321, 307, 305
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FCC7F8D0FCC5" box="[130,1914,855,876]" gridrow="31" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FCC7FF34FCC5" box="[130,158,855,876]" gridcol="0" gridrow="31" pageId="5" pageNumber="40">76</th>
|
||
<td id="768F5DC2CE79849CFF51FCC7FDEAFCC5" box="[183,576,855,876]" gridcol="1" gridrow="31" pageId="5" pageNumber="40">Unknown oligolignol</td>
|
||
<td id="768F5DC2CE79849CFD9EFCC7FD24FCC5" box="[632,654,855,876]" gridcol="2" gridrow="31" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FCC7FD60FCC5" box="[677,714,855,876]" gridcol="3" gridrow="31" pageId="5" pageNumber="40">300</td>
|
||
<td id="768F5DC2CE79849CFD18FCC7FCCFFCC5" box="[766,869,855,876]" gridcol="4" gridrow="31" pageId="5" pageNumber="40">C41H46O20</td>
|
||
<td id="768F5DC2CE79849CFC2BFCC7FB95FCC5" box="[973,1087,855,876]" gridcol="5" gridrow="31" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FCCBFC5BFCC3" box="[996,1009,859,874]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FCC7FBA5FCCB" box="[1029,1039,855,866]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FCC7FB22FCC5" box="[1104,1160,855,876]" gridcol="6" gridrow="31" pageId="5" pageNumber="40">857.25</td>
|
||
<td id="768F5DC2CE79849CFB78FCC7FA95FCC5" box="[1182,1343,855,876]" gridcol="7" gridrow="31" pageId="5" pageNumber="40">8</td>
|
||
<td id="768F5DC2CE79849CFAB1FCC7F8D0FCC5" box="[1367,1914,855,876]" gridcol="8" gridrow="31" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FCCCFADCFCC3" bold="true" box="[1367,1398,860,874]" pageId="5" pageNumber="40">857</emphasis>
|
||
, 661, 485, 467, 389, 371, 341, 195, 193, 191, 176, 175, 165
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FCFEF8D0FC2A" box="[130,1914,878,899]" gridrow="32" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FCFEFF34FC2A" box="[130,158,878,899]" gridcol="0" gridrow="32" pageId="5" pageNumber="40">77</th>
|
||
<td id="768F5DC2CE79849CFF51FCFEFDEAFC2A" box="[183,576,878,899]" gridcol="1" gridrow="32" pageId="5" pageNumber="40">
|
||
G(8-
|
||
<emphasis id="B91AEAEECE797B66FF3DFCE1FF4DFC28" box="[219,231,881,897]" italics="true" pageId="5" pageNumber="40">O</emphasis>
|
||
-4)FA Sulfate
|
||
</td>
|
||
<td id="768F5DC2CE79849CFD9EFCFEFD24FC2A" box="[632,654,878,899]" gridcol="2" gridrow="32" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FCFEFD60FC2A" box="[677,714,878,899]" gridcol="3" gridrow="32" pageId="5" pageNumber="40">237/</td>
|
||
<td id="768F5DC2CE79849CFD18FCFEFCCFFC2A" box="[766,869,878,899]" gridcol="4" gridrow="32" pageId="5" pageNumber="40">C20H22O11S</td>
|
||
<td id="768F5DC2CE79849CFC2BFCFEFB95FC2A" box="[973,1087,878,899]" gridcol="5" gridrow="32" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FCE2FC5BFC28" box="[996,1009,882,897]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FCFEFBA5FCD0" box="[1029,1039,878,889]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FCFEFB22FC2A" box="[1104,1160,878,899]" gridcol="6" gridrow="32" pageId="5" pageNumber="40">469.08</td>
|
||
<td id="768F5DC2CE79849CFB78FCFEFA95FC2A" box="[1182,1343,878,899]" gridcol="7" gridrow="32" pageId="5" pageNumber="40">4</td>
|
||
<td id="768F5DC2CE79849CFAB1FCFEF8D0FC2A" box="[1367,1914,878,899]" gridcol="8" gridrow="32" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FCE3FADCFC28" bold="true" box="[1367,1398,883,897]" pageId="5" pageNumber="40">469</emphasis>
|
||
, 389, 341, 275, 245, 203, 195, 193
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FC19F8D0FC3E" box="[130,1914,905,919]" gridrow="33" pageId="5" pageNumber="40" rowspan-0="1" rowspan-1="1" rowspan-2="1" rowspan-4="1" rowspan-5="1" rowspan-6="1" rowspan-7="1" rowspan-8="1">
|
||
<td id="768F5DC2CE79849CFD43FC19FD60FC3E" box="[677,714,905,919]" gridcol="3" gridrow="33" pageId="5" pageNumber="40">256</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FC0CF8D0FC18" box="[130,1914,924,945]" gridrow="34" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FC0CFF34FC18" box="[130,158,924,945]" gridcol="0" gridrow="34" pageId="5" pageNumber="40">78</th>
|
||
<td id="768F5DC2CE79849CFF51FC0CFDEAFC18" box="[183,576,924,945]" gridcol="1" gridrow="34" pageId="5" pageNumber="40">G(8-5)FA</td>
|
||
<td id="768F5DC2CE79849CFD9EFC0CFD24FC18" box="[632,654,924,945]" gridcol="2" gridrow="34" pageId="5" pageNumber="40">S</td>
|
||
<td id="768F5DC2CE79849CFD43FC0CFD60FC18" box="[677,714,924,945]" gridcol="3" gridrow="34" pageId="5" pageNumber="40">358</td>
|
||
<td id="768F5DC2CE79849CFD18FC0CFCCFFC18" box="[766,869,924,945]" gridcol="4" gridrow="34" pageId="5" pageNumber="40">C20H20O7</td>
|
||
<td id="768F5DC2CE79849CFC2BFC0CFB95FC18" box="[973,1087,924,945]" gridcol="5" gridrow="34" pageId="5" pageNumber="40">
|
||
[M-H-H O]
|
||
<emphasis id="B91AEAEECE797B66FBC1FC0CFB9BFC0E" box="[1063,1073,924,935]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
2
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FC0CFB22FC18" box="[1104,1160,924,945]" gridcol="6" gridrow="34" pageId="5" pageNumber="40">353.10</td>
|
||
<td id="768F5DC2CE79849CFB78FC0CFA95FC18" box="[1182,1343,924,945]" gridcol="7" gridrow="34" pageId="5" pageNumber="40">3</td>
|
||
<td id="768F5DC2CE79849CFAB1FC0CF8D0FC18" box="[1367,1914,924,945]" gridcol="8" gridrow="34" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FC30FADCFC07" bold="true" box="[1367,1398,928,942]" pageId="5" pageNumber="40">371</emphasis>
|
||
, 353, 341, 338, 326, 322, 309, 297, 294, 282, 235, 191
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FC23F8D0FC61" box="[130,1914,947,968]" gridrow="35" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FC23FF34FC61" box="[130,158,947,968]" gridcol="0" gridrow="35" pageId="5" pageNumber="40">79</th>
|
||
<td id="768F5DC2CE79849CFF51FC23FDEAFC61" box="[183,576,947,968]" gridcol="1" gridrow="35" pageId="5" pageNumber="40">G(8-5)FA Sulfate</td>
|
||
<td id="768F5DC2CE79849CFD9EFC23FD24FC61" box="[632,654,947,968]" gridcol="2" gridrow="35" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FC23FD60FC61" box="[677,714,947,968]" gridcol="3" gridrow="35" pageId="5" pageNumber="40">323</td>
|
||
<td id="768F5DC2CE79849CFD18FC23FCCFFC61" box="[766,869,947,968]" gridcol="4" gridrow="35" pageId="5" pageNumber="40">C20H20O10S</td>
|
||
<td id="768F5DC2CE79849CFC2BFC23FB95FC61" box="[973,1087,947,968]" gridcol="5" gridrow="35" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FC27FC5BFC6F" box="[996,1009,951,966]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FC23FBA5FC17" box="[1029,1039,947,958]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FC23FB22FC61" box="[1104,1160,947,968]" gridcol="6" gridrow="35" pageId="5" pageNumber="40">451.07</td>
|
||
<td id="768F5DC2CE79849CFB78FC23FA95FC61" box="[1182,1343,947,968]" gridcol="7" gridrow="35" pageId="5" pageNumber="40">3</td>
|
||
<td id="768F5DC2CE79849CFAB1FC23F8D0FC61" box="[1367,1914,947,968]" gridcol="8" gridrow="35" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FC27FADCFC6C" bold="true" box="[1367,1398,951,965]" pageId="5" pageNumber="40">451</emphasis>
|
||
, 371, 353, 341, 338, 326, 309, 297, 294, 282, 267, 245, 97
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FC59F8D0FC76" box="[130,1914,969,991]" gridrow="36" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FC59FF34FC76" box="[130,158,969,991]" gridcol="0" gridrow="36" pageId="5" pageNumber="40">80</th>
|
||
<td id="768F5DC2CE79849CFF51FC59FDEAFC76" box="[183,576,969,991]" gridcol="1" gridrow="36" pageId="5" pageNumber="40">FA dimer</td>
|
||
<td id="768F5DC2CE79849CFD9EFC59FD24FC76" box="[632,654,969,991]" gridcol="2" gridrow="36" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FC59FD60FC76" box="[677,714,969,991]" gridcol="3" gridrow="36" pageId="5" pageNumber="40">242/</td>
|
||
<td id="768F5DC2CE79849CFD18FC59FCCFFC76" box="[766,869,969,991]" gridcol="4" gridrow="36" pageId="5" pageNumber="40">C20H20O8</td>
|
||
<td id="768F5DC2CE79849CFC2BFC59FB95FC76" box="[973,1087,969,991]" gridcol="5" gridrow="36" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FC02FC5DFC5BFC75" box="[996,1009,973,988]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
<emphasis id="B91AEAEECE797B66FBE3FC59FBA5FC7D" box="[1029,1039,969,980]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
[M H]
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FC59FB22FC76" box="[1104,1160,969,991]" gridcol="6" gridrow="36" pageId="5" pageNumber="40">387.11</td>
|
||
<td id="768F5DC2CE79849CFB78FC59FA95FC76" box="[1182,1343,969,991]" gridcol="7" gridrow="36" pageId="5" pageNumber="40">4</td>
|
||
<td id="768F5DC2CE79849CFAB1FC59F8D0FC76" box="[1367,1914,969,991]" gridcol="8" gridrow="36" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FC5EFADCFC75" bold="true" box="[1367,1398,974,988]" pageId="5" pageNumber="40">387</emphasis>
|
||
, 339, 324, 309, 235, 220, 217, 203, 202, 176, 151, 136
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FC75F8D0FC5A" box="[130,1914,997,1011]" gridrow="37" pageId="5" pageNumber="40" rowspan-0="1" rowspan-1="1" rowspan-2="1" rowspan-4="1" rowspan-5="1" rowspan-6="1" rowspan-7="1" rowspan-8="1">
|
||
<td id="768F5DC2CE79849CFD43FC75FD60FC5A" box="[677,714,997,1011]" gridcol="3" gridrow="37" pageId="5" pageNumber="40">249</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FC67F8D0FBA5" box="[130,1914,1015,1036]" gridrow="38" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FC67FF34FBA5" box="[130,158,1015,1036]" gridcol="0" gridrow="38" pageId="5" pageNumber="40">81</th>
|
||
<td id="768F5DC2CE79849CFF51FC67FDEAFBA5" box="[183,576,1015,1036]" gridcol="1" gridrow="38" pageId="5" pageNumber="40">Didehydro-di(coumaroyl)spermidine Sulfate</td>
|
||
<td id="768F5DC2CE79849CFD9EFC67FD24FBA5" box="[632,654,1015,1036]" gridcol="2" gridrow="38" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FC67FD60FBA5" box="[677,714,1015,1036]" gridcol="3" gridrow="38" pageId="5" pageNumber="40">219</td>
|
||
<td id="768F5DC2CE79849CFD18FC67FCCFFBA5" box="[766,869,1015,1036]" gridcol="4" gridrow="38" pageId="5" pageNumber="40">C25H29N3O7S</td>
|
||
<td id="768F5DC2CE79849CFC2BFC67FB95FBA5" box="[973,1087,1015,1036]" gridcol="5" gridrow="38" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FC6BFC5BFBA3" box="[996,1009,1019,1034]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FC67FBA5FBAB" box="[1029,1039,1015,1026]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FC67FB22FBA5" box="[1104,1160,1015,1036]" gridcol="6" gridrow="38" pageId="5" pageNumber="40">514.17</td>
|
||
<td id="768F5DC2CE79849CFB78FC67FA95FBA5" box="[1182,1343,1015,1036]" gridcol="7" gridrow="38" pageId="5" pageNumber="40">4</td>
|
||
<td id="768F5DC2CE79849CFAB1FC67F8D0FBA5" box="[1367,1914,1015,1036]" gridcol="8" gridrow="38" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FC6CFADCFBA3" bold="true" box="[1367,1398,1020,1034]" pageId="5" pageNumber="40">516</emphasis>
|
||
([M+H] +), 436, 419, 362, 348, 347, 291, 290, 265, 203, 202, 145
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FB9EF8D0FB8A" box="[130,1914,1038,1059]" gridrow="39" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FB9EFF34FB8A" box="[130,158,1038,1059]" gridcol="0" gridrow="39" pageId="5" pageNumber="40">82</th>
|
||
<td id="768F5DC2CE79849CFF51FB9EFDEAFB8A" box="[183,576,1038,1059]" gridcol="1" gridrow="39" pageId="5" pageNumber="40">
|
||
Kaempferol 3-
|
||
<emphasis id="B91AEAEECE797B66FECDFB81FE9DFB88" box="[299,311,1041,1057]" italics="true" pageId="5" pageNumber="40">O</emphasis>
|
||
-Rha(1+2)Glc 7-
|
||
<emphasis id="B91AEAEECE797B66FE26FB81FE66FB88" box="[448,460,1041,1057]" italics="true" pageId="5" pageNumber="40">O</emphasis>
|
||
-Rha
|
||
</td>
|
||
<td id="768F5DC2CE79849CFD9EFB9EFD24FB8A" box="[632,654,1038,1059]" gridcol="2" gridrow="39" pageId="5" pageNumber="40">I,L</td>
|
||
<td id="768F5DC2CE79849CFD43FB9EFD60FB8A" box="[677,714,1038,1059]" gridcol="3" gridrow="39" pageId="5" pageNumber="40">228</td>
|
||
<td id="768F5DC2CE79849CFD18FB9EFCCFFB8A" box="[766,869,1038,1059]" gridcol="4" gridrow="39" pageId="5" pageNumber="40">C33H40O19</td>
|
||
<td id="768F5DC2CE79849CFC2BFB9EFB95FB8A" box="[973,1087,1038,1059]" gridcol="5" gridrow="39" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FB82FC5BFB88" box="[996,1009,1042,1057]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FB9EFBA5FBB0" box="[1029,1039,1038,1049]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FB9EFB22FB8A" box="[1104,1160,1038,1059]" gridcol="6" gridrow="39" pageId="5" pageNumber="40">739.21</td>
|
||
<td id="768F5DC2CE79849CFB78FB9EFA95FB8A" box="[1182,1343,1038,1059]" gridcol="7" gridrow="39" pageId="5" pageNumber="40">11</td>
|
||
<td id="768F5DC2CE79849CFAB1FB9EF8D0FB8A" box="[1367,1914,1038,1059]" gridcol="8" gridrow="39" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FB83FADCFB88" bold="true" box="[1367,1398,1043,1057]" pageId="5" pageNumber="40">739</emphasis>
|
||
, 593, 430, 284
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FBB5F8D0FB93" box="[130,1914,1061,1082]" gridrow="40" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FBB5FF34FB93" box="[130,158,1061,1082]" gridcol="0" gridrow="40" pageId="5" pageNumber="40">83</th>
|
||
<td id="768F5DC2CE79849CFF51FBB5FDEAFB93" box="[183,576,1061,1082]" gridcol="1" gridrow="40" pageId="5" pageNumber="40">
|
||
9,12,13-Trihydroxy-10(
|
||
<emphasis id="B91AEAEECE797B66FE95FBB9FED6FB91" box="[371,380,1065,1080]" italics="true" pageId="5" pageNumber="40">E</emphasis>
|
||
),15(
|
||
<emphasis id="B91AEAEECE797B66FE44FBB9FE01FB91" box="[418,427,1065,1080]" italics="true" pageId="5" pageNumber="40">Z</emphasis>
|
||
)- octadecadienoic
|
||
</td>
|
||
<td id="768F5DC2CE79849CFD9EFBB5FD24FB93" box="[632,654,1061,1082]" gridcol="2" gridrow="40" pageId="5" pageNumber="40">S,L</td>
|
||
<td id="768F5DC2CE79849CFD43FBB5FD60FB93" box="[677,714,1061,1082]" gridcol="3" gridrow="40" pageId="5" pageNumber="40">420</td>
|
||
<td id="768F5DC2CE79849CFD18FBB5FCCFFB93" box="[766,869,1061,1082]" gridcol="4" gridrow="40" pageId="5" pageNumber="40">C18H32O5</td>
|
||
<td id="768F5DC2CE79849CFC2BFBB5FB95FB93" box="[973,1087,1061,1082]" gridcol="5" gridrow="40" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FBB9FC5BFB91" box="[996,1009,1065,1080]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FBB5FBA5FB99" box="[1029,1039,1061,1072]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FBB5FB22FB93" box="[1104,1160,1061,1082]" gridcol="6" gridrow="40" pageId="5" pageNumber="40">327.22</td>
|
||
<td id="768F5DC2CE79849CFB78FBB5FA95FB93" box="[1182,1343,1061,1082]" gridcol="7" gridrow="40" pageId="5" pageNumber="40">4</td>
|
||
<td id="768F5DC2CE79849CFAB1FBB5F8D0FB93" box="[1367,1914,1061,1082]" gridcol="8" gridrow="40" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FBB9FADCFB9E" bold="true" box="[1367,1398,1065,1079]" pageId="5" pageNumber="40">327</emphasis>
|
||
, 309, 291, 239, 229, 221, 211, 185, 183, 177, 171
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FBD0F8D0FBE7" box="[130,1914,1088,1102]" gridrow="41" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FBD0F8D0FBE7" box="[130,1914,1088,1102]" colspan="9" colspanRight="8" gridcol="0" gridrow="41" pageId="5" pageNumber="40">acid</th>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FBC2F8D0FBC1" box="[130,1914,1106,1128]" gridrow="42" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FBC2FF34FBC1" box="[130,158,1106,1128]" gridcol="0" gridrow="42" pageId="5" pageNumber="40">84</th>
|
||
<td id="768F5DC2CE79849CFF51FBC2FDEAFBC1" box="[183,576,1106,1128]" gridcol="1" gridrow="42" pageId="5" pageNumber="40">9,12,13-Trihydroxyoctadec-10-enoic acid</td>
|
||
<td id="768F5DC2CE79849CFD9EFBC2FD24FBC1" box="[632,654,1106,1128]" gridcol="2" gridrow="42" pageId="5" pageNumber="40">I,L</td>
|
||
<td id="768F5DC2CE79849CFD43FBC2FD60FBC1" box="[677,714,1106,1128]" gridcol="3" gridrow="42" pageId="5" pageNumber="40">445</td>
|
||
<td id="768F5DC2CE79849CFD18FBC2FCCFFBC1" box="[766,869,1106,1128]" gridcol="4" gridrow="42" pageId="5" pageNumber="40">C18H34O5</td>
|
||
<td id="768F5DC2CE79849CFC2BFBC2FB95FBC1" box="[973,1087,1106,1128]" gridcol="5" gridrow="42" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FBC6FC5BFBCC" box="[996,1009,1110,1125]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FBC2FBA5FBF4" box="[1029,1039,1106,1117]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FBC2FB22FBC1" box="[1104,1160,1106,1128]" gridcol="6" gridrow="42" pageId="5" pageNumber="40">329.23</td>
|
||
<td id="768F5DC2CE79849CFB78FBC2FA95FBC1" box="[1182,1343,1106,1128]" gridcol="7" gridrow="42" pageId="5" pageNumber="40">4</td>
|
||
<td id="768F5DC2CE79849CFAB1FBC2F8D0FBC1" box="[1367,1914,1106,1128]" gridcol="8" gridrow="42" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FBC7FADCFBCC" bold="true" box="[1367,1398,1111,1125]" pageId="5" pageNumber="40">329</emphasis>
|
||
, 311, 293, 229, 211, 197, 193, 183, 171, 139
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FBF9F8D0FBD6" box="[130,1914,1129,1151]" gridrow="43" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FBF9FF34FBD6" box="[130,158,1129,1151]" gridcol="0" gridrow="43" pageId="5" pageNumber="40">85</th>
|
||
<td id="768F5DC2CE79849CFF51FBF9FDEAFBD6" box="[183,576,1129,1151]" gridcol="1" gridrow="43" pageId="5" pageNumber="40">Fatty acid derivative</td>
|
||
<td id="768F5DC2CE79849CFD9EFBF9FD24FBD6" box="[632,654,1129,1151]" gridcol="2" gridrow="43" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FBF9FD60FBD6" box="[677,714,1129,1151]" gridcol="3" gridrow="43" pageId="5" pageNumber="40">634</td>
|
||
<td id="768F5DC2CE79849CFD18FBF9FCCFFBD6" box="[766,869,1129,1151]" gridcol="4" gridrow="43" pageId="5" pageNumber="40">C18H30O4</td>
|
||
<td id="768F5DC2CE79849CFC2BFBF9FB95FBD6" box="[973,1087,1129,1151]" gridcol="5" gridrow="43" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FBFDFC5BFBD5" box="[996,1009,1133,1148]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FBF9FBA5FBDD" box="[1029,1039,1129,1140]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FBF9FB22FBD6" box="[1104,1160,1129,1151]" gridcol="6" gridrow="43" pageId="5" pageNumber="40">309.21</td>
|
||
<td id="768F5DC2CE79849CFB78FBF9FA95FBD6" box="[1182,1343,1129,1151]" gridcol="7" gridrow="43" pageId="5" pageNumber="40">2</td>
|
||
<td id="768F5DC2CE79849CFAB1FBF9F8D0FBD6" box="[1367,1914,1129,1151]" gridcol="8" gridrow="43" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FBFEFADCFBD5" bold="true" box="[1367,1398,1134,1148]" pageId="5" pageNumber="40">309</emphasis>
|
||
, 291, 273, 265, 247
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FB10F8D0FB3C" box="[130,1914,1152,1173]" gridrow="44" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FB10FF34FB3C" box="[130,158,1152,1173]" gridcol="0" gridrow="44" pageId="5" pageNumber="40">86</th>
|
||
<td id="768F5DC2CE79849CFF51FB10FDEAFB3C" box="[183,576,1152,1173]" gridcol="1" gridrow="44" pageId="5" pageNumber="40">Azelaoyl lysoPC</td>
|
||
<td id="768F5DC2CE79849CFD9EFB10FD24FB3C" box="[632,654,1152,1173]" gridcol="2" gridrow="44" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FB10FD60FB3C" box="[677,714,1152,1173]" gridcol="3" gridrow="44" pageId="5" pageNumber="40">232/</td>
|
||
<td id="768F5DC2CE79849CFD18FB10FCCFFB3C" box="[766,869,1152,1173]" gridcol="4" gridrow="44" pageId="5" pageNumber="40">C17H34NO9P</td>
|
||
<td id="768F5DC2CE79849CFC2BFB10FB95FB3C" box="[973,1087,1152,1173]" gridcol="5" gridrow="44" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FB14FC5BFB3A" box="[996,1009,1156,1171]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FB10FBA5FB22" box="[1029,1039,1152,1163]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FB10FB22FB3C" box="[1104,1160,1152,1173]" gridcol="6" gridrow="44" pageId="5" pageNumber="40">426.19</td>
|
||
<td id="768F5DC2CE79849CFB78FB10FA95FB3C" box="[1182,1343,1152,1173]" gridcol="7" gridrow="44" pageId="5" pageNumber="40">2</td>
|
||
<td id="768F5DC2CE79849CFAB1FB10F8D0FB3C" box="[1367,1914,1152,1173]" gridcol="8" gridrow="44" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FB15FADCFB3A" bold="true" box="[1367,1398,1157,1171]" pageId="5" pageNumber="40">428</emphasis>
|
||
([M+H] +), 410, 258, 245, 184, 104
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FB0CF8D0FB03" box="[130,1914,1180,1194]" gridrow="45" pageId="5" pageNumber="40" rowspan-0="1" rowspan-1="1" rowspan-2="1" rowspan-4="1" rowspan-5="1" rowspan-6="1" rowspan-7="1" rowspan-8="1">
|
||
<td id="768F5DC2CE79849CFD43FB0CFD60FB03" box="[677,714,1180,1194]" gridcol="3" gridrow="45" pageId="5" pageNumber="40">244</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FB3FF8D0FB6A" box="[130,1914,1199,1219]" gridrow="46" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FB3FFF34FB6A" box="[130,158,1199,1219]" gridcol="0" gridrow="46" pageId="5" pageNumber="40">87</th>
|
||
<td id="768F5DC2CE79849CFF51FB3FFDEAFB6A" box="[183,576,1199,1219]" gridcol="1" gridrow="46" pageId="5" pageNumber="40">C4H10O Hex</td>
|
||
<td id="768F5DC2CE79849CFD9EFB3FFD24FB6A" box="[632,654,1199,1219]" gridcol="2" gridrow="46" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FB3FFD60FB6A" box="[677,714,1199,1219]" gridcol="3" gridrow="46" pageId="5" pageNumber="40">162</td>
|
||
<td id="768F5DC2CE79849CFD18FB3FFCCFFB6A" box="[766,869,1199,1219]" gridcol="4" gridrow="46" pageId="5" pageNumber="40">C10H20O6</td>
|
||
<td id="768F5DC2CE79849CFC2BFB3FFB95FB6A" box="[973,1087,1199,1219]" gridcol="5" gridrow="46" pageId="5" pageNumber="40">[M+Na] +</td>
|
||
<td id="768F5DC2CE79849CFBB6FB3FFB22FB6A" box="[1104,1160,1199,1219]" gridcol="6" gridrow="46" pageId="5" pageNumber="40">259.12</td>
|
||
<td id="768F5DC2CE79849CFB78FB3FFA95FB6A" box="[1182,1343,1199,1219]" gridcol="7" gridrow="46" pageId="5" pageNumber="40">4</td>
|
||
<td id="768F5DC2CE79849CFAB1FB3FF8D0FB6A" box="[1367,1914,1199,1219]" gridcol="8" gridrow="46" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FB23FADCFB68" bold="true" box="[1367,1398,1203,1217]" pageId="5" pageNumber="40">237</emphasis>
|
||
([M+H] +), 163, 145, 127, 85
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FB56F8D0FB73" box="[130,1914,1222,1242]" gridrow="47" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FB56FF34FB73" box="[130,158,1222,1242]" gridcol="0" gridrow="47" pageId="5" pageNumber="40">88</th>
|
||
<td id="768F5DC2CE79849CFF51FB56FDEAFB73" box="[183,576,1222,1242]" gridcol="1" gridrow="47" pageId="5" pageNumber="40">C4H10O Malonyl-Hex</td>
|
||
<td id="768F5DC2CE79849CFD9EFB56FD24FB73" box="[632,654,1222,1242]" gridcol="2" gridrow="47" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FB56FD60FB73" box="[677,714,1222,1242]" gridcol="3" gridrow="47" pageId="5" pageNumber="40">232</td>
|
||
<td id="768F5DC2CE79849CFD18FB56FCCFFB73" box="[766,869,1222,1242]" gridcol="4" gridrow="47" pageId="5" pageNumber="40">C13H22O9</td>
|
||
<td id="768F5DC2CE79849CFC2BFB56FB95FB73" box="[973,1087,1222,1242]" gridcol="5" gridrow="47" pageId="5" pageNumber="40">[M+Na] +</td>
|
||
<td id="768F5DC2CE79849CFBB6FB56FB22FB73" box="[1104,1160,1222,1242]" gridcol="6" gridrow="47" pageId="5" pageNumber="40">345.11</td>
|
||
<td id="768F5DC2CE79849CFB78FB56FA95FB73" box="[1182,1343,1222,1242]" gridcol="7" gridrow="47" pageId="5" pageNumber="40">4</td>
|
||
<td id="768F5DC2CE79849CFAB1FB56F8D0FB73" box="[1367,1914,1222,1242]" gridcol="8" gridrow="47" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FB59FADCFB7E" bold="true" box="[1367,1398,1225,1239]" pageId="5" pageNumber="40">345</emphasis>
|
||
, 301, 259
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FB4CF8D0FB58" box="[130,1914,1244,1265]" gridrow="48" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FB4CFF34FB58" box="[130,158,1244,1265]" gridcol="0" gridrow="48" pageId="5" pageNumber="40">89</th>
|
||
<td id="768F5DC2CE79849CFF51FB4CFDEAFB58" box="[183,576,1244,1265]" gridcol="1" gridrow="48" pageId="5" pageNumber="40">C4H10O Hex-DeoxyHex</td>
|
||
<td id="768F5DC2CE79849CFD9EFB4CFD24FB58" box="[632,654,1244,1265]" gridcol="2" gridrow="48" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FB4CFD60FB58" box="[677,714,1244,1265]" gridcol="3" gridrow="48" pageId="5" pageNumber="40">200</td>
|
||
<td id="768F5DC2CE79849CFD18FB4CFCCFFB58" box="[766,869,1244,1265]" gridcol="4" gridrow="48" pageId="5" pageNumber="40">C16H30O10</td>
|
||
<td id="768F5DC2CE79849CFC2BFB4CFB95FB58" box="[973,1087,1244,1265]" gridcol="5" gridrow="48" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FB70FC5BFB46" box="[996,1009,1248,1263]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FB4CFBA5FB4E" box="[1029,1039,1244,1255]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FB4CFB22FB58" box="[1104,1160,1244,1265]" gridcol="6" gridrow="48" pageId="5" pageNumber="40">381.18</td>
|
||
<td id="768F5DC2CE79849CFB78FB4CFA95FB58" box="[1182,1343,1244,1265]" gridcol="7" gridrow="48" pageId="5" pageNumber="40">6</td>
|
||
<td id="768F5DC2CE79849CFAB1FB4CF8D0FB58" box="[1367,1914,1244,1265]" gridcol="8" gridrow="48" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FB70FADCFB47" bold="true" box="[1367,1398,1248,1262]" pageId="5" pageNumber="40">383</emphasis>
|
||
([M+H]+), 309, 291, 273, 255, 237, 221, 147, 129
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FB62F8D0FAA1" box="[130,1914,1266,1288]" gridrow="49" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FB62FF34FAA1" box="[130,158,1266,1288]" gridcol="0" gridrow="49" pageId="5" pageNumber="40">90</th>
|
||
<td id="768F5DC2CE79849CFF51FB62FDEAFAA1" box="[183,576,1266,1288]" gridcol="1" gridrow="49" pageId="5" pageNumber="40">C4H10O Malonyl-Hex-DeoxyHex</td>
|
||
<td id="768F5DC2CE79849CFD9EFB62FD24FAA1" box="[632,654,1266,1288]" gridcol="2" gridrow="49" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FB62FD60FAA1" box="[677,714,1266,1288]" gridcol="3" gridrow="49" pageId="5" pageNumber="40">255</td>
|
||
<td id="768F5DC2CE79849CFD18FB62FCCFFAA1" box="[766,869,1266,1288]" gridcol="4" gridrow="49" pageId="5" pageNumber="40">C19H32O13</td>
|
||
<td id="768F5DC2CE79849CFC2BFB62FB95FAA1" box="[973,1087,1266,1288]" gridcol="5" gridrow="49" pageId="5" pageNumber="40">
|
||
[M-H-CO]
|
||
<emphasis id="B91AEAEECE797B66FBC2FB62FB84FB54" box="[1060,1070,1266,1277]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
2
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FB62FB22FAA1" box="[1104,1160,1266,1288]" gridcol="6" gridrow="49" pageId="5" pageNumber="40">423.19</td>
|
||
<td id="768F5DC2CE79849CFB78FB62FA95FAA1" box="[1182,1343,1266,1288]" gridcol="7" gridrow="49" pageId="5" pageNumber="40">6</td>
|
||
<td id="768F5DC2CE79849CFAB1FB62F8D0FAA1" box="[1367,1914,1266,1288]" gridcol="8" gridrow="49" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FB67FADCFAAC" bold="true" box="[1367,1398,1271,1285]" pageId="5" pageNumber="40">467</emphasis>
|
||
([M
|
||
<emphasis id="B91AEAEECE797B66FA7EFB66FA0FFAAC" box="[1432,1445,1270,1285]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FA5FFB62FA69FB54" box="[1465,1475,1266,1277]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
), 423, 381, 277, 235, 217, 161, 159, 143, 113, 101
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FA99F8D0FAB6" box="[130,1914,1289,1311]" gridrow="50" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FA99FF34FAB6" box="[130,158,1289,1311]" gridcol="0" gridrow="50" pageId="5" pageNumber="40">91</th>
|
||
<td id="768F5DC2CE79849CFF51FA99FDEAFAB6" box="[183,576,1289,1311]" gridcol="1" gridrow="50" pageId="5" pageNumber="40">C7H9N5O Hex</td>
|
||
<td id="768F5DC2CE79849CFD9EFA99FD24FAB6" box="[632,654,1289,1311]" gridcol="2" gridrow="50" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FA99FD60FAB6" box="[677,714,1289,1311]" gridcol="3" gridrow="50" pageId="5" pageNumber="40">63</td>
|
||
<td id="768F5DC2CE79849CFD18FA99FCCFFAB6" box="[766,869,1289,1311]" gridcol="4" gridrow="50" pageId="5" pageNumber="40">C13H19N5O6</td>
|
||
<td id="768F5DC2CE79849CFC2BFA99FB95FAB6" box="[973,1087,1289,1311]" gridcol="5" gridrow="50" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FA9DFC5BFAB5" box="[996,1009,1293,1308]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FA99FBA5FABD" box="[1029,1039,1289,1300]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FA99FB22FAB6" box="[1104,1160,1289,1311]" gridcol="6" gridrow="50" pageId="5" pageNumber="40">340.13</td>
|
||
<td id="768F5DC2CE79849CFB78FA99FA95FAB6" box="[1182,1343,1289,1311]" gridcol="7" gridrow="50" pageId="5" pageNumber="40">5</td>
|
||
<td id="768F5DC2CE79849CFAB1FA99F8D0FAB6" box="[1367,1914,1289,1311]" gridcol="8" gridrow="50" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FA9EFADCFAB5" bold="true" box="[1367,1398,1294,1308]" pageId="5" pageNumber="40">342</emphasis>
|
||
([M+H] +), 180, 135, 110
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FAB0F8D0FA9C" box="[130,1914,1312,1333]" gridrow="51" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FAB0FF34FA9C" box="[130,158,1312,1333]" gridcol="0" gridrow="51" pageId="5" pageNumber="40">92</th>
|
||
<td id="768F5DC2CE79849CFF51FAB0FDEAFA9C" box="[183,576,1312,1333]" gridcol="1" gridrow="51" pageId="5" pageNumber="40">C9H10O3 Hex</td>
|
||
<td id="768F5DC2CE79849CFD9EFAB0FD24FA9C" box="[632,654,1312,1333]" gridcol="2" gridrow="51" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FAB0FD60FA9C" box="[677,714,1312,1333]" gridcol="3" gridrow="51" pageId="5" pageNumber="40">198</td>
|
||
<td id="768F5DC2CE79849CFD18FAB0FCCFFA9C" box="[766,869,1312,1333]" gridcol="4" gridrow="51" pageId="5" pageNumber="40">C15H20O8</td>
|
||
<td id="768F5DC2CE79849CFC2BFAB0FB95FA9C" box="[973,1087,1312,1333]" gridcol="5" gridrow="51" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FAB4FC5BFA9A" box="[996,1009,1316,1331]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FAB0FBA5FA82" box="[1029,1039,1312,1323]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FAB0FB22FA9C" box="[1104,1160,1312,1333]" gridcol="6" gridrow="51" pageId="5" pageNumber="40">327.11</td>
|
||
<td id="768F5DC2CE79849CFB78FAB0FA95FA9C" box="[1182,1343,1312,1333]" gridcol="7" gridrow="51" pageId="5" pageNumber="40">5</td>
|
||
<td id="768F5DC2CE79849CFAB1FAB0F8D0FA9C" box="[1367,1914,1312,1333]" gridcol="8" gridrow="51" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FAB5FADCFA9A" bold="true" box="[1367,1398,1317,1331]" pageId="5" pageNumber="40">327</emphasis>
|
||
, 165, 147, 101
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FAA7F8D0FAE5" box="[130,1914,1335,1356]" gridrow="52" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FAA7FF34FAE5" box="[130,158,1335,1356]" gridcol="0" gridrow="52" pageId="5" pageNumber="40">93</th>
|
||
<td id="768F5DC2CE79849CFF51FAA7FDEAFAE5" box="[183,576,1335,1356]" gridcol="1" gridrow="52" pageId="5" pageNumber="40">C12H16O5 Hex</td>
|
||
<td id="768F5DC2CE79849CFD9EFAA7FD24FAE5" box="[632,654,1335,1356]" gridcol="2" gridrow="52" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FAA7FD60FAE5" box="[677,714,1335,1356]" gridcol="3" gridrow="52" pageId="5" pageNumber="40">202</td>
|
||
<td id="768F5DC2CE79849CFD18FAA7FCCFFAE5" box="[766,869,1335,1356]" gridcol="4" gridrow="52" pageId="5" pageNumber="40">C18H26O10</td>
|
||
<td id="768F5DC2CE79849CFC2BFAA7FB95FAE5" box="[973,1087,1335,1356]" gridcol="5" gridrow="52" pageId="5" pageNumber="40">
|
||
[M
|
||
<emphasis id="B91AEAEECE797B66FC02FAABFC5BFAE3" box="[996,1009,1339,1354]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FBE3FAA7FBA5FAEB" box="[1029,1039,1335,1346]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FAA7FB22FAE5" box="[1104,1160,1335,1356]" gridcol="6" gridrow="52" pageId="5" pageNumber="40">401.14</td>
|
||
<td id="768F5DC2CE79849CFB78FAA7FA95FAE5" box="[1182,1343,1335,1356]" gridcol="7" gridrow="52" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FB78FAABFB01FAE3" box="[1182,1195,1339,1354]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
a
|
||
</td>
|
||
<td id="768F5DC2CE79849CFAB1FAA7F8D0FAE5" box="[1367,1914,1335,1356]" gridcol="8" gridrow="52" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FAACFADCFAE3" bold="true" box="[1367,1398,1340,1354]" pageId="5" pageNumber="40">447</emphasis>
|
||
([M-H+FA]
|
||
<emphasis id="B91AEAEECE797B66FA37FAA7FA71FAEB" box="[1489,1499,1335,1346]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
), 401, 255, 205, 161, 113
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FADEF8D0FACA" box="[130,1914,1358,1379]" gridrow="53" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FADEFF34FACA" box="[130,158,1358,1379]" gridcol="0" gridrow="53" pageId="5" pageNumber="40">94</th>
|
||
<td id="768F5DC2CE79849CFF51FADEFDEAFACA" box="[183,576,1358,1379]" gridcol="1" gridrow="53" pageId="5" pageNumber="40">C7H14O4 Malonyl-Hex</td>
|
||
<td id="768F5DC2CE79849CFD9EFADEFD24FACA" box="[632,654,1358,1379]" gridcol="2" gridrow="53" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FADEFD60FACA" box="[677,714,1358,1379]" gridcol="3" gridrow="53" pageId="5" pageNumber="40">209</td>
|
||
<td id="768F5DC2CE79849CFD18FADEFCCFFACA" box="[766,869,1358,1379]" gridcol="4" gridrow="53" pageId="5" pageNumber="40">C16H26O12</td>
|
||
<td id="768F5DC2CE79849CFC2BFADEFB95FACA" box="[973,1087,1358,1379]" gridcol="5" gridrow="53" pageId="5" pageNumber="40">
|
||
[M-H-CO]
|
||
<emphasis id="B91AEAEECE797B66FBC2FADEFB84FAF0" box="[1060,1070,1358,1369]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
2
|
||
</td>
|
||
<td id="768F5DC2CE79849CFBB6FADEFB22FACA" box="[1104,1160,1358,1379]" gridcol="6" gridrow="53" pageId="5" pageNumber="40">365.15</td>
|
||
<td id="768F5DC2CE79849CFB78FADEFA95FACA" box="[1182,1343,1358,1379]" gridcol="7" gridrow="53" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FB78FAC2FB01FAC8" box="[1182,1195,1362,1377]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
a
|
||
</td>
|
||
<td id="768F5DC2CE79849CFAB1FADEF8D0FACA" box="[1367,1914,1358,1379]" gridcol="8" gridrow="53" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FAC2FADCFAC9" bold="true" box="[1367,1398,1362,1376]" pageId="5" pageNumber="40">409</emphasis>
|
||
([M
|
||
<emphasis id="B91AEAEECE797B66FA7EFAC2FA0FFAC8" box="[1432,1445,1362,1377]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE797B66FA5FFADEFA69FAF0" box="[1465,1475,1358,1369]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
), 365, 323, 203, 161, 149, 143, 101
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FAF5F8D0FAD3" box="[130,1914,1381,1402]" gridrow="54" pageId="5" pageNumber="40">
|
||
<th id="768F5DC2CE79849CFF64FAF5FF34FAD3" box="[130,158,1381,1402]" gridcol="0" gridrow="54" pageId="5" pageNumber="40">95</th>
|
||
<td id="768F5DC2CE79849CFF51FAF5FDEAFAD3" box="[183,576,1381,1402]" gridcol="1" gridrow="54" pageId="5" pageNumber="40">C12H16O6 Hex</td>
|
||
<td id="768F5DC2CE79849CFD9EFAF5FD24FAD3" box="[632,654,1381,1402]" gridcol="2" gridrow="54" pageId="5" pageNumber="40">I</td>
|
||
<td id="768F5DC2CE79849CFD43FAF5FD60FAD3" box="[677,714,1381,1402]" gridcol="3" gridrow="54" pageId="5" pageNumber="40">269/</td>
|
||
<td id="768F5DC2CE79849CFD18FAF5FCCFFAD3" box="[766,869,1381,1402]" gridcol="4" gridrow="54" pageId="5" pageNumber="40">C18H26O11</td>
|
||
<td id="768F5DC2CE79849CFC2BFAF5FB95FAD3" box="[973,1087,1381,1402]" gridcol="5" gridrow="54" pageId="5" pageNumber="40">[M+Na] +</td>
|
||
<td id="768F5DC2CE79849CFBB6FAF5FB22FAD3" box="[1104,1160,1381,1402]" gridcol="6" gridrow="54" pageId="5" pageNumber="40">441.14</td>
|
||
<td id="768F5DC2CE79849CFB78FAF5FA95FAD3" box="[1182,1343,1381,1402]" gridcol="7" gridrow="54" pageId="5" pageNumber="40">4</td>
|
||
<td id="768F5DC2CE79849CFAB1FAF5F8D0FAD3" box="[1367,1914,1381,1402]" gridcol="8" gridrow="54" pageId="5" pageNumber="40">
|
||
<emphasis id="B91AEAEECE797B66FAB1FAF9FADCFADE" bold="true" box="[1367,1398,1385,1399]" pageId="5" pageNumber="40">463</emphasis>
|
||
([M-H+FA]
|
||
<emphasis id="B91AEAEECE797B66FA37FAF5FA71FAD9" box="[1489,1499,1381,1392]" italics="true" pageId="5" pageNumber="40">–</emphasis>
|
||
), 385, 241, 225, 179, 161, 153, 149, 143, 131, 119
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE79849CFF64FA10F8D0FA27" box="[130,1914,1408,1422]" gridrow="55" pageId="5" pageNumber="40" rowspan-0="1" rowspan-1="1" rowspan-2="1" rowspan-4="1" rowspan-5="1" rowspan-6="1" rowspan-7="1" rowspan-8="1">
|
||
<td id="768F5DC2CE79849CFD43FA10FD60FA27" box="[677,714,1408,1422]" gridcol="3" gridrow="55" pageId="5" pageNumber="40">279</td>
|
||
</tr>
|
||
</table>
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE7A7B65FCD9FF27FC6DFEB4" blockId="6.[831,1501,182,285]" pageId="6" pageNumber="41">
|
||
an unsaturated side chain and a ring hydroxy group. Beside 12- hydroxyjasmonic acid
|
||
<emphasis id="B91AEAEECE7A7B65FBCAFF41FB91FF4C" box="[1068,1083,209,229]" italics="true" pageId="6" pageNumber="41">O</emphasis>
|
||
-sulfate (
|
||
<bibRefCitation id="EFFF4B0DCE7A7B65FB7CFF42FAF2FF4C" author="Gidda, S. K. & Miersch, O. & Levitin, A. & Schmidt, J. & Wasternack, C. & Varin, L." box="[1178,1368,210,230]" pageId="6" pageNumber="41" pagination="17895 - 17900" refId="ref11611" refString="Gidda, S. K., Miersch, O., Levitin, A., Schmidt, J., Wasternack, C., Varin, L., 2003. Biochemical and molecular characterization of a hydroxyjasmonate sulfotransferase from Arabidopsis thaliana. J. Biol. Chem. 278, 17895 - 17900." type="journal article" year="2003">Gidda et al., 2003</bibRefCitation>
|
||
), compound
|
||
<emphasis id="B91AEAEECE7A7B65FCD9FF7EFCF2FEA8" bold="true" box="[831,856,238,257]" pageId="6" pageNumber="41">53</emphasis>
|
||
represents a novel sulfated jasmonic acid catabolite produced in
|
||
<taxonomicName id="4C6E4D7FCE7A7B65FCBFFE99FC68FEB4" box="[857,962,265,285]" class="Magnoliopsida" family="Brassicaceae" genus="Arabidopsis" kingdom="Plantae" order="Brassicales" pageId="6" pageNumber="41" phylum="Tracheophyta" rank="species" species="thaliana">
|
||
<emphasis id="B91AEAEECE7A7B65FCBFFE99FC68FEB4" box="[857,962,265,285]" italics="true" pageId="6" pageNumber="41">A. thaliana</emphasis>
|
||
</taxonomicName>
|
||
.
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE7A7B65FCD9FED1FB8EFEFC" blockId="6.[831,1501,321,1150]" box="[831,1060,321,341]" pageId="6" pageNumber="41">
|
||
<heading id="D0998190CE7A7B65FCD9FED1FB8EFEFC" box="[831,1060,321,341]" fontSize="8" level="3" pageId="6" pageNumber="41" reason="8">
|
||
<emphasis id="B91AEAEECE7A7B65FCD9FED1FB8EFEFC" box="[831,1060,321,341]" italics="true" pageId="6" pageNumber="41">2.4.5. Phenylpropanoids</emphasis>
|
||
</heading>
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE7A7B65FCD9FECDFB48FBD7" blockId="6.[831,1501,321,1150]" pageId="6" pageNumber="41">
|
||
<emphasis id="B91AEAEECE7A7B65FCD9FECDFC78FED8" box="[831,978,349,369]" italics="true" pageId="6" pageNumber="41">2.4.5.1. Lignols.</emphasis>
|
||
Coniferin (
|
||
<emphasis id="B91AEAEECE7A7B65FBA1FECEFBCAFED8" bold="true" box="[1095,1120,350,369]" pageId="6" pageNumber="41">54</emphasis>
|
||
) and syringin (
|
||
<emphasis id="B91AEAEECE7A7B65FB1AFECEFABFFED8" bold="true" box="[1276,1301,350,369]" pageId="6" pageNumber="41">55</emphasis>
|
||
) represent the predominant phenylpropanoids in dark-grown roots of
|
||
<taxonomicName id="4C6E4D7FCE7A7B65FA89FEE8FB80FE00" authority="(Bednarek et al., 2005)" baseAuthorityName="Bednarek" baseAuthorityYear="2005" class="Magnoliopsida" family="Brassicaceae" genus="Arabidopsis" kingdom="Plantae" order="Brassicales" pageId="6" pageNumber="41" phylum="Tracheophyta" rank="species" species="thaliana">
|
||
<emphasis id="B91AEAEECE7A7B65FA89FEE8FA76FE25" box="[1391,1500,376,396]" italics="true" pageId="6" pageNumber="41">A. thaliana</emphasis>
|
||
(
|
||
<bibRefCitation id="EFFF4B0DCE7A7B65FCA1FE05FB88FE01" author="Bednarek, P. & Schneider, B. & Svatos, A. & Oldham, N. J. & Hahlbrock, K." box="[839,1058,405,425]" pageId="6" pageNumber="41" pagination="1058 - 1070" refId="ref10904" refString="Bednarek, P., Schneider, B., Svatos, A., Oldham, N. J., Hahlbrock, K., 2005. Structural complexity, differential response to infection, and tissue specificity of indolic and phenylpropanoid secondary metabolism in Arabidopsis roots. Plant Physiol. 138, 1058 - 1070." type="journal article" year="2005">Bednarek et al., 2005</bibRefCitation>
|
||
)
|
||
</taxonomicName>
|
||
and were also detected in root exudates. Both monolignol glucosides were accompanied by related di- and trilignols and derivatives thereof. The identity and the linkage
|
||
<typeStatus id="54D5885ECE7A7B65FA56FE5EFA77FE48" box="[1456,1501,462,481]" pageId="6" pageNumber="41">type</typeStatus>
|
||
of these compounds was derived from the analysis of CID mass spectra obtained from corresponding [M
|
||
<emphasis id="B91AEAEECE7A7B65FAE5FD94FABEFDB1" box="[1283,1300,516,536]" italics="true" pageId="6" pageNumber="41">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE7A7B65FACAFD90FA92FDA4" box="[1324,1336,512,525]" italics="true" pageId="6" pageNumber="41">
|
||
<superScript id="7C1B9BB4CE7A7B65FACAFD90FA92FDA4" attach="left" box="[1324,1336,512,525]" fontSize="5" pageId="6" pageNumber="41">–</superScript>
|
||
</emphasis>
|
||
ions (
|
||
<bibRefCitation id="EFFF4B0DCE7A7B65FA6AFD95FC6FFD9D" author="Morreel, K. & Dima, O. & Kim, H. & Lu, F. C. & Niculaes, C. & Vanholme, R. & Dauwe, R. & Goeminne, G. & Inze, D. & Messens, E. & Ralph, J. & Boerjan, W." pageId="6" pageNumber="41" pagination="1464 - 1478" refId="ref12659" refString="Morreel, K., Dima, O., Kim, H., Lu, F. C., Niculaes, C., Vanholme, R., Dauwe, R., Goeminne, G., Inze, D., Messens, E., Ralph, J., Boerjan, W., 2010 a. Mass spectrometry-based sequencing of lignin oligomers. Plant Physiol. 153, 1464 - 1478." type="journal article" year="2010">Morreel et al., 2010a</bibRefCitation>
|
||
,b). The CID mass spectra of the β- aryl ether-type dimers
|
||
<emphasis id="B91AEAEECE7A7B65FC6DFDADFC0EFDF9" bold="true" box="[907,932,573,592]" pageId="6" pageNumber="41">56</emphasis>
|
||
and
|
||
<emphasis id="B91AEAEECE7A7B65FC31FDADFC5AFDF9" bold="true" box="[983,1008,573,592]" pageId="6" pageNumber="41">57</emphasis>
|
||
carrying an 8-
|
||
<emphasis id="B91AEAEECE7A7B65FB62FDACFB39FDF9" box="[1156,1171,572,592]" italics="true" pageId="6" pageNumber="41">O</emphasis>
|
||
-4 linkage exhibited a characteristic neutral loss of 48.02 Da according to a combined loss of water and formaldehyde from the [M
|
||
<emphasis id="B91AEAEECE7A7B65FB9CFDE4FB21FD21" box="[1146,1163,628,648]" italics="true" pageId="6" pageNumber="41">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE7A7B65FB45FDE0FB05FDD4" box="[1187,1199,624,637]" italics="true" pageId="6" pageNumber="41">
|
||
<superScript id="7C1B9BB4CE7A7B65FB45FDE0FB05FDD4" attach="left" box="[1187,1199,624,637]" fontSize="5" pageId="6" pageNumber="41">–</superScript>
|
||
</emphasis>
|
||
ion. In addition, formation of A
|
||
<emphasis id="B91AEAEECE7A7B65FCABFD1CFCF3FD30" box="[845,857,652,665]" italics="true" pageId="6" pageNumber="41">
|
||
<superScript id="7C1B9BB4CE7A7B65FCABFD1CFCF3FD30" attach="left" box="[845,857,652,665]" fontSize="5" pageId="6" pageNumber="41">–</superScript>
|
||
</emphasis>
|
||
and B
|
||
<emphasis id="B91AEAEECE7A7B65FC7CFD1CFC0CFD30" box="[922,934,652,665]" italics="true" pageId="6" pageNumber="41">
|
||
<superScript id="7C1B9BB4CE7A7B65FC7CFD1CFC0CFD30" attach="left" box="[922,934,652,665]" fontSize="5" pageId="6" pageNumber="41">–</superScript>
|
||
</emphasis>
|
||
fragment ions by cleavage of the aryl ether bond facilitated the identification of the aromatic units of these dimers (
|
||
<bibRefCitation id="EFFF4B0DCE7A7B65FCA1FD58FB8BFD72" author="Morreel, K. & Kim, H. & Lu, F. C. & Dima, O. & Akiyama, T. & Vanholme, R. & Niculaes, C. & Goeminne, G. & Inze, D. & Messens, E. & Ralph, J. & Boerjan, W." box="[839,1057,712,732]" pageId="6" pageNumber="41" pagination="8095 - 8105" refId="ref12740" refString="Morreel, K., Kim, H., Lu, F. C., Dima, O., Akiyama, T., Vanholme, R., Niculaes, C., Goeminne, G., Inze, D., Messens, E., Ralph, J., Boerjan, W., 2010 b. Mass spectrometry-based fragmentation as an identification tool in lignomics. Anal. Chem. 82, 8095 - 8105." type="journal article" year="2010">Morreel et al., 2010b</bibRefCitation>
|
||
). For the phenylcoumaran-type dimers
|
||
<emphasis id="B91AEAEECE7A7B65FA25FD58FA76FD72" bold="true" box="[1475,1500,712,731]" pageId="6" pageNumber="41">58</emphasis>
|
||
and
|
||
<emphasis id="B91AEAEECE7A7B65FC94FD74FC21FD5E" bold="true" box="[882,907,740,759]" pageId="6" pageNumber="41">59</emphasis>
|
||
with 8–5 linkage, fragmentation of the [M
|
||
<emphasis id="B91AEAEECE7A7B65FA89FD73FA2AFD5E" box="[1391,1408,739,759]" italics="true" pageId="6" pageNumber="41">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE7A7B65FA7EFD70FA0EFD44" box="[1432,1444,736,749]" italics="true" pageId="6" pageNumber="41">
|
||
<superScript id="7C1B9BB4CE7A7B65FA7EFD70FA0EFD44" attach="left" box="[1432,1444,736,749]" fontSize="5" pageId="6" pageNumber="41">–</superScript>
|
||
</emphasis>
|
||
ions resulted in dominating neutral losses of 18.01 Da (H
|
||
<subScript id="17EA34B9CE7A7B65FA61FC99FA3AFCBC" attach="both" box="[1415,1424,777,789]" fontSize="5" pageId="6" pageNumber="41">2</subScript>
|
||
O) and 30.01 Da (
|
||
<collectingCountry id="F379766CCE7A7B65FC43FC8CFC6FFC86" box="[933,965,796,815]" name="Switzerland" pageId="6" pageNumber="41">CH</collectingCountry>
|
||
<subScript id="17EA34B9CE7A7B65FC23FCB5FC64FC98" attach="both" box="[965,974,805,817]" fontSize="5" pageId="6" pageNumber="41">2</subScript>
|
||
O) (
|
||
<bibRefCitation id="EFFF4B0DCE7A7B65FC10FC8CFB64FC86" author="Morreel, K. & Kim, H. & Lu, F. C. & Dima, O. & Akiyama, T. & Vanholme, R. & Niculaes, C. & Goeminne, G. & Inze, D. & Messens, E. & Ralph, J. & Boerjan, W." box="[1014,1230,796,815]" pageId="6" pageNumber="41" pagination="8095 - 8105" refId="ref12740" refString="Morreel, K., Kim, H., Lu, F. C., Dima, O., Akiyama, T., Vanholme, R., Niculaes, C., Goeminne, G., Inze, D., Messens, E., Ralph, J., Boerjan, W., 2010 b. Mass spectrometry-based fragmentation as an identification tool in lignomics. Anal. Chem. 82, 8095 - 8105." type="journal article" year="2010">Morreel et al., 2010b</bibRefCitation>
|
||
). Three resinol-type dilignols with 8–8 linkage including syringaresinol (
|
||
<emphasis id="B91AEAEECE7A7B65FAD3FCA8FAE4FCE2" bold="true" box="[1333,1358,824,843]" pageId="6" pageNumber="41">60</emphasis>
|
||
), lariciresinol (
|
||
<emphasis id="B91AEAEECE7A7B65FCA1FCC4FCCAFCCE" bold="true" box="[839,864,852,871]" pageId="6" pageNumber="41">61</emphasis>
|
||
) and a derived hexoside (
|
||
<emphasis id="B91AEAEECE7A7B65FB88FCC4FB2DFCCE" bold="true" box="[1134,1159,852,871]" pageId="6" pageNumber="41">62</emphasis>
|
||
) were found in root exudates. In accordance with the literature, the CID mass spectrum obtained from deprotonated
|
||
<emphasis id="B91AEAEECE7A7B65FBE3FC1BFBB4FC37" bold="true" box="[1029,1054,907,926]" pageId="6" pageNumber="41">60</emphasis>
|
||
showed the product ions [M
|
||
<emphasis id="B91AEAEECE7A7B65FAA0FC1BFAFDFC36" box="[1350,1367,907,927]" italics="true" pageId="6" pageNumber="41">–</emphasis>
|
||
H-CH
|
||
<subScript id="17EA34B9CE7A7B65FA68FC05FA3DFC08" attach="left" box="[1422,1431,917,929]" fontSize="5" pageId="6" pageNumber="41">3</subScript>
|
||
]
|
||
<superScript id="7C1B9BB4CE7A7B65FA79FC17FA05FC3D" attach="left" box="[1439,1455,903,916]" fontSize="5" pageId="6" pageNumber="41">
|
||
.
|
||
<emphasis id="B91AEAEECE7A7B65FA45FC17FA05FC3D" box="[1443,1455,903,916]" italics="true" pageId="6" pageNumber="41">–</emphasis>
|
||
</superScript>
|
||
and [M
|
||
<emphasis id="B91AEAEECE7A7B65FCBDFC36FCC6FC13" box="[859,876,934,954]" italics="true" pageId="6" pageNumber="41">–</emphasis>
|
||
H-CH
|
||
<subScript id="17EA34B9CE7A7B65FC45FC21FC06FC14" attach="both" box="[931,940,945,957]" fontSize="5" pageId="6" pageNumber="41">2</subScript>
|
||
O]
|
||
<emphasis id="B91AEAEECE7A7B65FC25FC33FC65FC19" box="[963,975,931,944]" italics="true" pageId="6" pageNumber="41">
|
||
<superScript id="7C1B9BB4CE7A7B65FC25FC33FC65FC19" attach="left" box="[963,975,931,944]" fontSize="5" pageId="6" pageNumber="41">–</superScript>
|
||
</emphasis>
|
||
as well as a
|
||
<superScript id="7C1B9BB4CE7A7B65FB97FC33FB22FC06" attach="right" box="[1137,1160,931,943]" fontSize="5" pageId="6" pageNumber="41">2,5</superScript>
|
||
X
|
||
<emphasis id="B91AEAEECE7A7B65FB70FC33FB08FC19" box="[1174,1186,931,944]" italics="true" pageId="6" pageNumber="41">
|
||
<superScript id="7C1B9BB4CE7A7B65FB70FC33FB08FC19" attach="left" box="[1174,1186,931,944]" fontSize="5" pageId="6" pageNumber="41">–</superScript>
|
||
</emphasis>
|
||
fragment ion at
|
||
<emphasis id="B91AEAEECE7A7B65FA80FC36FAD3FC13" box="[1382,1401,934,954]" italics="true" pageId="6" pageNumber="41">m</emphasis>
|
||
/
|
||
<emphasis id="B91AEAEECE7A7B65FA67FC36FA21FC13" box="[1409,1419,934,954]" italics="true" pageId="6" pageNumber="41">z</emphasis>
|
||
181.05 (
|
||
<bibRefCitation id="EFFF4B0DCE7A7B65FCA1FC53FBB5FC7F" author="Morreel, K. & Kim, H. & Lu, F. C. & Dima, O. & Akiyama, T. & Vanholme, R. & Niculaes, C. & Goeminne, G. & Inze, D. & Messens, E. & Ralph, J. & Boerjan, W." box="[839,1055,963,983]" pageId="6" pageNumber="41" pagination="8095 - 8105" refId="ref12740" refString="Morreel, K., Kim, H., Lu, F. C., Dima, O., Akiyama, T., Vanholme, R., Niculaes, C., Goeminne, G., Inze, D., Messens, E., Ralph, J., Boerjan, W., 2010 b. Mass spectrometry-based fragmentation as an identification tool in lignomics. Anal. Chem. 82, 8095 - 8105." type="journal article" year="2010">Morreel et al., 2010b</bibRefCitation>
|
||
). The accumulation of glycosylated syringaresinol and lariciresinol in roots of
|
||
<taxonomicName id="4C6E4D7FCE7A7B65FB28FC4EFA91FC5B" box="[1230,1339,990,1010]" class="Magnoliopsida" family="Brassicaceae" genus="Arabidopsis" kingdom="Plantae" order="Brassicales" pageId="6" pageNumber="41" phylum="Tracheophyta" rank="species" species="thaliana">
|
||
<emphasis id="B91AEAEECE7A7B65FB28FC4EFA91FC5B" box="[1230,1339,990,1010]" italics="true" pageId="6" pageNumber="41">A. thaliana</emphasis>
|
||
</taxonomicName>
|
||
was described (
|
||
<bibRefCitation id="EFFF4B0DCE7A7B65FCA1FC6BFBB1FBA7" author="Matsuda, F. & Hirai, M. Y. & Sasaki, E. & Akiyama, K. & Yonekura-Sakakibara, K. & Provart, N. J. & Sakurai, T. & Shimada, Y. & Saito, K." box="[839,1051,1019,1038]" pageId="6" pageNumber="41" pagination="566 - 578" refId="ref12522" refString="Matsuda, F., Hirai, M. Y., Sasaki, E., Akiyama, K., Yonekura-Sakakibara, K., Provart, N. J., Sakurai, T., Shimada, Y., Saito, K., 2010. AtMetExpress development: a phytochemical atlas of Arabidopsis development. Plant Physiol. 152, 566 - 578." type="journal article" year="2010">Matsuda et al., 2010</bibRefCitation>
|
||
;
|
||
<bibRefCitation id="EFFF4B0DCE7A7B65FBC1FC6BFAA1FBA7" author="Nakatsubo, T. & Mizutani, M. & Suzuki, S. & Hattori, T. & Umezawa, T." box="[1063,1291,1019,1038]" pageId="6" pageNumber="41" pagination="15550 - 15557" refId="ref12914" refString="Nakatsubo, T., Mizutani, M., Suzuki, S., Hattori, T., Umezawa, T., 2008. Characterization of Arabidopsis thaliana pinoresinol reductase, a new type of enzyme involved in lignan biosynthesis. J. Biol. Chem. 283, 15550 - 15557." type="journal article" year="2008">Nakatsubo et al., 2008</bibRefCitation>
|
||
). Based on the fragmentation characteristics observed for dilignols, three trilignols (
|
||
<emphasis id="B91AEAEECE7A7B65FCA1FBA3FC2CFBEF" bold="true" box="[839,902,1075,1094]" pageId="6" pageNumber="41">63–65</emphasis>
|
||
) with coniferyl and syringyl alcohol as monomeric untis were tentatively identified based on the fragmentation characteristics observed for corresponding dilignols.
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE7A7B65FCD9FB31FB4DFAF4" blockId="6.[831,1501,1185,2015]" pageId="6" pageNumber="41">
|
||
<emphasis id="B91AEAEECE7A7B65FCD9FB31FC57FB1C" box="[831,1021,1185,1205]" italics="true" pageId="6" pageNumber="41">2.4.5.2. Coumarins.</emphasis>
|
||
The coumarin glucoside scopolin represents another abundant root phenylpropanoid (
|
||
<bibRefCitation id="EFFF4B0DCE7A7B65FB13FB2EFA72FB78" author="Bednarek, P. & Schneider, B. & Svatos, A. & Oldham, N. J. & Hahlbrock, K." box="[1269,1496,1214,1234]" pageId="6" pageNumber="41" pagination="1058 - 1070" refId="ref10904" refString="Bednarek, P., Schneider, B., Svatos, A., Oldham, N. J., Hahlbrock, K., 2005. Structural complexity, differential response to infection, and tissue specificity of indolic and phenylpropanoid secondary metabolism in Arabidopsis roots. Plant Physiol. 138, 1058 - 1070." type="journal article" year="2005">Bednarek et al., 2005</bibRefCitation>
|
||
;
|
||
<bibRefCitation id="EFFF4B0DCE7A7B65FCD9FB4AFC71FB44" author="Kai, K. & Shimizu, B. & Mizutani, M. & Watanabe, K. & Sakata, K." box="[831,987,1242,1262]" pageId="6" pageNumber="41" pagination="379 - 386" refId="ref11937" refString="Kai, K., Shimizu, B., Mizutani, M., Watanabe, K., Sakata, K., 2006. Accumulation of coumarins in Arabidopsis thaliana. Phytochemistry 67, 379 - 386." type="journal article" year="2006">Kai et al., 2006</bibRefCitation>
|
||
). It was recently shown, that the biosynthesis of coumarins in roots and their exudation can be stimulated inter alia upon iron deprivation indicating that coumarins are involved in the acquisition of iron in
|
||
<taxonomicName id="4C6E4D7FCE7A7B65FB81FABDFB7DFAE8" box="[1127,1239,1325,1345]" class="Magnoliopsida" family="Brassicaceae" genus="Arabidopsis" kingdom="Plantae" order="Brassicales" pageId="6" pageNumber="41" phylum="Tracheophyta" rank="species" species="thaliana">
|
||
<emphasis id="B91AEAEECE7A7B65FB81FABDFB7DFAE8" box="[1127,1239,1325,1345]" italics="true" pageId="6" pageNumber="41">A. thaliana</emphasis>
|
||
</taxonomicName>
|
||
(
|
||
<bibRefCitation id="EFFF4B0DCE7A7B65FB08FABEFA72FAE8" author="Fourcroy, P. & Siso-Terraza, P. & Sudre, D. & Saviron, M. & Reyt, G. & Gaymard, F. & Abadia, A. & Abadia, J. & Alvarez-Fernandez, A. & Briat, J. F." box="[1262,1496,1326,1345]" pageId="6" pageNumber="41" pagination="155 - 167" refId="ref11473" refString="Fourcroy, P., Siso-Terraza, P., Sudre, D., Saviron, M., Reyt, G., Gaymard, F., Abadia, A., Abadia, J., Alvarez-Fernandez, A., Briat, J. F., 2014. Involvement of the ABCG 37 transporter in secretion of scopoletin and derivatives by Arabidopsis roots in response to iron deficiency. New Phytol. 201, 155 - 167." type="journal article" year="2014">Fourcroy et al., 2014</bibRefCitation>
|
||
;
|
||
<bibRefCitation id="EFFF4B0DCE7A7B65FCD9FADAFBAEFAF4" author="Schmid, N. B. & Giehl, R. F. & Doll, S. & Mock, H. P. & Strehmel, N. & Scheel, D. & Kong, X. & Hider, R. C. & von Wiren, N." box="[831,1028,1354,1373]" pageId="6" pageNumber="41" pagination="160 - 172" refId="ref13238" refString="Schmid, N. B., Giehl, R. F., Doll, S., Mock, H. P., Strehmel, N., Scheel, D., Kong, X., Hider, R. C., von Wiren, N., 2014. Feruloyl-CoA 6 ' - Hydroxylase 1 - dependent coumarins mediate iron acquisition from alkaline substrates in Arabidopsis. Plant Physiol. 164, 160 - 172." type="journal article" year="2014">Schmid et al., 2014</bibRefCitation>
|
||
;
|
||
<bibRefCitation id="EFFF4B0DCE7A7B65FBF6FADAFB70FAF4" author="Schmidt, H. & Gunther, C. & Weber, M. & Sporlein, C. & Loscher, S. & Bottcher, C. & Schobert, R. & Clemens, S." box="[1040,1242,1354,1373]" pageId="6" pageNumber="41" pagination="102444" refId="ref13321" refString="Schmidt, H., Gunther, C., Weber, M., Sporlein, C., Loscher, S., Bottcher, C., Schobert, R., Clemens, S., 2014. Metabolome analysis of Arabidopsis thaliana roots identifies a key metabolic pathway for iron acquisition. PLoS One 9 (7), e 102444." type="journal article" year="2014">Schmidt et al., 2014</bibRefCitation>
|
||
).
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE7A7B64FCB8FAF6FECBF865" blockId="6.[831,1501,1185,2015]" lastBlockId="7.[87,757,1864,1996]" lastPageId="7" lastPageNumber="42" pageId="6" pageNumber="41">
|
||
Esculetin (
|
||
<emphasis id="B91AEAEECE7A7B65FC2DFAF6FC4EFAD0" bold="true" box="[971,996,1382,1401]" pageId="6" pageNumber="41">66</emphasis>
|
||
), scopoletin (
|
||
<emphasis id="B91AEAEECE7A7B65FB92FAF6FB27FAD0" bold="true" box="[1140,1165,1382,1401]" pageId="6" pageNumber="41">67</emphasis>
|
||
) and its glucosides esculin (
|
||
<emphasis id="B91AEAEECE7A7B65FA5DFAF6FA7EFAD0" bold="true" box="[1467,1492,1382,1401]" pageId="6" pageNumber="41">68</emphasis>
|
||
) and scopolin (
|
||
<emphasis id="B91AEAEECE7A7B65FC35FA11FC46FA3D" bold="true" box="[979,1004,1409,1428]" pageId="6" pageNumber="41">69</emphasis>
|
||
) were detected in root exudates and identified by authenticated standards. Beside these coumarins which are already known to be exuded from roots (
|
||
<bibRefCitation id="EFFF4B0DCE7A7B65FB1CFA2AFA72FA65" author="Fourcroy, P. & Siso-Terraza, P. & Sudre, D. & Saviron, M. & Reyt, G. & Gaymard, F. & Abadia, A. & Abadia, J. & Alvarez-Fernandez, A. & Briat, J. F." box="[1274,1496,1465,1485]" pageId="6" pageNumber="41" pagination="155 - 167" refId="ref11473" refString="Fourcroy, P., Siso-Terraza, P., Sudre, D., Saviron, M., Reyt, G., Gaymard, F., Abadia, A., Abadia, J., Alvarez-Fernandez, A., Briat, J. F., 2014. Involvement of the ABCG 37 transporter in secretion of scopoletin and derivatives by Arabidopsis roots in response to iron deficiency. New Phytol. 201, 155 - 167." type="journal article" year="2014">Fourcroy et al., 2014</bibRefCitation>
|
||
;
|
||
<bibRefCitation id="EFFF4B0DCE7A7B65FCD9FA45FBA2FA41" author="Schmid, N. B. & Giehl, R. F. & Doll, S. & Mock, H. P. & Strehmel, N. & Scheel, D. & Kong, X. & Hider, R. C. & von Wiren, N." box="[831,1032,1493,1513]" pageId="6" pageNumber="41" pagination="160 - 172" refId="ref13238" refString="Schmid, N. B., Giehl, R. F., Doll, S., Mock, H. P., Strehmel, N., Scheel, D., Kong, X., Hider, R. C., von Wiren, N., 2014. Feruloyl-CoA 6 ' - Hydroxylase 1 - dependent coumarins mediate iron acquisition from alkaline substrates in Arabidopsis. Plant Physiol. 164, 160 - 172." type="journal article" year="2014">Schmid et al., 2014</bibRefCitation>
|
||
), further esculetin and scopoletin conjugates were tentatively identified in root exudates on the basis of their mass spectral fragmentation pattern. Scopoletin was found to be conjugated to a hexose–pentose and to a benzoylated hexose–pentose as indicated by a neutral loss of 294.10 Da (C
|
||
<subScript id="17EA34B9CE7A7B65FACCF9DEFA97F9F3" attach="both" box="[1322,1341,1614,1626]" fontSize="5" pageId="6" pageNumber="41">11</subScript>
|
||
H
|
||
<subScript id="17EA34B9CE7A7B65FAABF9DEFACAF9F3" attach="both" box="[1357,1376,1614,1626]" fontSize="5" pageId="6" pageNumber="41">18</subScript>
|
||
O
|
||
<subScript id="17EA34B9CE7A7B65FA89F9DEFAD2F9F3" attach="left" box="[1391,1400,1614,1626]" fontSize="5" pageId="6" pageNumber="41">9</subScript>
|
||
) from the [M
|
||
<emphasis id="B91AEAEECE7A7B65FCBDF9F0FCC6F9DD" box="[859,876,1632,1652]" italics="true" pageId="6" pageNumber="41">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE7A7B65FC62F9CCFC3AF9C0" box="[900,912,1628,1641]" italics="true" pageId="6" pageNumber="41">
|
||
<superScript id="7C1B9BB4CE7A7B65FC62F9CCFC3AF9C0" attach="left" box="[900,912,1628,1641]" fontSize="5" pageId="6" pageNumber="41">–</superScript>
|
||
</emphasis>
|
||
ion of
|
||
<emphasis id="B91AEAEECE7A7B65FC00F9F1FC55F9DD" bold="true" box="[998,1023,1633,1652]" pageId="6" pageNumber="41">70</emphasis>
|
||
and consecutive neutral losses of 122.04 Da (C
|
||
<subScript id="17EA34B9CE7A7B65FCB2F916FCF7F93B" attach="both" box="[852,861,1670,1682]" fontSize="5" pageId="6" pageNumber="41">7</subScript>
|
||
H
|
||
<subScript id="17EA34B9CE7A7B65FC88F916FCDDF93B" attach="right" box="[878,887,1670,1682]" fontSize="5" pageId="6" pageNumber="41">6</subScript>
|
||
O
|
||
<subScript id="17EA34B9CE7A7B65FC61F916FC3AF93B" attach="left" box="[903,912,1670,1682]" fontSize="5" pageId="6" pageNumber="41">2</subScript>
|
||
) and 294.10 Da from the [M
|
||
<emphasis id="B91AEAEECE7A7B65FB51F9ECFB62F939" box="[1207,1224,1660,1680]" italics="true" pageId="6" pageNumber="41">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE7A7B65FB06F9E8FB46F92C" box="[1248,1260,1656,1669]" italics="true" pageId="6" pageNumber="41">
|
||
<superScript id="7C1B9BB4CE7A7B65FB06F9E8FB46F92C" attach="left" box="[1248,1260,1656,1669]" fontSize="5" pageId="6" pageNumber="41">–</superScript>
|
||
</emphasis>
|
||
ion of
|
||
<emphasis id="B91AEAEECE7A7B65FADEF9EDFAFBF939" bold="true" box="[1336,1361,1661,1680]" pageId="6" pageNumber="41">71</emphasis>
|
||
, respectively. In addition, an 8-
|
||
<emphasis id="B91AEAEECE7A7B65FC0AF908FC51F905" box="[1004,1019,1688,1708]" italics="true" pageId="6" pageNumber="41">O</emphasis>
|
||
-4-linked coniferylalcohol–scopoletin conjugate (
|
||
<emphasis id="B91AEAEECE7A7B65FCA1F924FCCAF96E" bold="true" box="[839,864,1716,1735]" pageId="6" pageNumber="41">72</emphasis>
|
||
) was annotated based on the occurrence of a characteristic neutral loss of 48.02 Da from its [M
|
||
<emphasis id="B91AEAEECE7A7B65FB5AF95FFB67F94A" box="[1212,1229,1743,1763]" italics="true" pageId="6" pageNumber="41">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE7A7B65FB03F95CFB5BF970" box="[1253,1265,1740,1753]" italics="true" pageId="6" pageNumber="41">
|
||
<superScript id="7C1B9BB4CE7A7B65FB03F95CFB5BF970" attach="left" box="[1253,1265,1740,1753]" fontSize="5" pageId="6" pageNumber="41">–</superScript>
|
||
</emphasis>
|
||
ion and characteristic A
|
||
<emphasis id="B91AEAEECE7A7B65FCABF978FCF3F95C" box="[845,857,1768,1781]" italics="true" pageId="6" pageNumber="41">
|
||
<superScript id="7C1B9BB4CE7A7B65FCABF978FCF3F95C" attach="left" box="[845,857,1768,1781]" fontSize="5" pageId="6" pageNumber="41">–</superScript>
|
||
</emphasis>
|
||
and B
|
||
<emphasis id="B91AEAEECE7A7B65FC70F978FC08F95C" box="[918,930,1768,1781]" italics="true" pageId="6" pageNumber="41">
|
||
<superScript id="7C1B9BB4CE7A7B65FC70F978FC08F95C" attach="left" box="[918,930,1768,1781]" fontSize="5" pageId="6" pageNumber="41">–</superScript>
|
||
</emphasis>
|
||
fragment ions at
|
||
<emphasis id="B91AEAEECE7A7B65FBA9F97BFBC8F956" box="[1103,1122,1771,1791]" italics="true" pageId="6" pageNumber="41">m</emphasis>
|
||
/
|
||
<emphasis id="B91AEAEECE7A7B65FB8CF97BFBDEF956" box="[1130,1140,1771,1791]" italics="true" pageId="6" pageNumber="41">z</emphasis>
|
||
195.07 and
|
||
<emphasis id="B91AEAEECE7A7B65FB0AF97BFB55F956" box="[1260,1279,1771,1791]" italics="true" pageId="6" pageNumber="41">m</emphasis>
|
||
/
|
||
<emphasis id="B91AEAEECE7A7B65FAE1F97BFABBF956" box="[1287,1297,1771,1791]" italics="true" pageId="6" pageNumber="41">z</emphasis>
|
||
191.03. Compounds
|
||
<emphasis id="B91AEAEECE7A7B65FCD9F898FCF2F8B2" bold="true" box="[831,856,1800,1819]" pageId="6" pageNumber="41">73</emphasis>
|
||
and
|
||
<emphasis id="B91AEAEECE7A7B65FC69F898FC02F8B2" bold="true" box="[911,936,1800,1819]" pageId="6" pageNumber="41">74</emphasis>
|
||
were tentatively identified as 8-
|
||
<emphasis id="B91AEAEECE7A7B65FB19F897FAA4F8B2" box="[1279,1294,1799,1819]" italics="true" pageId="6" pageNumber="41">O</emphasis>
|
||
-4-linked cross-coupling products of coniferyl alcohol with esculetin and syringyl alcohol with esculetin, respectively. The presence of an unsubstitued 3- OH group in the esculetin moiety thereby results in the formation of a benzodioxane-type linkage motif. In accordance with the literature (
|
||
<bibRefCitation id="EFFF4B0DCE7A7B65FC6EF804FBC6F80E" author="Morreel, K. & Kim, H. & Lu, F. C. & Dima, O. & Akiyama, T. & Vanholme, R. & Niculaes, C. & Goeminne, G. & Inze, D. & Messens, E. & Ralph, J. & Boerjan, W." box="[904,1132,1940,1959]" pageId="6" pageNumber="41" pagination="8095 - 8105" refId="ref12740" refString="Morreel, K., Kim, H., Lu, F. C., Dima, O., Akiyama, T., Vanholme, R., Niculaes, C., Goeminne, G., Inze, D., Messens, E., Ralph, J., Boerjan, W., 2010 b. Mass spectrometry-based fragmentation as an identification tool in lignomics. Anal. Chem. 82, 8095 - 8105." type="journal article" year="2010">Morreel et al., 2010b</bibRefCitation>
|
||
), CID of deprotonated
|
||
<emphasis id="B91AEAEECE7A7B65FA8DF803FA2EF80F" bold="true" box="[1387,1412,1939,1958]" pageId="6" pageNumber="41">73</emphasis>
|
||
and
|
||
<emphasis id="B91AEAEECE7A7B65FA25F803FA76F80F" bold="true" box="[1475,1500,1939,1958]" pageId="6" pageNumber="41">74</emphasis>
|
||
resulted in neutral losses of water and formaldehyde from the [M
|
||
<emphasis id="B91AEAEECE7A7B65FCBDF85AFCC6F877" box="[859,876,1994,2014]" italics="true" pageId="6" pageNumber="41">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE7A7B65FC62F857FC3AF87D" box="[900,912,1991,2004]" italics="true" pageId="6" pageNumber="41">
|
||
<superScript id="7C1B9BB4CE7A7B65FC62F857FC3AF87D" attach="left" box="[900,912,1991,2004]" fontSize="5" pageId="6" pageNumber="41">–</superScript>
|
||
</emphasis>
|
||
ion and formation of A
|
||
<emphasis id="B91AEAEECE7A7B65FB74F857FB34F87D" box="[1170,1182,1991,2004]" italics="true" pageId="6" pageNumber="41">
|
||
<superScript id="7C1B9BB4CE7A7B65FB74F857FB34F87D" attach="left" box="[1170,1182,1991,2004]" fontSize="5" pageId="6" pageNumber="41">–</superScript>
|
||
</emphasis>
|
||
and B
|
||
<emphasis id="B91AEAEECE7A7B65FB01F857FB59F87D" box="[1255,1267,1991,2004]" italics="true" pageId="6" pageNumber="41">
|
||
<superScript id="7C1B9BB4CE7A7B65FB01F857FB59F87D" attach="left" box="[1255,1267,1991,2004]" fontSize="5" pageId="6" pageNumber="41">–</superScript>
|
||
</emphasis>
|
||
fragment ions at
|
||
<emphasis id="B91AEAEECE7A7B65FA5EF85AFA61F877" box="[1464,1483,1994,2014]" italics="true" pageId="6" pageNumber="41">m</emphasis>
|
||
/
|
||
<emphasis id="B91AEAEECE7A7B65FA34F85AFA76F877" box="[1490,1500,1994,2014]" italics="true" pageId="6" pageNumber="41">z</emphasis>
|
||
179.07 and
|
||
<emphasis id="B91AEAEECE7B7B64FF36F8D8FF49F8F5" box="[208,227,1864,1884]" italics="true" pageId="7" pageNumber="42">m</emphasis>
|
||
/
|
||
<emphasis id="B91AEAEECE7B7B64FF0DF8D8FF5FF8F5" box="[235,245,1864,1884]" italics="true" pageId="7" pageNumber="42">z</emphasis>
|
||
177.02 for
|
||
<emphasis id="B91AEAEECE7B7B64FE8BF8D9FE2CF8F5" bold="true" box="[365,390,1865,1884]" pageId="7" pageNumber="42">73</emphasis>
|
||
and
|
||
<emphasis id="B91AEAEECE7B7B64FE5DF8D8FE64F8F5" box="[443,462,1864,1884]" italics="true" pageId="7" pageNumber="42">m</emphasis>
|
||
/
|
||
<emphasis id="B91AEAEECE7B7B64FE30F8D8FE4AF8F5" box="[470,480,1864,1884]" italics="true" pageId="7" pageNumber="42">z</emphasis>
|
||
209.08 and
|
||
<emphasis id="B91AEAEECE7B7B64FD86F8D8FDD9F8F5" box="[608,627,1864,1884]" italics="true" pageId="7" pageNumber="42">m</emphasis>
|
||
/
|
||
<emphasis id="B91AEAEECE7B7B64FD9DF8D8FD2FF8F5" box="[635,645,1864,1884]" italics="true" pageId="7" pageNumber="42">z</emphasis>
|
||
177.02 for
|
||
<emphasis id="B91AEAEECE7B7B64FFB1F8F5FFDAF8D1" bold="true" box="[87,112,1893,1912]" pageId="7" pageNumber="42">74</emphasis>
|
||
. In addition, a scopoletin dehydrodimer (
|
||
<emphasis id="B91AEAEECE7B7B64FDC9F8F5FDE2F8D1" bold="true" box="[559,584,1893,1912]" pageId="7" pageNumber="42">75</emphasis>
|
||
) with unknown linkage motif and an unknown oligolignol (
|
||
<emphasis id="B91AEAEECE7B7B64FDF0F811FD85F83D" bold="true" box="[534,559,1921,1940]" pageId="7" pageNumber="42">76</emphasis>
|
||
) with four phenylpropanoid units of which one was identified as scopoletin were detected in root exudates.
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE7A7B65FF91F83BFE94FF4E" pageId="6" pageNumber="41">
|
||
<table id="F96EC45CCE7A849CFF95FF58FEEAF816" box="[115,320,200,1983]" colsContinueFrom="5.[130,1914,126,1422]" gridcols="9" gridrows="9" pageId="6" pageNumber="41" textDirection="bu">
|
||
<tr id="355E34BECE7A849CFF95FF58FF23F816" box="[115,137,200,1983]" gridrow="0" pageId="6" pageNumber="41" textDirection="bu">
|
||
<th id="768F5DC2CE7A849CFF95F831FF23F816" box="[115,137,1953,1983]" gridcol="0" gridrow="0" pageId="6" pageNumber="41" textDirection="bu">96</th>
|
||
<th id="768F5DC2CE7A849CFF95F93DFF23F822" box="[115,137,1709,1931]" gridcol="1" gridrow="0" pageId="6" pageNumber="41" textDirection="bu">Unknown</th>
|
||
<th id="768F5DC2CE7A849CFF95FA2FFF23FA60" box="[115,137,1471,1481]" gridcol="2" gridrow="0" pageId="6" pageNumber="41" textDirection="bu">–</th>
|
||
<th id="768F5DC2CE7A849CFF95FAE7FF23FA34" box="[115,137,1399,1437]" gridcol="3" gridrow="0" pageId="6" pageNumber="41" textDirection="bu">326 /</th>
|
||
<th id="768F5DC2CE7A849CFF95FB45FF23FAEB" box="[115,137,1237,1346]" gridcol="4" gridrow="0" pageId="6" pageNumber="41" textDirection="bu">
|
||
C12
|
||
<collectionCode id="ED7FAE39CE7A7B65FF91FA8CFF2DFA80" box="[119,135,1308,1321]" country="Finland" lsid="urn:lsid:biocol.org:col:15618" name="University of Helsinki" pageId="6" pageNumber="41" type="Herbarium">H</collectionCode>
|
||
16
|
||
<collectionCode id="ED7FAE39CE7A7B65FF91FA91FF2DFAA7" box="[119,135,1281,1294]" country="Norway" lsid="urn:lsid:biocol.org:col:13093" name="Botanical Museum - University of Oslo" pageId="6" pageNumber="41" type="Herbarium">O</collectionCode>
|
||
6
|
||
</th>
|
||
<th id="768F5DC2CE7A849CFF95FB83FF23FBDC" box="[115,137,1043,1141]" gridcol="5" gridrow="0" pageId="6" pageNumber="41" textDirection="bu">
|
||
[M + Na]
|
||
<subScript id="17EA34B9CE7A7B65FF95FBA0FFD4FB9E" attach="right" box="[115,126,1072,1079]" fontSize="4" pageId="6" pageNumber="41">
|
||
<superScript id="7C1B9BB4CE7A7B65FF95FBA0FFD4FB9E" attach="none" box="[115,126,1072,1079]" fontSize="4" pageId="6" pageNumber="41">+</superScript>
|
||
</subScript>
|
||
</th>
|
||
<th id="768F5DC2CE7A849CFF95FC2AFF23FC58" box="[115,137,954,1009]" gridcol="6" gridrow="0" pageId="6" pageNumber="41" textDirection="bu">279.08</th>
|
||
<th id="768F5DC2CE7A849CFF95FC1FFF23FC0A" box="[115,137,911,931]" gridcol="7" gridrow="0" pageId="6" pageNumber="41" textDirection="bu">1</th>
|
||
<th id="768F5DC2CE7A849CFF95FF58FF23FD42" box="[115,137,200,747]" gridcol="8" gridrow="0" pageId="6" pageNumber="41" textDirection="bu">
|
||
239 ([M + H-H O]
|
||
<superScript id="7C1B9BB4CE7A7B65FF95FDCDFFD4FDCD" attach="right" box="[115,126,605,612]" fontSize="4" pageId="6" pageNumber="41">+</superScript>
|
||
), 207, 179, 147, 119
|
||
<subScript id="17EA34B9CE7A7B65FF98FDE7FF23FDD7" attach="left" box="[126,137,631,638]" fontSize="4" pageId="6" pageNumber="41">2</subScript>
|
||
</th>
|
||
</tr>
|
||
<tr id="355E34BECE7A849CFF68FF58FF34F816" box="[142,158,200,1983]" gridrow="1" pageId="6" pageNumber="41" rowspan-0="1" rowspan-1="1" rowspan-2="1" rowspan-4="1" rowspan-5="1" rowspan-6="1" rowspan-7="1" rowspan-8="1" textDirection="bu">
|
||
<td id="768F5DC2CE7A849CFF68FAE7FF34FA34" box="[142,158,1399,1437]" gridcol="3" gridrow="1" pageId="6" pageNumber="41" textDirection="bu">339</td>
|
||
</tr>
|
||
<tr id="355E34BECE7A849CFF47FF58FF1DF816" box="[161,183,200,1983]" gridrow="2" pageId="6" pageNumber="41" textDirection="bu">
|
||
<th id="768F5DC2CE7A849CFF47F831FF1DF816" box="[161,183,1953,1983]" gridcol="0" gridrow="2" pageId="6" pageNumber="41" textDirection="bu">97</th>
|
||
<td id="768F5DC2CE7A849CFF47F93DFF1DF822" box="[161,183,1709,1931]" gridcol="1" gridrow="2" pageId="6" pageNumber="41" textDirection="bu">
|
||
C 14 H 28 O
|
||
<superScript id="7C1B9BB4CE7A7B65FF4AF8D1FF1DF8E1" attach="left" box="[172,183,1857,1864]" fontSize="4" pageId="6" pageNumber="41">5</superScript>
|
||
Malonyl-Hex
|
||
</td>
|
||
<td id="768F5DC2CE7A849CFF47FA2FFF1DFA60" box="[161,183,1471,1481]" gridcol="2" gridrow="2" pageId="6" pageNumber="41" textDirection="bu">I</td>
|
||
<td id="768F5DC2CE7A849CFF47FAE7FF1DFA34" box="[161,183,1399,1437]" gridcol="3" gridrow="2" pageId="6" pageNumber="41" textDirection="bu">404</td>
|
||
<td id="768F5DC2CE7A849CFF47FB45FF1DFAEB" box="[161,183,1237,1346]" gridcol="4" gridrow="2" pageId="6" pageNumber="41" textDirection="bu">
|
||
C23
|
||
<specimenCode id="DBC89E87CE7A7B65FF43FA8CFF1DFAB4" box="[165,183,1294,1321]" collectionCode="H" country="Finland" lsid="urn:lsid:biocol.org:col:15618" name="University of Helsinki" pageId="6" pageNumber="41" type="Herbarium">H40</specimenCode>
|
||
O 13
|
||
</td>
|
||
<td id="768F5DC2CE7A849CFF47FB83FF1DFBDC" box="[161,183,1043,1141]" gridcol="5" gridrow="2" pageId="6" pageNumber="41" textDirection="bu">
|
||
[M-H-CO]
|
||
<emphasis id="B91AEAEECE7A7B65FF47FB83FF06FBB4" box="[161,172,1043,1053]" italics="true" pageId="6" pageNumber="41">–</emphasis>
|
||
2
|
||
</td>
|
||
<td id="768F5DC2CE7A849CFF47FC2AFF1DFC58" box="[161,183,954,1009]" gridcol="6" gridrow="2" pageId="6" pageNumber="41" textDirection="bu">479.25</td>
|
||
<td id="768F5DC2CE7A849CFF47FC1FFF1DFC0A" box="[161,183,911,931]" gridcol="7" gridrow="2" pageId="6" pageNumber="41" textDirection="bu">
|
||
<emphasis id="B91AEAEECE7A7B65FF43FC06FF1FFC0A" box="[165,181,918,931]" italics="true" pageId="6" pageNumber="41">–</emphasis>
|
||
<superScript id="7C1B9BB4CE7A7B65FF47FC1FFF06FC3F" attach="right" box="[161,172,911,918]" fontSize="4" pageId="6" pageNumber="41">a</superScript>
|
||
</td>
|
||
<td id="768F5DC2CE7A849CFF47FF58FF1DFD42" box="[161,183,200,747]" gridcol="8" gridrow="2" pageId="6" pageNumber="41" textDirection="bu">
|
||
<emphasis id="B91AEAEECE7A7B65FF43FD5CFF1FFD42" bold="true" box="[165,181,716,747]" pageId="6" pageNumber="41">479</emphasis>
|
||
, 437, 291, 161
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE7A849CFF5EFF58FF67F816" box="[184,205,200,1983]" gridrow="3" pageId="6" pageNumber="41" textDirection="bu">
|
||
<th id="768F5DC2CE7A849CFF5EF831FF67F816" box="[184,205,1953,1983]" gridcol="0" gridrow="3" pageId="6" pageNumber="41" textDirection="bu">98</th>
|
||
<td id="768F5DC2CE7A849CFF5EF93DFF67F822" box="[184,205,1709,1931]" gridcol="1" gridrow="3" pageId="6" pageNumber="41" textDirection="bu">
|
||
C 18 H 19 N
|
||
<subScript id="17EA34B9CE7A7B65FF24F8D1FF67F89D" attach="left" fontSize="4" pageId="6" pageNumber="41">
|
||
<superScript id="7C1B9BB4CE7A7B65FF24F8D1FF67F89D" attach="left" fontSize="4" pageId="6" pageNumber="41">5 O 7</superScript>
|
||
</subScript>
|
||
Sulfate
|
||
</td>
|
||
<td id="768F5DC2CE7A849CFF5EFA2FFF67FA60" box="[184,205,1471,1481]" gridcol="2" gridrow="3" pageId="6" pageNumber="41" textDirection="bu">I</td>
|
||
<td id="768F5DC2CE7A849CFF5EFAE7FF67FA34" box="[184,205,1399,1437]" gridcol="3" gridrow="3" pageId="6" pageNumber="41" textDirection="bu">234</td>
|
||
<td id="768F5DC2CE7A849CFF5EFB45FF67FAEB" box="[184,205,1237,1346]" gridcol="4" gridrow="3" pageId="6" pageNumber="41" textDirection="bu">
|
||
C18
|
||
<collectionCode id="ED7FAE39CE7A7B65FF5DFA8CFF61FA80" box="[187,203,1308,1321]" country="Finland" lsid="urn:lsid:biocol.org:col:15618" name="University of Helsinki" pageId="6" pageNumber="41" type="Herbarium">H</collectionCode>
|
||
19 N 5 O 10 S
|
||
</td>
|
||
<td id="768F5DC2CE7A849CFF5EFB83FF67FBDC" box="[184,205,1043,1141]" gridcol="5" gridrow="3" pageId="6" pageNumber="41" textDirection="bu">
|
||
<superScript id="7C1B9BB4CE7A7B65FF5DFBE0FF69FB94" attach="none" fontSize="4" pageId="6" pageNumber="41">
|
||
[M
|
||
<emphasis id="B91AEAEECE7A7B65FF5AFBC0FF66FBF4" box="[188,204,1104,1117]" italics="true" pageId="6" pageNumber="41">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE7A7B65FF5EFBA3FF69FB94" box="[184,195,1075,1085]" italics="true" pageId="6" pageNumber="41">
|
||
<subScript id="17EA34B9CE7A7B65FF5EFBA3FF69FB94" attach="right" box="[184,195,1075,1085]" fontSize="4" pageId="6" pageNumber="41">–</subScript>
|
||
</emphasis>
|
||
</superScript>
|
||
</td>
|
||
<td id="768F5DC2CE7A849CFF5EFC2AFF67FC58" box="[184,205,954,1009]" gridcol="6" gridrow="3" pageId="6" pageNumber="41" textDirection="bu">496.08</td>
|
||
<td id="768F5DC2CE7A849CFF5EFC1FFF67FC0A" box="[184,205,911,931]" gridcol="7" gridrow="3" pageId="6" pageNumber="41" textDirection="bu">6</td>
|
||
<td id="768F5DC2CE7A849CFF5EFF58FF67FD42" box="[184,205,200,747]" gridcol="8" gridrow="3" pageId="6" pageNumber="41" textDirection="bu">496, 374, 345, 294, 223, 150, 121, 97</td>
|
||
</tr>
|
||
<tr id="355E34BECE7A849CFF29FF58FF4EF816" box="[207,228,200,1983]" gridrow="4" pageId="6" pageNumber="41" textDirection="bu">
|
||
<th id="768F5DC2CE7A849CFF29F831FF4EF816" box="[207,228,1953,1983]" gridcol="0" gridrow="4" pageId="6" pageNumber="41" textDirection="bu">99</th>
|
||
<td id="768F5DC2CE7A849CFF29F93DFF4EF822" box="[207,228,1709,1931]" gridcol="1" gridrow="4" pageId="6" pageNumber="41" textDirection="bu">Unknown secondary amine</td>
|
||
<td id="768F5DC2CE7A849CFF29FA2FFF4EFA60" box="[207,228,1471,1481]" gridcol="2" gridrow="4" pageId="6" pageNumber="41" textDirection="bu">I</td>
|
||
<td id="768F5DC2CE7A849CFF29FAE7FF4EFA34" box="[207,228,1399,1437]" gridcol="3" gridrow="4" pageId="6" pageNumber="41" textDirection="bu">63</td>
|
||
<td id="768F5DC2CE7A849CFF29FB45FF4EFAEB" box="[207,228,1237,1346]" gridcol="4" gridrow="4" pageId="6" pageNumber="41" textDirection="bu">
|
||
C 6
|
||
<specimenCode id="DBC89E87CE7A7B65FF34FAB4FF4EFA8D" box="[210,228,1301,1329]" collectionCode="H" country="Finland" lsid="urn:lsid:biocol.org:col:15618" name="University of Helsinki" pageId="6" pageNumber="41" type="Herbarium">H 13</specimenCode>
|
||
<collectionCode id="ED7FAE39CE7A7B65FF34FA98FF48FABC" box="[210,226,1288,1301]" country="China" lsid="urn:lsid:biocol.org:col:13092" name="Nanjing University" pageId="6" pageNumber="41" type="Herbarium">N</collectionCode>
|
||
</td>
|
||
<td id="768F5DC2CE7A849CFF29FB83FF4EFBDC" box="[207,228,1043,1141]" gridcol="5" gridrow="4" pageId="6" pageNumber="41" textDirection="bu">
|
||
[M + Na]
|
||
<subScript id="17EA34B9CE7A7B65FF29FBA0FF70FB9E" attach="right" box="[207,218,1072,1079]" fontSize="4" pageId="6" pageNumber="41">
|
||
<superScript id="7C1B9BB4CE7A7B65FF29FBA0FF70FB9E" attach="right" box="[207,218,1072,1079]" fontSize="4" pageId="6" pageNumber="41">+</superScript>
|
||
</subScript>
|
||
</td>
|
||
<td id="768F5DC2CE7A849CFF29FC2AFF4EFC58" box="[207,228,954,1009]" gridcol="6" gridrow="4" pageId="6" pageNumber="41" textDirection="bu">122.09</td>
|
||
<td id="768F5DC2CE7A849CFF29FC1FFF4EFC0A" box="[207,228,911,931]" gridcol="7" gridrow="4" pageId="6" pageNumber="41" textDirection="bu">1</td>
|
||
<td id="768F5DC2CE7A849CFF29FF58FF4EFD42" box="[207,228,200,747]" gridcol="8" gridrow="4" pageId="6" pageNumber="41" textDirection="bu">
|
||
<emphasis id="B91AEAEECE7A7B65FF34FD5CFF48FD42" bold="true" box="[210,226,716,747]" pageId="6" pageNumber="41">100</emphasis>
|
||
([M +H]
|
||
<subScript id="17EA34B9CE7A7B65FF29FD15FF70FD25" attach="right" box="[207,218,645,652]" fontSize="4" pageId="6" pageNumber="41">+</subScript>
|
||
), 83, 55
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE7A849CFF00FF58FF51F816" box="[230,251,200,1983]" gridrow="5" pageId="6" pageNumber="41" textDirection="bu">
|
||
<th id="768F5DC2CE7A849CFF00F831FF51F816" box="[230,251,1953,1983]" gridcol="0" gridrow="5" pageId="6" pageNumber="41" textDirection="bu">100</th>
|
||
<td id="768F5DC2CE7A849CFF00F93DFF51F822" box="[230,251,1709,1931]" gridcol="1" gridrow="5" pageId="6" pageNumber="41" textDirection="bu">Unknown</td>
|
||
<td id="768F5DC2CE7A849CFF00FA2FFF51FA60" box="[230,251,1471,1481]" gridcol="2" gridrow="5" pageId="6" pageNumber="41" textDirection="bu">–</td>
|
||
<td id="768F5DC2CE7A849CFF00FAE7FF51FA34" box="[230,251,1399,1437]" gridcol="3" gridrow="5" pageId="6" pageNumber="41" textDirection="bu">234</td>
|
||
<td id="768F5DC2CE7A849CFF00FB45FF51FAEB" box="[230,251,1237,1346]" gridcol="4" gridrow="5" pageId="6" pageNumber="41" textDirection="bu">
|
||
C20
|
||
<collectionCode id="ED7FAE39CE7A7B65FF0FFA8DFF53FA83" box="[233,249,1309,1322]" country="Finland" lsid="urn:lsid:biocol.org:col:15618" name="University of Helsinki" pageId="6" pageNumber="41" type="Herbarium">H</collectionCode>
|
||
28 O 11
|
||
</td>
|
||
<td id="768F5DC2CE7A849CFF00FB83FF51FBDC" box="[230,251,1043,1141]" gridcol="5" gridrow="5" pageId="6" pageNumber="41" textDirection="bu">
|
||
[M
|
||
<emphasis id="B91AEAEECE7A7B65FF0FFBC0FF53FBF4" box="[233,249,1104,1117]" italics="true" pageId="6" pageNumber="41">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE7A7B65FF00FBA3FF5BFB94" box="[230,241,1075,1085]" italics="true" pageId="6" pageNumber="41">
|
||
<subScript id="17EA34B9CE7A7B65FF00FBA3FF5BFB94" attach="right" box="[230,241,1075,1085]" fontSize="4" pageId="6" pageNumber="41">
|
||
<superScript id="7C1B9BB4CE7A7B65FF00FBA3FF5BFB94" attach="right" box="[230,241,1075,1085]" fontSize="4" pageId="6" pageNumber="41">–</superScript>
|
||
</subScript>
|
||
</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE7A849CFF00FC2AFF51FC58" box="[230,251,954,1009]" gridcol="6" gridrow="5" pageId="6" pageNumber="41" textDirection="bu">443.15</td>
|
||
<td id="768F5DC2CE7A849CFF00FC1FFF51FC0A" box="[230,251,911,931]" gridcol="7" gridrow="5" pageId="6" pageNumber="41" textDirection="bu">6</td>
|
||
<td id="768F5DC2CE7A849CFF00FF58FF51FD42" box="[230,251,200,747]" gridcol="8" gridrow="5" pageId="6" pageNumber="41" textDirection="bu">
|
||
<emphasis id="B91AEAEECE7A7B65FF0FFD5CFF53FD42" bold="true" box="[233,249,716,747]" pageId="6" pageNumber="41">443</emphasis>
|
||
, 291, 151, 145, 125, 107, 101
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE7A849CFF1BFF58FEB8F816" box="[253,274,200,1983]" gridrow="6" pageId="6" pageNumber="41" textDirection="bu">
|
||
<th id="768F5DC2CE7A849CFF1BF831FEB8F816" box="[253,274,1953,1983]" gridcol="0" gridrow="6" pageId="6" pageNumber="41" textDirection="bu">101</th>
|
||
<td id="768F5DC2CE7A849CFF1BF93DFEB8F822" box="[253,274,1709,1931]" gridcol="1" gridrow="6" pageId="6" pageNumber="41" textDirection="bu">Unknown</td>
|
||
<td id="768F5DC2CE7A849CFF1BFA2FFEB8FA60" box="[253,274,1471,1481]" gridcol="2" gridrow="6" pageId="6" pageNumber="41" textDirection="bu">–</td>
|
||
<td id="768F5DC2CE7A849CFF1BFAE7FEB8FA34" box="[253,274,1399,1437]" gridcol="3" gridrow="6" pageId="6" pageNumber="41" textDirection="bu">182</td>
|
||
<td id="768F5DC2CE7A849CFF1BFB45FEB8FAEB" box="[253,274,1237,1346]" gridcol="4" gridrow="6" pageId="6" pageNumber="41" textDirection="bu">
|
||
C21 H28
|
||
<collectionCode id="ED7FAE39CE7A7B65FEE6FA91FEBAFAA7" box="[256,272,1281,1294]" country="Norway" lsid="urn:lsid:biocol.org:col:13093" name="Botanical Museum - University of Oslo" pageId="6" pageNumber="41" type="Herbarium">O</collectionCode>
|
||
12
|
||
</td>
|
||
<td id="768F5DC2CE7A849CFF1BFB83FEB8FBDC" box="[253,274,1043,1141]" gridcol="5" gridrow="6" pageId="6" pageNumber="41" textDirection="bu">
|
||
[M
|
||
<emphasis id="B91AEAEECE7A7B65FEE6FBC0FEBAFBF4" box="[256,272,1104,1117]" italics="true" pageId="6" pageNumber="41">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE7A7B65FF1BFBA3FEA2FB94" box="[253,264,1075,1085]" italics="true" pageId="6" pageNumber="41">
|
||
<subScript id="17EA34B9CE7A7B65FF1BFBA3FEA2FB94" attach="right" box="[253,264,1075,1085]" fontSize="4" pageId="6" pageNumber="41">
|
||
<superScript id="7C1B9BB4CE7A7B65FF1BFBA3FEA2FB94" attach="right" box="[253,264,1075,1085]" fontSize="4" pageId="6" pageNumber="41">–</superScript>
|
||
</subScript>
|
||
</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE7A849CFF1BFC2AFEB8FC58" box="[253,274,954,1009]" gridcol="6" gridrow="6" pageId="6" pageNumber="41" textDirection="bu">471.15</td>
|
||
<td id="768F5DC2CE7A849CFF1BFC1FFEB8FC0A" box="[253,274,911,931]" gridcol="7" gridrow="6" pageId="6" pageNumber="41" textDirection="bu">6</td>
|
||
<td id="768F5DC2CE7A849CFF1BFF58FEB8FD42" box="[253,274,200,747]" gridcol="8" gridrow="6" pageId="6" pageNumber="41" textDirection="bu">
|
||
<emphasis id="B91AEAEECE7A7B65FEE6FD5CFEBAFD42" bold="true" box="[256,272,716,747]" pageId="6" pageNumber="41">471</emphasis>
|
||
, 291, 179, 163, 145, 143, 125, 123, 119, 113, 107, 101
|
||
</td>
|
||
</tr>
|
||
<tr id="355E34BECE7A849CFEF5FF58FE83F816" box="[275,297,200,1983]" gridrow="7" pageId="6" pageNumber="41" textDirection="bu">
|
||
<th id="768F5DC2CE7A849CFEF5F831FE83F816" box="[275,297,1953,1983]" gridcol="0" gridrow="7" pageId="6" pageNumber="41" textDirection="bu">102</th>
|
||
<td id="768F5DC2CE7A849CFEF5F93DFE83F822" box="[275,297,1709,1931]" gridcol="1" gridrow="7" pageId="6" pageNumber="41" textDirection="bu">Unknown</td>
|
||
<td id="768F5DC2CE7A849CFEF5FA2FFE83FA60" box="[275,297,1471,1481]" gridcol="2" gridrow="7" pageId="6" pageNumber="41" textDirection="bu">–</td>
|
||
<td id="768F5DC2CE7A849CFEF5FAE7FE83FA34" box="[275,297,1399,1437]" gridcol="3" gridrow="7" pageId="6" pageNumber="41" textDirection="bu">260</td>
|
||
<td id="768F5DC2CE7A849CFEF5FB45FE83FAEB" box="[275,297,1237,1346]" gridcol="4" gridrow="7" pageId="6" pageNumber="41" textDirection="bu">
|
||
C11
|
||
<materialsCitation id="3B063CA1CE7A7B65FEF1FA8CFE83FAB4" box="[279,297,1294,1321]" collectionCode="H" longitude="-11.166667" pageId="6" pageNumber="41" specimenCount="1">
|
||
<collectionCode id="ED7FAE39CE7A7B65FEF1FA8CFE8DFA80" box="[279,295,1308,1321]" country="Finland" lsid="urn:lsid:biocol.org:col:15618" name="University of Helsinki" pageId="6" pageNumber="41" type="Herbarium">H</collectionCode>
|
||
10
|
||
</materialsCitation>
|
||
O 6
|
||
</td>
|
||
<td id="768F5DC2CE7A849CFEF5FB83FE83FBDC" box="[275,297,1043,1141]" gridcol="5" gridrow="7" pageId="6" pageNumber="41" textDirection="bu">
|
||
[M
|
||
<emphasis id="B91AEAEECE7A7B65FEF1FBC0FE8DFBF4" box="[279,295,1104,1117]" italics="true" pageId="6" pageNumber="41">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE7A7B65FEF5FBA3FEB4FB94" box="[275,286,1075,1085]" italics="true" pageId="6" pageNumber="41">
|
||
<subScript id="17EA34B9CE7A7B65FEF5FBA3FEB4FB94" attach="right" box="[275,286,1075,1085]" fontSize="4" pageId="6" pageNumber="41">
|
||
<superScript id="7C1B9BB4CE7A7B65FEF5FBA3FEB4FB94" attach="right" box="[275,286,1075,1085]" fontSize="4" pageId="6" pageNumber="41">–</superScript>
|
||
</subScript>
|
||
</emphasis>
|
||
</td>
|
||
<td id="768F5DC2CE7A849CFEF5FC2AFE83FC58" box="[275,297,954,1009]" gridcol="6" gridrow="7" pageId="6" pageNumber="41" textDirection="bu">237.04</td>
|
||
<td id="768F5DC2CE7A849CFEF5FC1FFE83FC0A" box="[275,297,911,931]" gridcol="7" gridrow="7" pageId="6" pageNumber="41" textDirection="bu">3</td>
|
||
<td id="768F5DC2CE7A849CFEF5FF58FE83FD42" box="[275,297,200,747]" gridcol="8" gridrow="7" pageId="6" pageNumber="41" textDirection="bu">237, 222, 193, 178, 149, 134</td>
|
||
</tr>
|
||
<tr id="355E34BECE7A849CFECCFF58FEEAF816" box="[298,320,200,1983]" gridrow="8" pageId="6" pageNumber="41" textDirection="bu">
|
||
<th id="768F5DC2CE7A849CFECCF831FEEAF816" box="[298,320,1953,1983]" gridcol="0" gridrow="8" pageId="6" pageNumber="41" textDirection="bu">103</th>
|
||
<td id="768F5DC2CE7A849CFECCF93DFEEAF822" box="[298,320,1709,1931]" gridcol="1" gridrow="8" pageId="6" pageNumber="41" textDirection="bu">Unknown</td>
|
||
<td id="768F5DC2CE7A849CFECCFA2FFEEAFA60" box="[298,320,1471,1481]" gridcol="2" gridrow="8" pageId="6" pageNumber="41" textDirection="bu">–</td>
|
||
<td id="768F5DC2CE7A849CFECCFAE7FEEAFA34" box="[298,320,1399,1437]" gridcol="3" gridrow="8" pageId="6" pageNumber="41" textDirection="bu">573</td>
|
||
<td id="768F5DC2CE7A849CFECCFB45FEEAFAEB" box="[298,320,1237,1346]" gridcol="4" gridrow="8" pageId="6" pageNumber="41" textDirection="bu">
|
||
<uuid id="FFC80C29CE7A7B65FEC8FAA8FE94FAEB" box="[302,318,1336,1346]" pageId="6" pageNumber="41">C</uuid>
|
||
28 H44
|
||
<collectionCode id="ED7FAE39CE7A7B65FEC8FA91FE94FAA7" box="[302,318,1281,1294]" country="Norway" lsid="urn:lsid:biocol.org:col:13093" name="Botanical Museum - University of Oslo" pageId="6" pageNumber="41" type="Herbarium">O</collectionCode>
|
||
4
|
||
</td>
|
||
<td id="768F5DC2CE7A849CFECCFB83FEEAFBDC" box="[298,320,1043,1141]" gridcol="5" gridrow="8" pageId="6" pageNumber="41" textDirection="bu">
|
||
[M + H]
|
||
<subScript id="17EA34B9CE7A7B65FECCFBA9FE9FFBE9" attach="right" box="[298,309,1081,1088]" fontSize="4" pageId="6" pageNumber="41">
|
||
<superScript id="7C1B9BB4CE7A7B65FECCFBA9FE9FFBE9" attach="right" box="[298,309,1081,1088]" fontSize="4" pageId="6" pageNumber="41">+</superScript>
|
||
</subScript>
|
||
</td>
|
||
<td id="768F5DC2CE7A849CFECCFC2AFEEAFC58" box="[298,320,954,1009]" gridcol="6" gridrow="8" pageId="6" pageNumber="41" textDirection="bu">445.33</td>
|
||
<td id="768F5DC2CE7A849CFECCFC1FFEEAFC0A" box="[298,320,911,931]" gridcol="7" gridrow="8" pageId="6" pageNumber="41" textDirection="bu">3</td>
|
||
<td id="768F5DC2CE7A849CFECCFF58FEEAFD42" box="[298,320,200,747]" gridcol="8" gridrow="8" pageId="6" pageNumber="41" textDirection="bu">
|
||
<emphasis id="B91AEAEECE7A7B65FEC8FD5CFE94FD42" bold="true" box="[302,318,716,747]" pageId="6" pageNumber="41">445</emphasis>
|
||
, 427, 409, 391, 353, 339, 325, 313, 311, 285, 283, 271, 269, 215
|
||
</td>
|
||
</tr>
|
||
</table>
|
||
</paragraph>
|
||
<tableNote id="76883772CE7A7B65FEB2F821FE7DF92A" pageId="6" pageNumber="41" targetBox="[115,320,200,1983]" targetPageId="6">
|
||
<paragraph id="8BD136FCCE7A7B65FEB2F821FECEF9D4" blockId="6.[340,471,180,2007]" box="[340,356,1658,2006]" pageId="6" pageNumber="41">Pent, pentoside; Hex, hexoside; DeoxyHex,</paragraph>
|
||
<paragraph id="8BD136FCCE7A7B65FEB2FA69FECEFA50" blockId="6.[340,471,180,2007]" box="[340,356,1526,1652]" pageId="6" pageNumber="41">deoxyhexoside;</paragraph>
|
||
<paragraph id="8BD136FCCE7A7B65FEB2FA50FECEFB70" blockId="6.[340,471,180,2007]" box="[340,356,1169,1521]" pageId="6" pageNumber="41">DHBA, dihydroxybenzoic acid; JA, jasmonic</paragraph>
|
||
<paragraph id="8BD136FCCE7A7B65FEB2FBF8FECEFC05" blockId="6.[340,471,180,2007]" box="[340,356,937,1164]" pageId="6" pageNumber="41">acid; G, coniferyl alcohol; S,</paragraph>
|
||
<paragraph id="8BD136FCCE7A7B65FEB2FCFAFECEFC8E" blockId="6.[340,471,180,2007]" box="[340,356,804,932]" pageId="6" pageNumber="41">sinapyl alcohol;</paragraph>
|
||
<paragraph id="8BD136FCCE7A7B65FEB2FC98FECEFCB7" blockId="6.[340,471,180,2007]" box="[340,356,776,798]" pageId="6" pageNumber="41">FA</paragraph>
|
||
<paragraph id="8BD136FCCE7A7B65FEB2FC95FECEFCAE" blockId="6.[340,471,180,2007]" box="[340,356,773,775]" pageId="6" pageNumber="41">,</paragraph>
|
||
<paragraph id="8BD136FCCE7A7B65FEB2FD5CFED9F86E" blockId="6.[340,471,180,2007]" box="[340,371,402,1991]" pageId="6" pageNumber="41">
|
||
ferulic acid; lysoPC, lysophosphatidylcholine.
|
||
<subScript id="17EA34B9CE7A7B65FE8EF850FED9F86E" attach="right" box="[360,371,1984,1991]" fontSize="4" pageId="6" pageNumber="41">1</subScript>
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE7A7B65FE8DF8CBFE03FCCC" blockId="6.[340,471,180,2007]" pageId="6" pageNumber="41">
|
||
verification level: S, chromatographic and mass spectral behavior as observed for an authenticated standard; I, putative structure deduced from interpretation of elemental composition, collision-induced dissociation mass spectra and online H / D exchange experiments; L, compound reported for A.
|
||
<taxonomicName id="4C6E4D7FCE7A7B65FE64FABAFE38FAC0" box="[386,402,1322,1385]" class="Magnoliopsida" family="Brassicaceae" genus="Arabidopsis" kingdom="Plantae" order="Brassicales" pageId="6" pageNumber="41" phylum="Tracheophyta" rank="species" species="thaliana">thaliana</taxonomicName>
|
||
in the literature, for references see Supplementary Table 2.
|
||
<subScript id="17EA34B9CE7A7B65FE70F850FE0BF86E" attach="right" box="[406,417,1984,1991]" fontSize="4" pageId="6" pageNumber="41">2</subScript>
|
||
number of exchangeable protons as determined by on-line H/ D exchange: a number of exchangeable protons could not be unambigously determined
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE7A7B65FE7FFD75FE03FEF3" blockId="6.[340,471,180,2007]" pageId="6" pageNumber="41">
|
||
due to low intensity,
|
||
<superScript id="7C1B9BB4CE7A7B65FE70FDC0FE0BFDFE" attach="right" box="[406,417,592,599]" fontSize="4" pageId="6" pageNumber="41">
|
||
<subScript id="17EA34B9CE7A7B65FE70FDC0FE0BFDFE" attach="right" box="[406,417,592,599]" fontSize="4" pageId="6" pageNumber="41">b</subScript>
|
||
</superScript>
|
||
compound does not form any quasi-molecular
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE7A7B65FE7FFF27FE6AF9EC" blockId="6.[340,471,180,2007]" box="[409,448,180,2007]" pageId="6" pageNumber="41">ion, number of exchangeable protons determined for the</paragraph>
|
||
<paragraph id="8BD136FCCE7A7B65FE56F9B1FE6AFB64" blockId="6.[340,471,180,2007]" pageId="6" pageNumber="41">
|
||
[M + H-NH]
|
||
<superScript id="7C1B9BB4CE7A7B65FE4AFA52FE1DFA60" attach="right" box="[428,439,1474,1481]" fontSize="4" pageId="6" pageNumber="41">+</superScript>
|
||
ion. For detailed information see
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE7A7B65FE56FBA2FE6AFB04" blockId="6.[340,471,180,2007]" box="[432,448,1074,1197]" pageId="6" pageNumber="41">Supplementary</paragraph>
|
||
<paragraph id="8BD136FCCE7A7B65FE56FB91FE68FA7F" blockId="6.[340,471,180,2007]" box="[432,450,1005,1494]" pageId="6" pageNumber="41">
|
||
Table 3.
|
||
<subScript id="17EA34B9CE7A7B65FE51FA5FFE68FA7F" attach="left" box="[439,450,1487,1494]" fontSize="4" pageId="6" pageNumber="41">3</subScript>
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE7A7B65FE25F850FE7DF92A" blockId="6.[340,471,180,2007]" box="[451,471,1663,1991]" pageId="6" pageNumber="41">
|
||
<subScript id="17EA34B9CE7A7B65FE25F850FE64F86E" attach="right" box="[451,462,1984,1991]" fontSize="4" pageId="6" pageNumber="41">3</subScript>
|
||
for details see Supplementary Table 4.
|
||
</paragraph>
|
||
</tableNote>
|
||
<caption id="DF116674CE7B7B64FFB1F97AFEBDF8A6" ID-DOI="http://doi.org/10.5281/zenodo.10490940" ID-Zenodo-Dep="10490940" httpUri="https://zenodo.org/record/10490940/files/figure.png" pageId="7" pageNumber="42" startId="7.[87,113,1770,1784]" targetBox="[178,1378,184,1738]" targetPageId="7" targetType="figure">
|
||
<paragraph id="8BD136FCCE7B7B64FFB1F97AFEBDF8A6" blockId="7.[87,1474,1769,1807]" pageId="7" pageNumber="42">
|
||
<emphasis id="B91AEAEECE7B7B64FFB1F97AFF21F951" bold="true" box="[87,139,1770,1784]" pageId="7" pageNumber="42">Fig. 3.</emphasis>
|
||
Molecular structures of identified and putatively annotated compounds detected in root exudates of
|
||
<taxonomicName id="4C6E4D7FCE7B7B64FC3DF979FBD3F951" box="[987,1145,1769,1784]" class="Magnoliopsida" family="Brassicaceae" genus="Arabidopsis" kingdom="Plantae" order="Brassicales" pageId="7" pageNumber="42" phylum="Tracheophyta" rank="species" species="thaliana">
|
||
<emphasis id="B91AEAEECE7B7B64FC3DF979FBD3F951" box="[987,1145,1769,1784]" italics="true" pageId="7" pageNumber="42">Arabidopsis thaliana</emphasis>
|
||
</taxonomicName>
|
||
. For annotation levels see Table 1. Hex Hexosyl; Pent Pentosyl.
|
||
</paragraph>
|
||
</caption>
|
||
<paragraph id="8BD136FCCE7B7B6BFCC3F8D8FE15FDF9" blockId="7.[805,1475,1864,1996]" lastBlockId="8.[113,783,182,1205]" lastPageId="8" lastPageNumber="43" pageId="7" pageNumber="42">
|
||
<emphasis id="B91AEAEECE7B7B64FCC3F8D8FAF6F8F5" box="[805,1372,1864,1884]" italics="true" pageId="7" pageNumber="42">2.4.5.3. Hydroxycinnamic acid conjugates and flavonoids.</emphasis>
|
||
Although phenolic acids represent well-known constituents of root exudates (
|
||
<bibRefCitation id="EFFF4B0DCE7B7B64FCCBF811FC59F83D" author="Lanoue, A. & Burlat, V. & Henkes, G. J. & Koch, I. & Schurr, U. & Rose, U. S." box="[813,1011,1921,1940]" pageId="7" pageNumber="42" pagination="577 - 588" refId="ref12134" refString="Lanoue, A., Burlat, V., Henkes, G. J., Koch, I., Schurr, U., Rose, U. S., 2010. De novo biosynthesis of defense root exudates in response to Fusarium attack in barley. New Phytol. 185, 577 - 588." type="journal article" year="2010">Lanoue et al., 2010</bibRefCitation>
|
||
), free hydroxycinnamic and hydroxybenzoic acids could not be detected in root exudates of
|
||
<taxonomicName id="4C6E4D7FCE7B7B64FAFFF80CFA29F819" box="[1305,1411,1948,1968]" class="Magnoliopsida" family="Brassicaceae" genus="Arabidopsis" kingdom="Plantae" order="Brassicales" pageId="7" pageNumber="42" phylum="Tracheophyta" rank="species" species="thaliana">
|
||
<emphasis id="B91AEAEECE7B7B64FAFFF80CFA29F819" box="[1305,1411,1948,1968]" italics="true" pageId="7" pageNumber="42">A. thaliana</emphasis>
|
||
</taxonomicName>
|
||
using the established experimental system. Due to the low process efficiencies found for cinnamic and salicylic acid (vide supra), it remains unclear, whether
|
||
<taxonomicName id="4C6E4D7FCE747B6BFE9CFF41FE7CFF4C" authorityName="Schur" authorityYear="1866" box="[378,470,209,229]" class="Magnoliopsida" family="Brassicaceae" genus="Arabidopsis" kingdom="Plantae" order="Brassicales" pageId="8" pageNumber="43" phylum="Tracheophyta" rank="species" species="thalina">
|
||
<emphasis id="B91AEAEECE747B6BFE9CFF41FE7CFF4C" box="[378,470,209,229]" italics="true" pageId="8" pageNumber="43">A. thalina</emphasis>
|
||
</taxonomicName>
|
||
roots do not exude these compounds under sterile conditions or their detection is hampered by the sample preparation protocol. However, three monolignol-ferulic acid conjugates (
|
||
<emphasis id="B91AEAEECE747B6BFEDBFEB6FEFCFE90" bold="true" box="[317,342,294,313]" pageId="8" pageNumber="43">77</emphasis>
|
||
,
|
||
<emphasis id="B91AEAEECE747B6BFE84FEB6FED1FE90" bold="true" box="[354,379,294,313]" pageId="8" pageNumber="43">78</emphasis>
|
||
,
|
||
<emphasis id="B91AEAEECE747B6BFE6EFEB6FE0BFE90" bold="true" box="[392,417,294,313]" pageId="8" pageNumber="43">79</emphasis>
|
||
) and a ferulic acid dimer (
|
||
<emphasis id="B91AEAEECE747B6BFD52FEB6FD67FE90" bold="true" box="[692,717,294,313]" pageId="8" pageNumber="43">80</emphasis>
|
||
) were identified. Interestingly, two of them (
|
||
<emphasis id="B91AEAEECE747B6BFE09FED2FDA2FEFC" bold="true" box="[495,520,322,341]" pageId="8" pageNumber="43">77</emphasis>
|
||
,
|
||
<emphasis id="B91AEAEECE747B6BFDF5FED2FD86FEFC" bold="true" box="[531,556,322,341]" pageId="8" pageNumber="43">79</emphasis>
|
||
) were detected as sulfate conjugates as indicated by a neutral loss of 79.96 Da from the [M
|
||
<emphasis id="B91AEAEECE747B6BFF68FEE8FF35FE25" box="[142,159,376,396]" italics="true" pageId="8" pageNumber="43">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE747B6BFF51FEE5FF69FE2B" box="[183,195,373,386]" italics="true" pageId="8" pageNumber="43">
|
||
<superScript id="7C1B9BB4CE747B6BFF51FEE5FF69FE2B" attach="left" box="[183,195,373,386]" fontSize="5" pageId="8" pageNumber="43">–</superScript>
|
||
</emphasis>
|
||
ions. For the 8-
|
||
<emphasis id="B91AEAEECE747B6BFE86FEE8FEC5FE25" box="[352,367,376,396]" italics="true" pageId="8" pageNumber="43">O</emphasis>
|
||
-4 cross-coupled coniferyl alcohol–ferulic acid conjugate
|
||
<emphasis id="B91AEAEECE747B6BFEEFFE06FE88FE00" bold="true" box="[265,290,406,425]" pageId="8" pageNumber="43">77</emphasis>
|
||
a characteristic neutral loss of 48.02 Da from the [M
|
||
<emphasis id="B91AEAEECE747B6BFF68FE20FF35FE6D" box="[142,159,432,452]" italics="true" pageId="8" pageNumber="43">–</emphasis>
|
||
H-SO
|
||
<subScript id="17EA34B9CE747B6BFF35FE2AFF76FE6F" attach="left" box="[211,220,442,454]" fontSize="5" pageId="8" pageNumber="43">3</subScript>
|
||
]
|
||
<emphasis id="B91AEAEECE747B6BFF02FE3DFF5AFE13" box="[228,240,429,442]" italics="true" pageId="8" pageNumber="43">
|
||
<superScript id="7C1B9BB4CE747B6BFF02FE3DFF5AFE13" attach="left" box="[228,240,429,442]" fontSize="5" pageId="8" pageNumber="43">–</superScript>
|
||
</emphasis>
|
||
ion was registered together with A
|
||
<emphasis id="B91AEAEECE747B6BFDA8FE3DFDF0FE13" box="[590,602,429,442]" italics="true" pageId="8" pageNumber="43">
|
||
<superScript id="7C1B9BB4CE747B6BFDA8FE3DFDF0FE13" attach="left" box="[590,602,429,442]" fontSize="5" pageId="8" pageNumber="43">–</superScript>
|
||
</emphasis>
|
||
and B
|
||
<emphasis id="B91AEAEECE747B6BFD7EFE3DFD0EFE13" box="[664,676,429,442]" italics="true" pageId="8" pageNumber="43">
|
||
<superScript id="7C1B9BB4CE747B6BFD7EFE3DFD0EFE13" attach="left" box="[664,676,429,442]" fontSize="5" pageId="8" pageNumber="43">–</superScript>
|
||
</emphasis>
|
||
fragments at
|
||
<emphasis id="B91AEAEECE747B6BFF6BFE5CFF0AFE49" box="[141,160,460,480]" italics="true" pageId="8" pageNumber="43">m</emphasis>
|
||
/
|
||
<emphasis id="B91AEAEECE747B6BFF4EFE5CFF18FE49" box="[168,178,460,480]" italics="true" pageId="8" pageNumber="43">z</emphasis>
|
||
195.06 and
|
||
<emphasis id="B91AEAEECE747B6BFED3FE5CFEE2FE49" box="[309,328,460,480]" italics="true" pageId="8" pageNumber="43">m</emphasis>
|
||
/
|
||
<emphasis id="B91AEAEECE747B6BFEA9FE5CFEF3FE49" box="[335,345,460,480]" italics="true" pageId="8" pageNumber="43">z</emphasis>
|
||
193.05. As observed for phenylcoumaran-type dilignols, the CID mass spectra of the 8–5 cross-coupled coniferyl alcohol–ferulic acid conjugates
|
||
<emphasis id="B91AEAEECE747B6BFDF4FD95FD81FDB1" bold="true" box="[530,555,517,536]" pageId="8" pageNumber="43">78</emphasis>
|
||
and
|
||
<emphasis id="B91AEAEECE747B6BFD86FD95FDD3FDB1" bold="true" box="[608,633,517,536]" pageId="8" pageNumber="43">79</emphasis>
|
||
are characterized by neutral losses of water and formaldehyde from the [M
|
||
<emphasis id="B91AEAEECE747B6BFD3CFDB0FD41FD9D" box="[730,747,544,564]" italics="true" pageId="8" pageNumber="43">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE747B6BFCE5FD8CFCA5FD80" box="[771,783,540,553]" italics="true" pageId="8" pageNumber="43">
|
||
<superScript id="7C1B9BB4CE747B6BFCE5FD8CFCA5FD80" attach="none" box="[771,783,540,553]" fontSize="5" pageId="8" pageNumber="43">–</superScript>
|
||
</emphasis>
|
||
or [M
|
||
<emphasis id="B91AEAEECE747B6BFF4CFDACFF11FDF9" box="[170,187,572,592]" italics="true" pageId="8" pageNumber="43">–</emphasis>
|
||
H-SO
|
||
<subScript id="17EA34B9CE747B6BFF09FDD6FF52FDFB" attach="left" box="[239,248,582,594]" fontSize="5" pageId="8" pageNumber="43">3</subScript>
|
||
]
|
||
<emphasis id="B91AEAEECE747B6BFEE6FDA8FEA6FDEC" box="[256,268,568,581]" italics="true" pageId="8" pageNumber="43">
|
||
<superScript id="7C1B9BB4CE747B6BFEE6FDA8FEA6FDEC" attach="left" box="[256,268,568,581]" fontSize="5" pageId="8" pageNumber="43">–</superScript>
|
||
</emphasis>
|
||
ion, respectively.
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE747B6BFF77FDC9FF7AFB83" blockId="8.[113,783,182,1205]" pageId="8" pageNumber="43">
|
||
Another sulfate conjugate was compound
|
||
<emphasis id="B91AEAEECE747B6BFDDFFDC9FDF8FDC5" bold="true" box="[569,594,601,620]" pageId="8" pageNumber="43">81</emphasis>
|
||
. Calculation of the elemental composition of
|
||
<emphasis id="B91AEAEECE747B6BFE93FDE4FE24FD2E" bold="true" box="[373,398,628,647]" pageId="8" pageNumber="43">81</emphasis>
|
||
suggested the presence of three nitrogen atoms. The CID mass spectrum obtained from [M+H]
|
||
<superScript id="7C1B9BB4CE747B6BFD21FD1DFD7AFD30" attach="left" box="[711,720,653,665]" fontSize="5" pageId="8" pageNumber="43">+</superScript>
|
||
of
|
||
<emphasis id="B91AEAEECE747B6BFD13FD00FCA4FD0A" bold="true" box="[757,782,656,675]" pageId="8" pageNumber="43">81</emphasis>
|
||
revealed neutral losses of 17.03 Da (NH
|
||
<subScript id="17EA34B9CE747B6BFDF9FD25FD82FD68" attach="left" box="[543,552,693,705]" fontSize="5" pageId="8" pageNumber="43">3</subScript>
|
||
), 74.08 Da (C
|
||
<subScript id="17EA34B9CE747B6BFD5BFD25FD6CFD68" attach="both" box="[701,710,693,705]" fontSize="5" pageId="8" pageNumber="43">3</subScript>
|
||
H
|
||
<subScript id="17EA34B9CE747B6BFD30FD25FD42FD68" attach="both" box="[726,744,693,705]" fontSize="5" pageId="8" pageNumber="43">10</subScript>
|
||
N
|
||
<subScript id="17EA34B9CE747B6BFD1FFD25FCA8FD68" attach="left" box="[761,770,693,705]" fontSize="5" pageId="8" pageNumber="43">2</subScript>
|
||
), 88.10 Da (C
|
||
<subScript id="17EA34B9CE747B6BFF0BFD41FF5CFD74" attach="both" box="[237,246,721,733]" fontSize="5" pageId="8" pageNumber="43">4</subScript>
|
||
H
|
||
<subScript id="17EA34B9CE747B6BFEE0FD41FEB3FD74" attach="both" box="[262,281,721,733]" fontSize="5" pageId="8" pageNumber="43">12</subScript>
|
||
N
|
||
<subScript id="17EA34B9CE747B6BFECFFD41FE98FD74" attach="left" box="[297,306,721,733]" fontSize="5" pageId="8" pageNumber="43">2</subScript>
|
||
) and 145.16 Da (C
|
||
<subScript id="17EA34B9CE747B6BFDE2FD42FDA7FD77" attach="both" box="[516,525,722,734]" fontSize="5" pageId="8" pageNumber="43">7</subScript>
|
||
H
|
||
<subScript id="17EA34B9CE747B6BFDF8FD41FD9BFD74" attach="both" box="[542,561,721,733]" fontSize="5" pageId="8" pageNumber="43">19</subScript>
|
||
N
|
||
<subScript id="17EA34B9CE747B6BFDA7FD41FDE0FD74" attach="left" box="[577,586,721,733]" fontSize="5" pageId="8" pageNumber="43">3</subScript>
|
||
) from the [M+H-SO
|
||
<subScript id="17EA34B9CE747B6BFF6AFD7DFF3FFD50" attach="left" box="[140,149,749,761]" fontSize="5" pageId="8" pageNumber="43">3</subScript>
|
||
]
|
||
<superScript id="7C1B9BB4CE747B6BFF78FD70FF0DFD45" attach="left" box="[158,167,736,748]" fontSize="5" pageId="8" pageNumber="43">+</superScript>
|
||
ion, the latter resulting in a fragment ion at
|
||
<emphasis id="B91AEAEECE747B6BFD8DFD73FDD4FD5E" box="[619,638,739,759]" italics="true" pageId="8" pageNumber="43">m</emphasis>
|
||
/
|
||
<emphasis id="B91AEAEECE747B6BFD63FD73FD25FD5E" box="[645,655,739,759]" italics="true" pageId="8" pageNumber="43">z</emphasis>
|
||
291.07 with the elemental composition of C
|
||
<subScript id="17EA34B9CE747B6BFE48FC99FE6AFCBC" attach="both" box="[430,448,777,789]" fontSize="5" pageId="8" pageNumber="43">18</subScript>
|
||
H
|
||
<subScript id="17EA34B9CE747B6BFE37FC99FE4EFCBC" attach="both" box="[465,484,777,789]" fontSize="5" pageId="8" pageNumber="43">11</subScript>
|
||
O
|
||
<subScript id="17EA34B9CE747B6BFE15FC99FE56FCBC" attach="left" box="[499,508,777,789]" fontSize="5" pageId="8" pageNumber="43">4</subScript>
|
||
<superScript id="7C1B9BB4CE747B6BFE15FD6CFE56FCA1" attach="left" box="[499,508,764,776]" fontSize="5" pageId="8" pageNumber="43">+</superScript>
|
||
. This suggests that
|
||
<emphasis id="B91AEAEECE747B6BFD23FC90FD74FCBA" bold="true" box="[709,734,768,787]" pageId="8" pageNumber="43">81</emphasis>
|
||
represents a sulfated cyclic didehydro-di(coumaroyl)spermidine conjugate. The
|
||
<taxonomicName id="4C6E4D7FCE747B6BFF11FCA8FEC7FCE2" box="[247,365,824,843]" class="Magnoliopsida" family="Brassicaceae" genus="Arabidopsis" kingdom="Plantae" order="Brassicales" pageId="8" pageNumber="43" phylum="Tracheophyta" rank="genus">Arabidopsis</taxonomicName>
|
||
genome contains a gene (
|
||
<emphasis id="B91AEAEECE747B6BFD79FCA7FCADFCE2" box="[671,775,823,843]" italics="true" pageId="8" pageNumber="43">
|
||
At
|
||
<quantity id="4C969B19CE747B6BFD52FCA7FD66FCE2" box="[692,716,823,843]" metricMagnitude="-3" metricUnit="kg" metricValue="2.0" pageId="8" pageNumber="43" unit="g" value="2.0">2g</quantity>
|
||
25150
|
||
</emphasis>
|
||
) encoding a functional coumaroyl-CoA:spermidine coumaroyltransferase (
|
||
<bibRefCitation id="EFFF4B0DCE747B6BFF5DFCE0FEFBFC2A" author="Luo, J. & Fuell, C. & Parr, A. & Hill, L. & Bailey, P. & Elliott, K. & Fairhurst, S. A. & Martin, C. & Michael, A. J." box="[187,337,880,899]" pageId="8" pageNumber="43" pagination="318 - 333" refId="ref12405" refString="Luo, J., Fuell, C., Parr, A., Hill, L., Bailey, P., Elliott, K., Fairhurst, S. A., Martin, C., Michael, A. J., 2009. A novel polyamine acyltransferase responsible for the accumulation of spermidine conjugates in Arabidopsis seed. Plant Cell 21, 318 - 333." type="journal article" year="2009">Luo et al., 2009</bibRefCitation>
|
||
). This gene was shown to exhibit a root specific expression pattern and its overexpression resulted in the accumulation of di(coumaroyl)spermidine and a related hexoside in roots (
|
||
<bibRefCitation id="EFFF4B0DCE747B6BFF28FC54FECDFC7F" author="Luo, J. & Fuell, C. & Parr, A. & Hill, L. & Bailey, P. & Elliott, K. & Fairhurst, S. A. & Martin, C. & Michael, A. J." box="[206,359,963,983]" pageId="8" pageNumber="43" pagination="318 - 333" refId="ref12405" refString="Luo, J., Fuell, C., Parr, A., Hill, L., Bailey, P., Elliott, K., Fairhurst, S. A., Martin, C., Michael, A. J., 2009. A novel polyamine acyltransferase responsible for the accumulation of spermidine conjugates in Arabidopsis seed. Plant Cell 21, 318 - 333." type="journal article" year="2009">Luo et al., 2009</bibRefCitation>
|
||
). Compound
|
||
<emphasis id="B91AEAEECE747B6BFE16FC53FDA3FC7F" bold="true" box="[496,521,963,982]" pageId="8" pageNumber="43">81</emphasis>
|
||
could represent a metabolite which might be synthesized from di(coumaroyl)spermidine by intramolecular oxidative phenol coupling and subsequent sulfation.
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE747B6BFF77FBA3FF78FB1C" blockId="8.[113,783,182,1205]" pageId="8" pageNumber="43">
|
||
Although flavonol glycosides are absent in dark-grown roots in
|
||
<taxonomicName id="4C6E4D7FCE747B6BFF97FBDEFF72FBCB" box="[113,216,1102,1122]" class="Magnoliopsida" family="Brassicaceae" genus="Arabidopsis" kingdom="Plantae" order="Brassicales" pageId="8" pageNumber="43" phylum="Tracheophyta" rank="species" species="thaliana">
|
||
<emphasis id="B91AEAEECE747B6BFF97FBDEFF72FBCB" box="[113,216,1102,1122]" italics="true" pageId="8" pageNumber="43">A. thaliana</emphasis>
|
||
</taxonomicName>
|
||
(
|
||
<bibRefCitation id="EFFF4B0DCE747B6BFF00FBDFFE10FBCB" author="Bednarek, P. & Schneider, B. & Svatos, A. & Oldham, N. J. & Hahlbrock, K." box="[230,442,1103,1122]" pageId="8" pageNumber="43" pagination="1058 - 1070" refId="ref10904" refString="Bednarek, P., Schneider, B., Svatos, A., Oldham, N. J., Hahlbrock, K., 2005. Structural complexity, differential response to infection, and tissue specificity of indolic and phenylpropanoid secondary metabolism in Arabidopsis roots. Plant Physiol. 138, 1058 - 1070." type="journal article" year="2005">Bednarek et al., 2005</bibRefCitation>
|
||
;
|
||
<bibRefCitation id="EFFF4B0DCE747B6BFE25FBDFFDD3FBCB" author="Hemm, M. R. & Rider, S. D. & Ogas, J. & Murry, D. J. & Chapple, C." box="[451,633,1103,1122]" pageId="8" pageNumber="43" pagination="765 - 778" refId="ref11735" refString="Hemm, M. R., Rider, S. D., Ogas, J., Murry, D. J., Chapple, C., 2004. Light induces phenylpropanoid metabolism in Arabidopsis roots. Plant J. 38, 765 - 778." type="journal article" year="2004">Hemm et al., 2004</bibRefCitation>
|
||
), a kaempferol triglycoside (
|
||
<emphasis id="B91AEAEECE747B6BFF11FBFBFEBAFBD7" bold="true" box="[247,272,1131,1150]" pageId="8" pageNumber="43">82</emphasis>
|
||
), which was found to be accumulating in rosette leaves (
|
||
<bibRefCitation id="EFFF4B0DCE747B6BFF24FB17FDB2FB33" author="Yonekura-Sakakibara, K. & Tohge, T. & Matsuda, F. & Nakabayashi, R. & Takayama, H. & Niida, R. & Watanabe-Takahashi, A. & Inoue, E. & Saito, K." box="[194,536,1159,1178]" pageId="8" pageNumber="43" pagination="2160 - 2176" refId="ref13878" refString="Yonekura-Sakakibara, K., Tohge, T., Matsuda, F., Nakabayashi, R., Takayama, H., Niida, R., Watanabe-Takahashi, A., Inoue, E., Saito, K., 2008. Comprehensive flavonol profiling and transcriptome coexpression analysis leading to decoding gene-metabolite correlations in Arabidopsis. Plant Cell 20, 2160 - 2176." type="journal article" year="2008">Yonekura-Sakakibara et al., 2008</bibRefCitation>
|
||
) was identified in root exudates.
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE747B6BFF94FB49FED1FB44" blockId="8.[113,783,1241,2015]" box="[114,379,1241,1261]" pageId="8" pageNumber="43">
|
||
<heading id="D0998190CE747B6BFF94FB49FED1FB44" box="[114,379,1241,1261]" fontSize="8" level="3" pageId="8" pageNumber="43" reason="8">
|
||
<emphasis id="B91AEAEECE747B6BFF94FB49FED1FB44" box="[114,379,1241,1261]" italics="true" pageId="8" pageNumber="43">2.4.6. Fatty acid derivatives</emphasis>
|
||
</heading>
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE747B6BFF77FB66FF77F905" blockId="8.[113,783,1241,2015]" pageId="8" pageNumber="43">
|
||
Among the more hydrophobic compounds of the semipolar root exudate fraction three oxygenated C18 fatty acids (
|
||
<emphasis id="B91AEAEECE747B6BFD6AFA82FD61FA8C" bold="true" box="[652,715,1298,1317]" pageId="8" pageNumber="43">83–85</emphasis>
|
||
) were detected. For compounds
|
||
<emphasis id="B91AEAEECE747B6BFE91FABEFE3AFAE8" bold="true" box="[375,400,1326,1345]" pageId="8" pageNumber="43">83</emphasis>
|
||
and
|
||
<emphasis id="B91AEAEECE747B6BFE22FABEFE77FAE8" bold="true" box="[452,477,1326,1345]" pageId="8" pageNumber="43">84</emphasis>
|
||
on-line H/D exchange experiments revealed the presence of four exchangeable protons indicating that both fatty acid derivatives are functionalized by three hydroxyl groups. The CID mass spectra obtained from the [M
|
||
<emphasis id="B91AEAEECE747B6BFD3CFA11FD41FA3C" box="[730,747,1409,1429]" italics="true" pageId="8" pageNumber="43">–</emphasis>
|
||
H]
|
||
<emphasis id="B91AEAEECE747B6BFCE5FAEDFCA5FA23" box="[771,783,1405,1418]" italics="true" pageId="8" pageNumber="43">
|
||
<superScript id="7C1B9BB4CE747B6BFCE5FAEDFCA5FA23" attach="none" box="[771,783,1405,1418]" fontSize="5" pageId="8" pageNumber="43">–</superScript>
|
||
</emphasis>
|
||
ion of
|
||
<emphasis id="B91AEAEECE747B6BFF52FA0DFF67FA19" bold="true" box="[180,205,1437,1456]" pageId="8" pageNumber="43">83</emphasis>
|
||
and
|
||
<emphasis id="B91AEAEECE747B6BFEE4FA0DFEB1FA19" bold="true" box="[258,283,1437,1456]" pageId="8" pageNumber="43">84</emphasis>
|
||
showed fragment ions at
|
||
<emphasis id="B91AEAEECE747B6BFDCEFA0CFD91FA19" box="[552,571,1436,1456]" italics="true" pageId="8" pageNumber="43">m</emphasis>
|
||
/
|
||
<emphasis id="B91AEAEECE747B6BFDA5FA0CFDE7FA19" box="[579,589,1436,1456]" italics="true" pageId="8" pageNumber="43">z</emphasis>
|
||
229.14 (C
|
||
<subScript id="17EA34B9CE747B6BFD53FA37FD62FA1A" attach="both" box="[693,712,1447,1459]" fontSize="5" pageId="8" pageNumber="43">12</subScript>
|
||
H
|
||
<subScript id="17EA34B9CE747B6BFD3EFA37FD41FA1A" attach="both" box="[728,747,1447,1459]" fontSize="5" pageId="8" pageNumber="43">21</subScript>
|
||
O
|
||
<subScript id="17EA34B9CE747B6BFD1DFA37FCAEFA1A" attach="left" box="[763,772,1447,1459]" fontSize="5" pageId="8" pageNumber="43">4</subScript>
|
||
<emphasis id="B91AEAEECE747B6BFD1DFA09FCADFA0F" box="[763,775,1433,1446]" italics="true" pageId="8" pageNumber="43">
|
||
<superScript id="7C1B9BB4CE747B6BFD1DFA09FCADFA0F" attach="left" box="[763,775,1433,1446]" fontSize="5" pageId="8" pageNumber="43">–</superScript>
|
||
</emphasis>
|
||
) and
|
||
<emphasis id="B91AEAEECE747B6BFF79FA28FF18FA65" box="[159,178,1464,1484]" italics="true" pageId="8" pageNumber="43">m</emphasis>
|
||
/
|
||
<emphasis id="B91AEAEECE747B6BFF5FFA28FF69FA65" box="[185,195,1464,1484]" italics="true" pageId="8" pageNumber="43">z</emphasis>
|
||
171.10 (C
|
||
<subScript id="17EA34B9CE747B6BFECBFA53FE9CFA66" attach="both" box="[301,310,1475,1487]" fontSize="5" pageId="8" pageNumber="43">9</subScript>
|
||
H
|
||
<subScript id="17EA34B9CE747B6BFEA0FA52FEF3FA67" attach="both" box="[326,345,1474,1486]" fontSize="5" pageId="8" pageNumber="43">15</subScript>
|
||
O
|
||
<subScript id="17EA34B9CE747B6BFE8FFA53FED8FA66" attach="left" box="[361,370,1475,1487]" fontSize="5" pageId="8" pageNumber="43">3</subScript>
|
||
<emphasis id="B91AEAEECE747B6BFE8FFA25FEDFFA6B" box="[361,373,1461,1474]" italics="true" pageId="8" pageNumber="43">
|
||
<superScript id="7C1B9BB4CE747B6BFE8FFA25FEDFFA6B" attach="left" box="[361,373,1461,1474]" fontSize="5" pageId="8" pageNumber="43">–</superScript>
|
||
</emphasis>
|
||
) suggesting that both fatty acid derivatives are hydroxylated in position 12 and/or 13 and 9 and/or 10. In a recent study, 9,12,13-trihydroxy-10,15-octadecadienoic acid and 9,12,13-trihydroxy-10-dodecenoic acid were identified as infection markers in the leaf apoplast washing fluid of
|
||
<taxonomicName id="4C6E4D7FCE747B6BFD40F9B8FCA5F995" box="[678,783,1576,1596]" class="Magnoliopsida" family="Brassicaceae" genus="Arabidopsis" kingdom="Plantae" order="Brassicales" pageId="8" pageNumber="43" phylum="Tracheophyta" rank="species" species="thaliana">
|
||
<emphasis id="B91AEAEECE747B6BFD40F9B8FCA5F995" box="[678,783,1576,1596]" italics="true" pageId="8" pageNumber="43">A. thaliana</emphasis>
|
||
</taxonomicName>
|
||
following infection by
|
||
<taxonomicName id="4C6E4D7FCE747B6BFE93F9D4FF07F9DD" authority="(Floerl et al., 2012)" baseAuthorityName="Floerl" baseAuthorityYear="2012" class="Eurotiomycetes" family="Herpotrichiellaceae" genus="Verticillium" kingdom="Fungi" order="Chaetothyriales" pageId="8" pageNumber="43" phylum="Ascomycota" rank="species" species="longisporum">
|
||
<emphasis id="B91AEAEECE747B6BFE93F9D4FDC6F9F1" box="[373,620,1604,1624]" italics="true" pageId="8" pageNumber="43">Verticillium longisporum</emphasis>
|
||
(
|
||
<bibRefCitation id="EFFF4B0DCE747B6BFD63F9D5FF0EF9DD" author="Floerl, S. & Majcherczyk, A. & Possienke, M. & Feussner, K. & Tappe, H. & Gatz, C. & Feussner, I. & Kues, U. & Polle, A." pageId="8" pageNumber="43" pagination="31435" refId="ref11400" refString="Floerl, S., Majcherczyk, A., Possienke, M., Feussner, K., Tappe, H., Gatz, C., Feussner, I., Kues, U., Polle, A., 2012. Verticillium longisporum infection affects the leaf apoplastic proteome, metabolome, and cell wall properties in Arabidopsis thaliana. PLoS One 7, e 31435." type="journal article" year="2012">Floerl et al., 2012</bibRefCitation>
|
||
)
|
||
</taxonomicName>
|
||
. Authenticated standards of both compounds exhibited identical chromatographic and mass spectral properties as observed for
|
||
<emphasis id="B91AEAEECE747B6BFF97F909FF20F905" bold="true" box="[113,138,1689,1708]" pageId="8" pageNumber="43">83</emphasis>
|
||
and
|
||
<emphasis id="B91AEAEECE747B6BFF58F909FF7DF905" bold="true" box="[190,215,1689,1708]" pageId="8" pageNumber="43">84</emphasis>
|
||
.
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE747B6BFF77F924FEC6F8C6" blockId="8.[113,783,1241,2015]" pageId="8" pageNumber="43">
|
||
The elemental composition of the fatty acid derivative
|
||
<emphasis id="B91AEAEECE747B6BFD58F924FD7DF96E" bold="true" box="[702,727,1716,1735]" pageId="8" pageNumber="43">85</emphasis>
|
||
indicated four oxygen atoms and four double bond equivalents, while on-line H/D exchange experiments revealed the presence of only two exchangeable protons. Unfortunately, the CID mass spectrum obtained from deprotonated
|
||
<emphasis id="B91AEAEECE747B6BFE44F8B4FE11F89E" bold="true" box="[418,443,1828,1847]" pageId="8" pageNumber="43">85</emphasis>
|
||
showed only unspecific neutral losses of water and carbon dioxide for which reason
|
||
<emphasis id="B91AEAEECE747B6BFD68F8D0FD0DF8FA" bold="true" box="[654,679,1856,1875]" pageId="8" pageNumber="43">85</emphasis>
|
||
could not be characterized further.
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE747B6BFF77F8E8FC52FDB1" blockId="8.[113,783,1241,2015]" lastBlockId="8.[831,1501,178,536]" pageId="8" pageNumber="43">
|
||
In contrast, the CID mass spectrum obtained from [M+H]
|
||
<superScript id="7C1B9BB4CE747B6BFD2BF8E4FD7CF829" attach="left" box="[717,726,1908,1920]" fontSize="5" pageId="8" pageNumber="43">+</superScript>
|
||
of
|
||
<emphasis id="B91AEAEECE747B6BFD13F8E8FCA4F822" bold="true" box="[757,782,1912,1931]" pageId="8" pageNumber="43">86</emphasis>
|
||
exhibited characteristic fragments at
|
||
<emphasis id="B91AEAEECE747B6BFE0EF803FE51F80E" box="[488,507,1939,1959]" italics="true" pageId="8" pageNumber="43">m</emphasis>
|
||
/
|
||
<emphasis id="B91AEAEECE747B6BFDE4F803FDA6F80E" box="[514,524,1939,1959]" italics="true" pageId="8" pageNumber="43">z</emphasis>
|
||
184.07 (C
|
||
<subScript id="17EA34B9CE747B6BFD94F80DFDD1F800" attach="right" box="[626,635,1949,1961]" fontSize="5" pageId="8" pageNumber="43">5</subScript>
|
||
H
|
||
<subScript id="17EA34B9CE747B6BFD6DF80DFD34F800" attach="both" box="[651,670,1949,1961]" fontSize="5" pageId="8" pageNumber="43">15</subScript>
|
||
NO
|
||
<subScript id="17EA34B9CE747B6BFD5BF80DFD6CF800" attach="both" box="[701,710,1949,1961]" fontSize="5" pageId="8" pageNumber="43">4</subScript>
|
||
P
|
||
<superScript id="7C1B9BB4CE747B6BFD35F800FD76F835" attach="left" box="[723,732,1936,1948]" fontSize="5" pageId="8" pageNumber="43">+</superScript>
|
||
) and
|
||
<emphasis id="B91AEAEECE747B6BFF97F83FFF2EF86A" box="[113,132,1967,1987]" italics="true" pageId="8" pageNumber="43">m</emphasis>
|
||
/
|
||
<emphasis id="B91AEAEECE747B6BFF6AF83FFF3CF86A" box="[140,150,1967,1987]" italics="true" pageId="8" pageNumber="43">z</emphasis>
|
||
104.11 (C
|
||
<subScript id="17EA34B9CE747B6BFEE4F828FEA1F86D" attach="both" box="[258,267,1976,1988]" fontSize="5" pageId="8" pageNumber="43">5</subScript>
|
||
H
|
||
<subScript id="17EA34B9CE747B6BFEFAF828FE85F86D" attach="right" box="[284,303,1976,1988]" fontSize="5" pageId="8" pageNumber="43">15</subScript>
|
||
NO
|
||
<superScript id="7C1B9BB4CE747B6BFEA8F83CFEFDF811" attach="left" box="[334,343,1964,1976]" fontSize="5" pageId="8" pageNumber="43">+</superScript>
|
||
<subScript id="17EA34B9CE747B6BFEA8F829FEFDF86C" attach="left" box="[334,343,1977,1989]" fontSize="5" pageId="8" pageNumber="43">4</subScript>
|
||
) indicating the presence of a phosphorylcholine moiety. The occurrence of fragments ions at
|
||
<emphasis id="B91AEAEECE747B6BFD7BF85AFD1AF877" box="[669,688,1994,2014]" italics="true" pageId="8" pageNumber="43">m</emphasis>
|
||
/
|
||
<emphasis id="B91AEAEECE747B6BFD51F85AFD6BF877" box="[695,705,1994,2014]" italics="true" pageId="8" pageNumber="43">z</emphasis>
|
||
187.10 (C
|
||
<subScript id="17EA34B9CE747B6BFCB2FF2FFCF7FF62" attach="both" box="[852,861,191,203]" fontSize="5" pageId="8" pageNumber="43">9</subScript>
|
||
H
|
||
<subScript id="17EA34B9CE747B6BFC88FF2FFC2BFF62" attach="right" box="[878,897,191,203]" fontSize="5" pageId="8" pageNumber="43">15</subScript>
|
||
O
|
||
<subScript id="17EA34B9CE747B6BFC76FF2FFC33FF62" attach="left" box="[912,921,191,203]" fontSize="5" pageId="8" pageNumber="43">4</subScript>
|
||
<emphasis id="B91AEAEECE747B6BFC76FF22FC36FF16" box="[912,924,178,191]" italics="true" pageId="8" pageNumber="43">
|
||
<superScript id="7C1B9BB4CE747B6BFC76FF22FC36FF16" attach="left" box="[912,924,178,191]" fontSize="5" pageId="8" pageNumber="43">–</superScript>
|
||
</emphasis>
|
||
),
|
||
<emphasis id="B91AEAEECE747B6BFC53FF25FC62FF60" box="[949,968,181,201]" italics="true" pageId="8" pageNumber="43">m</emphasis>
|
||
/
|
||
<emphasis id="B91AEAEECE747B6BFC29FF25FC73FF60" box="[975,985,181,201]" italics="true" pageId="8" pageNumber="43">z</emphasis>
|
||
169.09 (C
|
||
<subScript id="17EA34B9CE747B6BFBACFF2FFBF9FF62" attach="both" box="[1098,1107,191,203]" fontSize="5" pageId="8" pageNumber="43">9</subScript>
|
||
H
|
||
<subScript id="17EA34B9CE747B6BFB82FF2FFBDDFF62" attach="both" box="[1124,1143,191,203]" fontSize="5" pageId="8" pageNumber="43">13</subScript>
|
||
O
|
||
<subScript id="17EA34B9CE747B6BFB60FF2FFB25FF62" attach="left" box="[1158,1167,191,203]" fontSize="5" pageId="8" pageNumber="43">3</subScript>
|
||
<emphasis id="B91AEAEECE747B6BFB60FF22FB38FF16" box="[1158,1170,178,191]" italics="true" pageId="8" pageNumber="43">
|
||
<superScript id="7C1B9BB4CE747B6BFB60FF22FB38FF16" attach="left" box="[1158,1170,178,191]" fontSize="5" pageId="8" pageNumber="43">–</superScript>
|
||
</emphasis>
|
||
) and
|
||
<emphasis id="B91AEAEECE747B6BFB31FF25FB40FF60" box="[1239,1258,181,201]" italics="true" pageId="8" pageNumber="43">m</emphasis>
|
||
/
|
||
<emphasis id="B91AEAEECE747B6BFB14FF25FB56FF60" box="[1266,1276,181,201]" italics="true" pageId="8" pageNumber="43">z</emphasis>
|
||
125.10 (C
|
||
<subScript id="17EA34B9CE747B6BFA8BFF2FFADCFF62" attach="both" box="[1389,1398,191,203]" fontSize="5" pageId="8" pageNumber="43">8</subScript>
|
||
H
|
||
<subScript id="17EA34B9CE747B6BFA60FF2FFA33FF62" attach="both" box="[1414,1433,191,203]" fontSize="5" pageId="8" pageNumber="43">13</subScript>
|
||
O
|
||
<emphasis id="B91AEAEECE747B6BFA4EFF22FA1EFF16" box="[1448,1460,178,191]" italics="true" pageId="8" pageNumber="43">
|
||
<superScript id="7C1B9BB4CE747B6BFA4EFF22FA1EFF16" attach="left" box="[1448,1460,178,191]" fontSize="5" pageId="8" pageNumber="43">–</superScript>
|
||
</emphasis>
|
||
) in the CID mass spectrum obtained from deprotonated
|
||
<emphasis id="B91AEAEECE747B6BFA94FF42FA21FF4C" bold="true" box="[1394,1419,210,229]" pageId="8" pageNumber="43">86</emphasis>
|
||
was in accordance with a lysophosphatidylcholine of an oxygenated C9 fatty acid. Since on-line H/D-exchange experiments revealed the presence of two exchangeable protons
|
||
<emphasis id="B91AEAEECE747B6BFB30FEB6FB45FE90" bold="true" box="[1238,1263,294,313]" pageId="8" pageNumber="43">86</emphasis>
|
||
is postulated to be an azelaoyl lysophosphatidylcholine. Azelaic acid itself was shown to be produced by oxidative fragmentation of esterified 18:2 and 18:3 fatty acid species and proposed to be a general marker for lipid peroxidation (
|
||
<bibRefCitation id="EFFF4B0DCE747B6BFBE5FE05FB6AFE00" author="Zoeller, M. & Stingl, N. & Krischke, M. & Fekete, A. & Waller, F. & Berger, S. & Mueller, M. J." box="[1027,1216,405,425]" pageId="8" pageNumber="43" pagination="365 - 378" refId="ref14014" refString="Zoeller, M., Stingl, N., Krischke, M., Fekete, A., Waller, F., Berger, S., Mueller, M. J., 2012. Lipid profiling of the Arabidopsis hypersensitive response reveals specific lipid peroxidation and fragmentation processes: biogenesis of pimelic and azelaic acid. Plant Physiol. 160, 365 - 378." type="journal article" year="2012">Zoeller et al., 2012</bibRefCitation>
|
||
). In addition, this dicarboxylic acid was identified as pathogen inducible metabolite from the vascular sap of
|
||
<taxonomicName id="4C6E4D7FCE747B6BFBE0FE5CFBC5FE49" box="[1030,1135,460,480]" class="Magnoliopsida" family="Brassicaceae" genus="Arabidopsis" kingdom="Plantae" order="Brassicales" pageId="8" pageNumber="43" phylum="Tracheophyta" rank="species" species="thaliana">
|
||
<emphasis id="B91AEAEECE747B6BFBE0FE5CFBC5FE49" box="[1030,1135,460,480]" italics="true" pageId="8" pageNumber="43">A. thaliana</emphasis>
|
||
</taxonomicName>
|
||
and shown to confer local and systemic resistance against the pathogen
|
||
<taxonomicName id="4C6E4D7FCE747B6BFB1EFE78FC5EFDB1" authority="(Jung et al., 2009)" baseAuthorityName="Jung" baseAuthorityYear="2009" class="Betaproteobacteria" family="Burkholderiaceae" genus="Pseudomonas" kingdom="Bacteria" order="Burkholderiales" pageId="8" pageNumber="43" phylum="Proteobacteria" rank="species" species="syringae">
|
||
<emphasis id="B91AEAEECE747B6BFB1EFE78FA77FE55" box="[1272,1501,488,508]" italics="true" pageId="8" pageNumber="43">Pseudomonas syringae</emphasis>
|
||
(
|
||
<bibRefCitation id="EFFF4B0DCE747B6BFCA1FD95FC41FDB1" author="Jung, H. W. & Tschaplinski, T. J. & Wang, L. & Glazebrook, J. & Greenberg, J. T." box="[839,1003,517,536]" pageId="8" pageNumber="43" pagination="89 - 91" refId="ref11891" refString="Jung, H. W., Tschaplinski, T. J., Wang, L., Glazebrook, J., Greenberg, J. T., 2009. Priming in systemic plant immunity. Science 324, 89 - 91." type="journal article" year="2009">Jung et al., 2009</bibRefCitation>
|
||
)
|
||
</taxonomicName>
|
||
.
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE747B6BFCD9FDD7FBFBFDF2" blockId="8.[831,1501,583,883]" box="[831,1105,583,603]" pageId="8" pageNumber="43">
|
||
<heading id="D0998190CE747B6BFCD9FDD7FBFBFDF2" box="[831,1105,583,603]" fontSize="8" level="3" pageId="8" pageNumber="43" reason="8">
|
||
<emphasis id="B91AEAEECE747B6BFCD9FDD7FBFBFDF2" box="[831,1105,583,603]" italics="true" pageId="8" pageNumber="43">2.4.7. Unknown components</emphasis>
|
||
</heading>
|
||
</paragraph>
|
||
<paragraph id="8BD136FCCE747B6BFCB8FDF4FB43FCDB" blockId="8.[831,1501,583,883]" pageId="8" pageNumber="43">
|
||
Among the compounds which were reproducibly detected in root exudates of
|
||
<taxonomicName id="4C6E4D7FCE747B6BFC01FDEFFBE4FD3A" box="[999,1102,639,659]" class="Magnoliopsida" family="Brassicaceae" genus="Arabidopsis" kingdom="Plantae" order="Brassicales" pageId="8" pageNumber="43" phylum="Tracheophyta" rank="species" species="thaliana">
|
||
<emphasis id="B91AEAEECE747B6BFC01FDEFFBE4FD3A" box="[999,1102,639,659]" italics="true" pageId="8" pageNumber="43">A. thaliana</emphasis>
|
||
</taxonomicName>
|
||
, 17 could not or only partially be structurally characterized. Thereof, 11 compounds were annotated as glycoconjugates with unknown aglycone based on characteristic neutral losses and fragment ions. Among them, five hexose conjugates (
|
||
<emphasis id="B91AEAEECE747B6BFC67FD60FC30FCAA" bold="true" box="[897,922,752,771]" pageId="8" pageNumber="43">87</emphasis>
|
||
,
|
||
<emphasis id="B91AEAEECE747B6BFC43FD60FC14FCAA" bold="true" box="[933,958,752,771]" pageId="8" pageNumber="43">91</emphasis>
|
||
,
|
||
<emphasis id="B91AEAEECE747B6BFC2EFD60FC4BFCAA" bold="true" box="[968,993,752,771]" pageId="8" pageNumber="43">92</emphasis>
|
||
,
|
||
<emphasis id="B91AEAEECE747B6BFC0AFD60FBAFFCAA" bold="true" box="[1004,1029,752,771]" pageId="8" pageNumber="43">93</emphasis>
|
||
,
|
||
<emphasis id="B91AEAEECE747B6BFBF6FD60FB83FCAA" bold="true" box="[1040,1065,752,771]" pageId="8" pageNumber="43">95</emphasis>
|
||
), three malonyl–hexose conjugates (
|
||
<emphasis id="B91AEAEECE747B6BFA7CFD60FA19FCAA" bold="true" box="[1434,1459,752,771]" pageId="8" pageNumber="43">88</emphasis>
|
||
,
|
||
<emphasis id="B91AEAEECE747B6BFA58FD60FA7DFCAA" bold="true" box="[1470,1495,752,771]" pageId="8" pageNumber="43">94</emphasis>
|
||
,
|
||
<emphasis id="B91AEAEECE747B6BFCD9FC9BFCF2FCB7" bold="true" box="[831,856,779,798]" pageId="8" pageNumber="43">97</emphasis>
|
||
), a hexose–deoxyhexose conjugate (
|
||
<emphasis id="B91AEAEECE747B6BFB21FC9BFB4AFCB7" bold="true" box="[1223,1248,779,798]" pageId="8" pageNumber="43">89</emphasis>
|
||
) and a malonyl–hexose– deoxyhexose conjugate (
|
||
<emphasis id="B91AEAEECE747B6BFBDBFCB7FBFCFC93" bold="true" box="[1085,1110,807,826]" pageId="8" pageNumber="43">90</emphasis>
|
||
) were detected. Beside the three sulfated phenylpropanoids and the sulfated jasmonic acid derivative, another sulfate conjugate (
|
||
<emphasis id="B91AEAEECE747B6BFBB6FCCFFBC3FCDB" bold="true" box="[1104,1129,863,882]" pageId="8" pageNumber="43">98</emphasis>
|
||
) was found.
|
||
</paragraph>
|
||
</subSubSection>
|
||
</treatment>
|
||
</document> |